(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Reaction- Product Name
- (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
- CAS No.
- 192139-90-5
- Chemical Name
- (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
- Synonyms
- RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro);[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)];RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
- CBNumber
- CB91569347
- Molecular Formula
- C31H30ClN2O2RuS
- Formula Weight
- 631.17
- MOL File
- 192139-90-5.mol
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Property
- Melting point:
- >175 °C
- alpha
- 178o (C=0.5 IN CHLOROFORM)
- storage temp.
- 2-8°C
- solubility
- soluble in Chloroform, DCM, Ethyl Acetate
- form
- solid
- color
- yellow to dark brown
- optical activity
- [α]20/D +178°, c = 0.5 in chloroform
- Sensitive
- air sensitive
- InChI
- InChI=1/C21H20N2O2S.C10H10.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-22H,1H3;8H,1-3H3;1H;/q-2;;;+3/p-1/t20-,21-;;;/s3
- InChIKey
- DCJKLKCGNMDXFR-MNPNNRAMNA-M
- SMILES
- [Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 703915
- Product name
- RuCl(p-cymene)[(S,S)-Ts-DPEN]
- Packaging
- 100mg
- Price
- $48.3
- Updated
- 2024/03/01
- Product number
- 703915
- Product name
- RuCl(p-cymene)[(S,S)-Ts-DPEN]
- Packaging
- 500mg
- Price
- $136
- Updated
- 2024/03/01
- Product number
- R0124
- Product name
- RuCl[(S,S)-Tsdpen](p-cymene)
- Purity
- >90%(HPLC)
- Packaging
- 200mg
- Price
- $55
- Updated
- 2024/03/01
- Product number
- R0124
- Product name
- RuCl[(S,S)-Tsdpen](p-cymene)
- Purity
- >90%(HPLC)
- Packaging
- 1g
- Price
- $177
- Updated
- 2024/03/01
- Product number
- 44-0149
- Product name
- Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
- Packaging
- 250mg
- Price
- $53
- Updated
- 2024/03/01
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemical Properties,Usage,Production
Reaction
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
Chemical Properties
Solid
Uses
Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut
Uses
Catalyst involved in:
- Asymmetric transfer hydrogenation of imines and ketones
- Intramolecular asymmetric reductive amination
- Tandem hydroformylation / hydrogenation of terminal olefins
Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes
General Description
RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Suppliers
- Tel
- --
- Fax
- --
- sales-in@tcichemicals.com
- Country
- India
- ProdList
- 6768
- Advantage
- 58
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) manufacturers
- Product
- RuCl[(S,S)-Tsdpen](p-cymene) 192139-90-5
- Price
- US $0.00/G
- Min. Order
- 50G
- Purity
- 98%min
- Supply Ability
- 30kg/month
- Release date
- 2023-02-08
- Product
- (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2023-06-28
- Product
- (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) 192139-90-5
- Price
- US $0.00-0.00/g
- Min. Order
- 1g
- Purity
- 98%
- Supply Ability
- 500
- Release date
- 2023-02-14