ChemicalBook > CAS DataBase List > 6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID

6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID

Product Name
6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID
CAS No.
749849-14-7
Chemical Name
6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID
Synonyms
BUTTPARK 154\50-31;6-bromo-2-imidazo[1,2-a]pyridinecarboxylic acid;6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID;6-Bromoimidazo[1,2-a]pyridine-2-carboxylicacid 97%;IMidazo[1,2-a]pyridine-2-carboxylic acid, 6-broMo-;6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID, 95+%;6-Bromoimidazo[1,2-a]pyridine-2-carboxylicacidhydrate,95%;6-BroMoiMidazo[1,2-a]pyridine-2-carboxylic acid hydrate, 95%
CBNumber
CB9146581
Molecular Formula
C8H5BrN2O2
Formula Weight
241.04
MOL File
749849-14-7.mol
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6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID Property

Density 
1.89
storage temp. 
2-8°C
pka
-4.73±0.41(Predicted)
Appearance
Off-white to light brown Solid
CAS DataBase Reference
749849-14-7(CAS DataBase Reference)
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
B699755
Product name
6-Bromoimidazo[1,2-a]pyridine-2-carboxylicAcid
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
B699755
Product name
6-Bromoimidazo[1,2-a]pyridine-2-carboxylicAcid
Packaging
50mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
4H21-9-03
Product name
6-Bromo-imidazo[1,2-a]pyridine-2-carboxylic acid
Purity
95%
Packaging
250mg
Price
$55
Updated
2021/12/16
Matrix Scientific
Product number
071822
Product name
6-Bromoimidazo[1,2-a]pyridine-2-carboxylic acid
Purity
95+%
Packaging
1g
Price
$100
Updated
2021/12/16
Apolloscientific
Product number
OR110722
Product name
6-Bromoimidazo[1,2-a]pyridine-2-carboxylicacid
Purity
98%
Packaging
1g
Price
$108
Updated
2021/12/16
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6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

67625-37-0

749849-14-7

General procedure for the synthesis of 6-bromoimidazo[1,2-a]pyridine-2-carboxylic acid from ethyl 6-bromoimidazo[1,2-a]pyridine-2-carboxylate: ethyl 6-bromoimidazo[1,2-a]pyridine-2-carboxylate (200 mg, 0.74 mmol) was dissolved in a mixed solvent of tetrahydrofuran (2 mL) and methanol (2 mL), and lithium hydroxide (42 mg) was added. 0.98 mmol) in aqueous solution (2 mL). The reaction mixture was stirred at 60°C overnight. Upon completion of the reaction, the volatile solvent was removed by rotary evaporation. The residue was diluted with water and acidified to pH 4 with aqueous 1 N hydrochloric acid.The precipitate was collected by filtration, washed with water and dried under vacuum to afford 6-bromoimidazo[1,2-a]pyridine-2-carboxylic acid (0.125 g, 70% yield). The intermediate could be directly used in the subsequent reaction without further purification.LC-MS analysis showed a single absorption peak at 254 nm, and the measured molecular ion peak (MH+) was 241, which was in accordance with the theoretically calculated value (C8H5BrN2O2).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2006, vol. 16, # 21, p. 5598 - 5601
[2] Patent: WO2011/50245, 2011, A1. Location in patent: Page/Page column 99

6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID Suppliers

China 87 France 1 Germany 2 India 2 Russia 1 Ukraine 1 United Kingdom 10 United States 20 Global 124
ACB Blocks Ltd.
Tel
--
Fax
--
Email
info@acbblocks.com
Country
Russia
ProdList
2666
Advantage
46
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View Lastest Price from 6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID manufacturers

Career Henan Chemical Co
Product
6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID 749849-14-7
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-02

749849-14-7, 6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACIDRelated Search:

6-Bromo-2-mercaptothiazolo[4,5-b]pyridine methyl 6-bromoimidazo[1,2-a]pyridine-2-carboxylate 6-Bromo-imidazo[1,2-a]pyrimidine Ethyl 6-bromoimidazo[1,2-a]pyridine-2-carboxylate 6-BROMO-THIAZOLO[5,4-B]PYRIDINE 6-Bromoimidazo[1,2-b]pyri... 6-BROMOTHIAZOLO[5,4-B]PYRAZINE 6-bromoimidazo[1,2-a]pyrazin-8-amine 6-BROMO-IMIDAZO[1,2-A]PYRIDINE-2-CARBOXALDEHYDE 6-Bromoimidazo[1,2-a]pyridine 6-Bromoimidazo[1,2-a]pyridine-3-carboxylicacid Thiazolo[4,5-b]pyridin-2-aMine, 6-broMo- 3-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER, 95+%,3-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER 3-Bromoimidazo[1,5-a]pyridine-1-carboxylic acid 3-BROMOIMIDAZO[1,2-A]PYRIDINE-6-CARBOXYLIC ACID 3-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID, 95+%,3-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID 5-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID 7-bromoimidazo[1,2-a]pyridine-3-carboxylic acid

  • 6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID
  • BUTTPARK 154\50-31
  • 6-BROMOIMIDAZO[1,2-A]PYRIDINE-2-CARBOXYLIC ACID, 95+%
  • IMidazo[1,2-a]pyridine-2-carboxylic acid, 6-broMo-
  • 6-Bromoimidazo[1,2-a]pyridine-2-carboxylicacid 97%
  • 6-BroMoiMidazo[1,2-a]pyridine-2-carboxylic acid hydrate, 95%
  • 6-bromo-2-imidazo[1,2-a]pyridinecarboxylic acid
  • 6-Bromoimidazo[1,2-a]pyridine-2-carboxylicacidhydrate,95%
  • 749849-14-7
  • 749848-14-7
  • C8H6Br2N2O2
  • C8H5BrN2O2
  • Heterocycle-Pyridine series
  • Carboxylic Acids
  • Fused Ring Systems
  • Carboxylic Acids