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Bis(triphenylphosphine)nickel(II) bromide

Product Name
Bis(triphenylphosphine)nickel(II) bromide
CAS No.
14126-37-5
Chemical Name
Bis(triphenylphosphine)nickel(II) bromide
Synonyms
NiBr2(PPh3)2;Dibromobis(triphenyL;DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKELBROMIDE;Nickel,dibromobis[triphenylphosphine]-;Bis-(triphenylphosphino)-nickel bromide;Dibromobis(triphenylphosphine)nickel(Ⅱ);Bis(triphenylphosphine)dibromonickel(II);Nickel(II)bromidebis(triphenylphosphine);DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
CBNumber
CB9146561
Molecular Formula
C36H30Br2NiP2
Formula Weight
743.07
MOL File
14126-37-5.mol
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Bis(triphenylphosphine)nickel(II) bromide Property

Melting point:
219-223 °C (lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
green
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChI
InChI=1S/2C18H15P.2BrH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKey
QEKXARSPUFVXIX-UHFFFAOYSA-L
SMILES
P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Br)Br
CAS DataBase Reference
14126-37-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36/37
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
331708
Product name
Dibromobis(triphenylphosphine)nickel(II)
Purity
99%
Packaging
10g
Price
$125
Updated
2024/03/01
Sigma-Aldrich
Product number
331708
Product name
Dibromobis(triphenylphosphine)nickel(II)
Purity
99%
Packaging
50g
Price
$236.8
Updated
2024/03/01
Alfa Aesar
Product number
042192
Product name
Dibromobis(triphenylphosphine)nickel(II), 99%
Packaging
5g
Price
$60.65
Updated
2024/03/01
Alfa Aesar
Product number
042192
Product name
Dibromobis(triphenylphosphine)nickel(II), 99%
Packaging
1g
Price
$26.7
Updated
2023/06/20
Strem Chemicals
Product number
28-0092
Product name
Bis(triphenylphosphine)nickel(II) bromide, 99%
Packaging
10g
Price
$80
Updated
2024/03/01
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Bis(triphenylphosphine)nickel(II) bromide Chemical Properties,Usage,Production

Chemical Properties

DARK GREEN CRYSTALLINE POWDER OR CRYSTALS

Uses

As a polymerization catalyst

Uses

Catalysts for the cross-coupling reactions, C-X bond reduction, homocoupling of Csp2 halides, displacement of aryl halides, and oligomerization of dienes

Bis(triphenylphosphine)nickel(II) bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Bis(triphenylphosphine)nickel(II) bromide manufacturers

Career Henan Chemical Co
Product
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE 14126-37-5
Price
US $1.00/KG
Min. Order
1G
Purity
98%
Supply Ability
1000KG
Release date
2018-08-10

14126-37-5, Bis(triphenylphosphine)nickel(II) bromideRelated Search:


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  • Dibromobis(triphenylphosphine)nickel(II), 99%, for synthesis
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  • Catalysis and Inorganic Chemistry
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  • Metal Compounds