1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

Product Name: 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE
CAS No.: 57842-27-0
Chemical Name: 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE
Synonyms: bdtf;1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE;1,3-Benzolithiolylium Tetrafluoroborate;1,3-benzodithiol-3-ium:tetrafluoroborate;1,3-BENZODITHIOL-2-YLIUM TETRAFLUOROBORATE;1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE 97%;1,3-Benzodithiol-1-ium tetrafluoroborate 98%;Benzo[d][1,3]dithiol-1-ium tetrafluoroborate;1,3-Benzodithiolylium Tetrafluoroborate 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE USP/EP/BP
CBNumber: CB9155527
Molecular Formula: C7H5BF4S2
Formula Weight: 240.05
MOL File: 57842-27-0.mol

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1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Property

Melting point:: 150 °C (dec.) (lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Solid
color: Gray to brown
BRN: 4731453
CAS DataBase Reference: 57842-27-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: 1759
WGK Germany: 3
F: 8-10-21
Hazard Note: Irritant
HazardClass: 8
PackingGroup: III
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 393770
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Purity: 98%
Packaging: 5G
Price: $126
Updated: 2023/01/07

TCI Chemical

Product number: B1151
Product name: 1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent]
Purity: >96.0%(T)
Packaging: 5g
Price: $116
Updated: 2024/03/01

TRC

Product number: B410545
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 1g
Price: $180
Updated: 2021/12/16

AK Scientific

Product number: Z3507
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 5g
Price: $193
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB61071
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 5G
Price: $200
Updated: 2021/12/16

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1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Chemical Properties,Usage,Production

Uses

1,3-Benzodithiolylium tetrafluoroborate may be used in the synthesis of the following:

Dibenzotetrathiafulvalene by reacting with 1,8-diazabicyclo[5.4.0]undec-7-ene.
Substituted arylcarbenium ions by reacting with boronic derivatives.
α-(1,3-benzodithiol-2-ylidene) ketones and 1,3-benzodithiole by reacting with ketones.
2-styryl-1,3-benzodithioles by reacting with styryl-type cobaloximes.
2-(3-indolyl)-1,3-benzodithiolylium tetrafluoroborate by reacting with indole.
2-(1,3-benzodithiol-2-ylidene)-3,5-cyclohexadien-1-ones and 4-(1,3-benzodithiol-2-ylidene)-2,5-cyclohexadien-1-ones by reacting with 2,4- and 2,6-disubstituted phenols.

General Description

1,3-Benzodithiolylium tetrafluoroborate is a carbenium ionic compound. It has been synthesized by reacting 1,3-benzodithiole with trityl tetrafluoroborate. It is widely used as an α-alkylating agent for the enantioselective α-alkylation of aldehydes., The nature of adsorption of 1,3-benzodithiolylium tetrafluoroborate on various carbon nanotubes (CNTs) has been studied. 1,3-Benzodithiolylium tetrafluoroborate reacts with different nucleophilic reagents at the 2-position to form the respective 1,3-benzodithioles.

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Isoamyl nitrite Acetic anhydride Carbon disulfide Fluoroboric acid Anthranilic acid 3-Methyl-1-butanol

Preparation Products

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1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Suppliers

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57842-27-0, 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATERelated Search:

TRIMETHYLSULFONIUM HYDROXIDE 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

1,3-BENZODITHIOL-2-YLIUM TETRAFLUOROBORATE

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

1,3-Benzodithiolylium tetrafluoroborate[Hydroxyl protecting agent]

1,3-Benzodithiol-1-ium tetrafluoroborate 98%

bdtf

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE 97%

1,3-Benzolithiolylium Tetrafluoroborate

Benzo[d][1,3]dithiol-1-ium tetrafluoroborate, BDTF

1,3-Benzodithiolylium Tetrafluoroborate&nbsp

Benzo[d][1,3]dithiol-1-ium tetrafluoroborate

1,3-benzodithiol-3-ium:tetrafluoroborate

1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent]&gt

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE USP/EP/BP

57842-27-0

C7H5S2BF4

C7H5BF4S2

S-Containing

Heterocyclic Building Blocks

Others

Protecting Agents for Hydroxyl Group (DNA/RNA Synthesis)

Sulfonium Compounds

DNA / RNA Synthesis

Sulfur Compounds (for Synthesis)

B (Classes of Boron Compounds)

Protection & Derivatization Reagents (for Synthesis)

Iodonium Sulfonium & Oxonium Compounds

Tetrafluoroborates

Building Blocks

Heterocyclic Compounds

Iodonium Sulfonium & Oxonium Compounds

Sulfonium Compounds

B (Classes of Boron Compounds)

Biochemistry

Nucleosides, Nucleotides & Related Reagents

Protecting Agents for Hydroxyl and Amino Groups

Protecting Agents, Phosphorylating Agents & Condensing Agents

Protection & Derivatization Reagents (for Synthesis)

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry

Tetrafluoroborates