1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

Product Name: 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE
CAS No.: 57842-27-0
Chemical Name: 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE
Synonyms: bdtf;1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE;1,3-Benzolithiolylium Tetrafluoroborate;1,3-benzodithiol-3-ium:tetrafluoroborate;1,3-BENZODITHIOL-2-YLIUM TETRAFLUOROBORATE;1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE 97%;1,3-Benzodithiol-1-ium tetrafluoroborate 98%;Benzo[d][1,3]dithiol-1-ium tetrafluoroborate;1,3-Benzodithiolylium Tetrafluoroborate 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE USP/EP/BP
CBNumber: CB9155527
Molecular Formula: C7H5BF4S2
Formula Weight: 240.05
MOL File: 57842-27-0.mol

More

Less

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Property

Melting point:: 150 °C (dec.) (lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Solid
color: Gray to brown
BRN: 4731453
CAS DataBase Reference: 57842-27-0(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: 1759
WGK Germany: 3
F: 8-10-21
Hazard Note: Irritant
HazardClass: 8
PackingGroup: III
HS Code: 2934999090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 393770
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Purity: 98%
Packaging: 5G
Price: $126
Updated: 2023/01/07

TCI Chemical

Product number: B1151
Product name: 1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent]
Purity: >96.0%(T)
Packaging: 5g
Price: $116
Updated: 2024/03/01

TRC

Product number: B410545
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 1g
Price: $180
Updated: 2021/12/16

AK Scientific

Product number: Z3507
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 5g
Price: $193
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB61071
Product name: 1,3-Benzodithiolylium tetrafluoroborate
Packaging: 5G
Price: $200
Updated: 2021/12/16

More

Less

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Chemical Properties,Usage,Production

Uses

1,3-Benzodithiolylium tetrafluoroborate may be used in the synthesis of the following:

Dibenzotetrathiafulvalene by reacting with 1,8-diazabicyclo[5.4.0]undec-7-ene.
Substituted arylcarbenium ions by reacting with boronic derivatives.
α-(1,3-benzodithiol-2-ylidene) ketones and 1,3-benzodithiole by reacting with ketones.
2-styryl-1,3-benzodithioles by reacting with styryl-type cobaloximes.
2-(3-indolyl)-1,3-benzodithiolylium tetrafluoroborate by reacting with indole.
2-(1,3-benzodithiol-2-ylidene)-3,5-cyclohexadien-1-ones and 4-(1,3-benzodithiol-2-ylidene)-2,5-cyclohexadien-1-ones by reacting with 2,4- and 2,6-disubstituted phenols.

General Description

1,3-Benzodithiolylium tetrafluoroborate is a carbenium ionic compound. It has been synthesized by reacting 1,3-benzodithiole with trityl tetrafluoroborate. It is widely used as an α-alkylating agent for the enantioselective α-alkylation of aldehydes., The nature of adsorption of 1,3-benzodithiolylium tetrafluoroborate on various carbon nanotubes (CNTs) has been studied. 1,3-Benzodithiolylium tetrafluoroborate reacts with different nucleophilic reagents at the 2-position to form the respective 1,3-benzodithioles.

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Isoamyl nitrite Acetic anhydride Carbon disulfide Fluoroboric acid Anthranilic acid 3-Methyl-1-butanol

Preparation Products

More

Less

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE Suppliers

Americas 1 Belgium 1 Canada 1 China 36 Europe 1 France 2 Germany 6 India 2 Japan 3 Poland 1 Spain 1 Switzerland 2 The Netherlands 1 United Kingdom 10 United States 27 Global 95

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Guangzhou Jhd Chemical Reagent Co., Ltd.

Tel: 020-84383047
Fax: 020-84380294
Email: sales@jhd.com.cn
Country: China
ProdList: 9186
Advantage: 65

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19800
Advantage: 60

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: 02557626880
Email: sales01@aikonchem.com
Country: China
ProdList: 15084
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815688 13927872512
Fax: 0751-8963795
Email: 3007421951@qq.com
Country: China
ProdList: 10057
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel: +86-18339805032; +8618339805032
Email: alfa4@alfachem.cn
Country: China
ProdList: 13227
Advantage: 58

Dideu Industries Group Limited

Tel: +86-29-89586680 +86-15129568250
Email: 1026@dideu.com
Country: China
ProdList: 22883
Advantage: 58

Hubei xin bonus chemical co. LTD

Tel: 86-13657291602
Fax: 027-59338440
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 22963
Advantage: 58

Henan Weitesi Chemical Technology Co. LTD

Tel: 0371-0371-55135753 18003832934
Fax: QQ：2853979818
Email: 2853979818@qq.com
Country: China
ProdList: 9994
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29774
Advantage: 58

Shangqiu Ladybug Network Technology Co., LTD

Tel: 0370-2059268 17530790913
Fax: 03702782809
Email: 3628320093@qq.com
Country: China
ProdList: 4206
Advantage: 58

Qiyuan (Guangdong) Pharmaceutical Chemical Co., Ltd.

