ChemicalBook > CAS DataBase List > (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

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Product Name: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
CAS No.: 192139-90-5
Chemical Name: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Synonyms: RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;Chiralyst Ru637;RuCl(S,S)-Tsdpen;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro)
CBNumber: CB91569347
Molecular Formula: C31H30ClN2O2RuS
Formula Weight: 631.17
MOL File: 192139-90-5.mol

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(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Property

Melting point:: >175 °C
alpha: 178o (C=0.5 IN CHLOROFORM)
storage temp.: 2-8°C
solubility: soluble in Chloroform, DCM, Ethyl Acetate
form: solid
color: yellow to dark brown
optical activity: [α]20/D +178°, c = 0.5 in chloroform
Sensitive: air sensitive
InChI: InChI=1/C21H20N2O2S.C10H10.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-22H,1H3;8H,1-3H3;1H;/q-2;;;+3/p-1/t20-,21-;;;/s3
InChIKey: DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES: [Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 24/25
WGK Germany: 3
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 925209
Product name: Chiralyst Ru637
Purity: Umicore
Packaging: 250 mg
Price: $104
Updated: 2025/07/31

Sigma-Aldrich

Product number: 925209
Product name: Chiralyst Ru637
Purity: Umicore
Packaging: 1 g
Price: $240
Updated: 2025/07/31

Sigma-Aldrich

Product number: 703915
Product name: RuCl(p-cymene)[(S,S)-Ts-DPEN]
Packaging: 100mg
Price: $49.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: 703915
Product name: RuCl(p-cymene)[(S,S)-Ts-DPEN]
Packaging: 500mg
Price: $111.58
Updated: 2025/07/31

TCI Chemical

Product number: R0124
Product name: RuCl[(S,S)-Tsdpen](p-cymene)
Purity: >90%(HPLC)
Packaging: 200mg
Price: $55
Updated: 2025/07/31

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(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemical Properties,Usage,Production

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This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Solid

Uses

Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut

Uses

Catalyst involved in:

Asymmetric transfer hydrogenation of imines and ketones
Intramolecular asymmetric reductive amination
Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

General Description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Suppliers

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View Lastest Price from (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 500
Release date: 2025-09-11

WUHAN FORTUNA CHEMICAL CO., LTD

Product: RuCl[(S,S)-Tsdpen](p-cymene) 192139-90-5
Price: US $0.00/G
Min. Order: 50G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-08

Hangzhou ICH Biofarm Co., Ltd

Product: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200KG
Release date: 2023-06-28

192139-90-5, (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)Related Search:

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Cumene 1,2-Diphenylethane (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (P-CYMENE)RUTHENIUM(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

-1,2-diphenylethanediamine(chloro)

-N-(p-Toluenesulfonyl)

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)

RuCl(p-cymene)[(S,S)-Ts-DPEN] Chloro{[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

[(1S,2S)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide,chlororuthenium(1+),1-methyl-4-propan-2-ylbenzene

[N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-

Ruthenium,[N-[(1S,2S)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

RuCl(p-cymene)[(S,S)-Ts-DPEN]

Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

[N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p- cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%

Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)

Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II)

Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene)

[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)]

Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene)

RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore

[(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride]

RuCl[(S,S)- Tsdpen](p-cyMene)

(S,S)-N-(p-ToL

ethanediamine(chL

oro)(p-cymene)ruthenium(II)

)-1,2-diphenyL

[(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)

Chloro(p-cymene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ISO 9001：2015 REACH

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro...

[(1S,2S)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide

[((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)

RuCl[(S,S)-Tsdpen](p-cymene)/Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

((S,S)-2-Amino-1,2-Diphenylethyl)[(4-Tolyl)Sulfonyl]Amido](P-Cymene)Ruthenium (II)Chloride

N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium (ACI)

RuCl(p-cymene)[(S,S)-Ts-DPEN]

Chiralyst Ru637

RuCl(S,S)-Tsdpen

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine (p-isopropylbenzene) chloride

RuCl(p-cymene)[(S,S)-Ts-DPEN]/(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediaMine(chloro)(p-cyMene)ruthenium(II)

N-[(1S,2S)-2-(Amino-kappan)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kappan]chloro[(1,2,3,4,5,6-eta)-1-methyl-4-(1-methylethyl)-benzene]ruthenium

192139-90-5

C32H44ClN2O2RuS

organometallic complex