ChemicalBook > CAS DataBase List > (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER

(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER

Product Name
(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
CAS No.
88568-95-0
Chemical Name
(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
Synonyms
Methyl 2-(((benzyloxy)carbonyl)aMino)-2-(diMethoxyphosphoryl)acetate;(±)-Z-α-Phosphonoglycine trimethyl ester;(±)-Z-a-phosphonoglycine trimethyl ester;Methyl 2-(((b;ycine trimethyL;)-Z-α-Phosphonog;)-Z-α-PhosphonogL;Z-Gly(PO(OME2))-OMe;Z-α-Phosphonoglycine;Z-a-Phosphonoglycine
CBNumber
CB9143207
Molecular Formula
C13H18NO7P
Formula Weight
331.26
MOL File
88568-95-0.mol
More
Less

(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER Property

Melting point:
77-80 °C(lit.)
Boiling point:
480.5±45.0 °C(Predicted)
Density 
1.284±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
pka
9.42±0.46(Predicted)
form 
Crystalline Powder
color 
White
BRN 
5764460
InChI
InChI=1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16)
InChIKey
GSYSFVSGPABNNL-UHFFFAOYSA-N
SMILES
C(OC)(=O)C(P(OC)(OC)=O)NC(OCC1=CC=CC=C1)=O
CAS DataBase Reference
88568-95-0(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
22-24/25-36-26-37/39
WGK Germany 
3
HS Code 
29242990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
376353
Product name
Z-α-Phosphonoglycine trimethyl ester
Purity
97%
Packaging
5g
Price
$152
Updated
2025/07/31
TCI Chemical
Product number
C2440
Product name
N-Carbobenzoxy-2-phosphonoglycine Trimethyl Ester
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$52
Updated
2025/07/31
TCI Chemical
Product number
C2440
Product name
N-Carbobenzoxy-2-phosphonoglycine Trimethyl Ester
Purity
>98.0%(HPLC)(N)
Packaging
5g
Price
$108
Updated
2025/07/31
TRC
Product number
P353820
Product name
Z-α-Phosphonoglycine
Packaging
5g
Price
$165
Updated
2021/12/16
AK Scientific
Product number
J91538
Product name
(+/-)-Cbz-alpha-phosphonoglycinetrimethylester
Packaging
1g
Price
$10
Updated
2021/12/16
More
Less

(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER Chemical Properties,Usage,Production

Description

(+/-)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester is an important organic compound with the appearance of white to off-white powder to crystals, melting point of 78.0~ 82.0 °C, soluble in methanol, irritating to the eyes and skin, store in a cool, dry place in a closed Keep away from strong oxidising agents. Keep away from strong oxidising agents. It is mainly used in chemical industry and experimental research.

Chemical Properties

White crystalline powder

Uses

Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids

Uses

Z-α-Phosphonoglycine is used in the synthesis of calcitonin gene-related peptide antagonists. Also used in the synthesis of dehydroamino acid esters for amino acid and peptide research.

reaction suitability

reaction type: solution phase peptide synthesis

(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER Suppliers

Americas 1 Belgium 3 Canada 1 China 190 Europe 1 France 2 Germany 5 Hungary 1 India 6 Japan 6 Switzerland 1 The Netherlands 1 United Kingdom 13 United States 49 Global 280
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
More
Less

View Lastest Price from (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER manufacturers

Career Henan Chemical Co
Product
(+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER 88568-95-0
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-07-30

88568-95-0, (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTERRelated Search:

(+/-)-BOC-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER (+/-)-BOC-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER DIMETHYLPHOSPHONOACETIC ACID (Aminomethyl)phosphonic acid AMINOETHYLPHOSPHINIC ACID Dimethyl 2-hydroxyethylphosphonate PHOSPHONOACETIC ACID Trimethyl phosphonoacetate (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER METHYL CBZ-AMINO(DIETHOXYPHOSPHORYL)ACETATE 2-HYDROXYETHYL PHOSPHONIC ACID N-CBZ-ETHYL-2-(DIMETHYLPHOSPHONO)-GLYCINATE Z-GLY-OME DL-1-(Aminoethyl)phosphonic acid N-METHYLAMINOMETHYL PHOSPHONIC ACID