Tel: 400-666-9280 18026564465
Email: 304903156@qq.com
Country: China
ProdList: 8001
Advantage: 58

Guangdong Fangxin Biotechnology Co., Ltd.

Tel: 0751-2838688 13376594225
Email: 1276075424@qq.com
Country: China
ProdList: 9933
Advantage: 58

Shanghai Haohong Scientific Co., Ltd.

Tel: 400-400-8210725
Email: malulu@leyan.com
Country: China
ProdList: 39953
Advantage: 58

ZhengZhou Edward Biology Co.,Ltd

Tel: 13298105281 13298105281
Email: 1522334715@qq.com
Country: China
ProdList: 7508
Advantage: 58

Baoji Didu Pharmaceutical and Chemical Co., Ltd

Tel: 029-81148929 13186179623
Email: 1049@dideu.com
Country: China
ProdList: 10011
Advantage: 58

Hebei Weibang Biotechnology Co., Ltd

Tel: +8615350571055
Email: Sibel@weibangbio.com
Country: China
ProdList: 6087
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6650
Advantage: 58

Beijing Yunbang Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: yunbnagbio@163.com
Country: China
ProdList: 6871
Advantage: 50

Frapp's Pharma (Hongkong) Co.,Ltd

Tel: --
Fax: --
Email: frapps2008@gmail.com
Country: China
ProdList: 1209
Advantage: 35

Binhai Hanhong Biochemical Co., Ltd

Tel: --
Fax: --
Email: 2355241815@qq.com
Country: China
ProdList: 3448
Advantage: 54

Suzhou Rovathin Foreign Trade Co.,Ltd

Tel: --
Fax: --
Email: sales@rovathin.com
Country: China
ProdList: 4395
Advantage: 58

Guangzhou WeiBo Chemical Co., Ltd.

Tel: --
Fax: --
Email: weibochem@163.com
Country: China
ProdList: 6187
Advantage: 67

Shanghai PI Chemicals Ltd.

Tel: --
Fax: --
Email: sales@pipharm.com
Country: China
ProdList: 6344
Advantage: 56

Shanghai Hanhong Chemical Co., Ltd

Tel: --
Fax: --
Email: info@hanhonggroup.com
Country: China
ProdList: 3944
Advantage: 67

Advanced Technology & Industrial Co., Ltd.

Tel: --
Fax: --
Email: sales@advtechind.com
Country: China
ProdList: 6523
Advantage: 75

Shanghai FWD Chemicals Co., Ltd.

Tel: --
Fax: --
Email: sales@fwdchem.com
Country: China
ProdList: 6927
Advantage: 58

57842-27-0, 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATERelated Search:

TRIMETHYLSULFONIUM HYDROXIDE 1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

1,3-BENZODITHIOL-2-YLIUM TETRAFLUOROBORATE

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE

1,3-Benzodithiolylium tetrafluoroborate[Hydroxyl protecting agent]

1,3-Benzodithiol-1-ium tetrafluoroborate 98%

bdtf

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE 97%

1,3-Benzolithiolylium Tetrafluoroborate

Benzo[d][1,3]dithiol-1-ium tetrafluoroborate, BDTF

1,3-Benzodithiolylium Tetrafluoroborate&nbsp

Benzo[d][1,3]dithiol-1-ium tetrafluoroborate

1,3-benzodithiol-3-ium:tetrafluoroborate

1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent]&gt

1,3-BENZODITHIOLYLIUM TETRAFLUOROBORATE USP/EP/BP

57842-27-0

C7H5S2BF4

C7H5BF4S2

S-Containing

Heterocyclic Building Blocks

Others

Protecting Agents for Hydroxyl Group (DNA/RNA Synthesis)

Sulfonium Compounds

DNA / RNA Synthesis

Sulfur Compounds (for Synthesis)

B (Classes of Boron Compounds)

Protection & Derivatization Reagents (for Synthesis)

Iodonium Sulfonium & Oxonium Compounds

Tetrafluoroborates

Building Blocks

Heterocyclic Compounds

Iodonium Sulfonium & Oxonium Compounds

Sulfonium Compounds

B (Classes of Boron Compounds)

Biochemistry

Nucleosides, Nucleotides & Related Reagents

Protecting Agents for Hydroxyl and Amino Groups

Protecting Agents, Phosphorylating Agents & Condensing Agents

Protection & Derivatization Reagents (for Synthesis)

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry

Tetrafluoroborates