ChemicalBook > CAS DataBase List > (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
- Product Name
- (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
- CAS No.
- 149341-33-3
- Chemical Name
- (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
- Synonyms
- R-QUINAR;(R)-QUINAP;(S)-QUINAP;(S)-(−(S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline;(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98%
- CBNumber
- CB9159161
- Molecular Formula
- C31H22NP
- Formula Weight
- 439.49
- MOL File
- 149341-33-3.mol
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(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Property
- Melting point:
- 220-230 °C
- Boiling point:
- 588.1±38.0 °C(Predicted)
- storage temp.
- 2-8°C
- pka
- 4.45±0.30(Predicted)
- form
- Crystalline Powder
- color
- White to off-white
- BRN
- 6664856
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Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26
- WGK Germany
- 3
- HS Code
- 29334990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 743585
- Product name
- (S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
- Purity
- ≥95.0% (qNMR)
- Packaging
- 50mg
- Price
- $190
- Updated
- 2023/01/07
Sigma-Aldrich
- Product number
- 743585
- Product name
- (S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
- Purity
- ≥95.0% (qNMR)
- Packaging
- 250mg
- Price
- $900
- Updated
- 2023/01/07
American Custom Chemicals Corporation
- Product number
- ING0001331
- Product name
- (S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
- Purity
- 95.00%
- Packaging
- 100MG
- Price
- $395.81
- Updated
- 2021/12/16
BLDpharm
- Product number
- BD433914
- Product name
- (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline
- Purity
- 98+%
- Packaging
- 1g
- Price
- $715
- Updated
- 2021/12/16
BLDpharm
- Product number
- BD433914
- Product name
- (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline
- Purity
- 98+%
- Packaging
- 250mg
- Price
- $284
- Updated
- 2021/12/16
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(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Chemical Properties,Usage,Production
Chemical Properties
white to off-white crystalline powder
Uses
(S)-QUINAP can be used as a ligand:
- In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.??????
- For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.
[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.
General Description
(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Suppliers
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149341-33-3, (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINERelated Search:
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
DIPHENYL(O-TOLYL)PHOSPHINE