  • N-Cbz-2-Phosphonoglycine trimethyl ester
  • N-Cbz-2-phosphonoglycine Trimethyl Ester Trimethyl 2-(Carbobenzoxyamino)-2-phosphonoacetate Trimethyl 2-(Cbz-amino)-2-phosphonoacetate
  • (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetate,95%
  • (+/-)-Benzyloxycarbonyl-alfa-phosphonoglycinetrimethylester
  • N-Carbobenzoxy-2-phosphonoglycine Trimethyl Ester
  • (§1)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetate, 95%
  • (+/-)-Cbz-alpha-phosphonoglycine
  • (+/-)-METHYL 2-BENZYLOXYCARBONYLAMINO-2-(DIMETHOXYPHOSPHINYL)ACETATE
  • DL-Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • (+/-)-CBZ-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • (+/-)-Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • Z-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • (+/-)-TRIMETHYL Z-ALPHA-PHOSPHONOGLYCINATE
  • N-CBZ-2-METHYL (DIMETHYLPHOSPHONO) GLYCINATE
  • N-BENZYLOXYCARBONYLPHOSPHONOGLYCINE TRIMETHYL ESTER
  • N-BENZYLOXYCARBONYL TRIMETHYLPHOSPHONOGLYCINE
  • (±)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester(N-Cbz-PTE)
  • Methyl N-(benzyloxycarbonyl)-2-(dimethylphosphono)glycinate
  • Z-Gly(PO(OME2))-OMe
  • 2-(DiMethoxyphosphinyl)-2-[[(benzyloxy)carbonyl]aMino]acetic acid Methyl ester
  • Benzyloxycarbonyl-alpha-phosphonoglycinetriMethyl es
  • (+/-)-BENZYLOXYCARBONYL-ALPHA-PHOSPHONOGLYCINE
  • Methyl 2-(((benzyloxy)carbonyl)aMino)-2-(diMethoxyphosphoryl)acetate
  • Acetic acid, 2-(dimethoxyphosphinyl)-2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester
  • Cbz-a-phosphono-glycine trimethyl ester
  • <i>N</i>-Carbobenzoxy-2-phosphonoglycine trimethyl ester
  • N-Benzylcarbonyl-alpha-phosphonoglycine trimethyl ester
  • (Dimethoxyphosphinyl)(benzyloxycarbonylamino)acetic acid methyl ester
  • (Dimethoxyphosphinyl)[(benzyloxycarbonyl)amino]acetic acid methyl ester
  • 2-(Dimethoxyphosphinyl)-N-[(phenylmethoxy)carbonyl]glycine methyl ester
  • 2-[(Benzyloxycarbonyl)amino]-2-(dimethoxyphosphinyl)acetic acid methyl ester
  • N-(Benzyloxycarbonyl)-2-(dimethoxyphosphinyl)glycine methyl ester
  • N-(Benzyloxycarbonyl)-2-phosphonoglycine trimethyl ester
  • (^+)-Benzyloxycarbonyl-^a-phosphonoglycine trimethyl ester, 97%
  • (±)-Z-α-Phosphonoglycine trimethyl ester, >=97%
  • N-Cbz-PTE (+/-)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester
  • (±)-Z-α-phosphonoglycine trimethyl ester97.0 +%
  • (±)-Trimethyl Z-α-phosphonoglycinate, (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate
  • )-Z-α-Phosphonog
  • ycine trimethyL
  • N-(BENZYLOXYCARBONYL)-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • N-Z-PHOSPHONOGLYCINE TRIMETHYL ESTER
  • (±)-Trimethyl Z-α-phosphonoglycinate
  • (±)-Z-α-Phosphonoglycine trimethyl ester
  • (+-)-N-cbz-A-phosphonoglycine trimethyl ester
  • N-(BENZYLOXYCARBONYL)-ALPHA-PHOSPHONO-GL
  • DL-alpha-Phosphonoglycinetrimethylester
  • CBZ-ALPHA-PHOSPHONO-DL-GLYCINE TRIMETHYL ESTER
  • (n)-benzyloxycarbonyl-à-phosphonoglycine trimethyl ester
  • (n)-cbz-à-phosphonoglycine trimethyl ester
  • (+/-)-Benzyloxycarbonyl-α-phosphonoglycinetrimethylester
  • Benzyloxycarbonylamino-(dimethoxy-phosphoryl)-acetic acid methyl ester
  • (±)-Z-a-phosphonoglycine trimethyl ester
  • (±)-Benzyloxycarbonyl-ɑ-phosphonoglycine trimethyl ester, 97%
  • (±)-Trimethyl Z-α-phosphonoglycinate, (±)-Z-α-Phosphonoglycine trimethyl ester, (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate
  • Trimethyl N-(benzyloxycarbonyl)-2-phosphonoglycinate
  • Methyl 2-(((b