Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate
- Product Name
- Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate
- CAS No.
- 117337-19-6
- Chemical Name
- Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate
- Synonyms
- kih-9201;Hsdb 7270;FLUTHIACET-METHYL;Eluthiacet-methyl;Semaglutide Impurity 9;Fluthiacet-methyl [iso];Fluthiacet-methyl Standard;Fluthiacet-methyl Solution;1000 μg/mL in Acetonitrile;fluthiacet-methyl (bsi, pa iso)
- CBNumber
- CB9232165
- Molecular Formula
- C15H15ClFN3O3S2
- Formula Weight
- 403.88
- MOL File
- 117337-19-6.mol
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate Property
- Melting point:
- 104.6°
- Boiling point:
- 503.5±60.0 °C(Predicted)
- Density
- 1.57±0.1 g/cm3(Predicted)
- storage temp.
- 0-6°C
- pka
- -2.86±0.20(Predicted)
- BRN
- 11510131
- EPA Substance Registry System
- Fluthiacet-methyl (117337-19-6)
Safety
- Hazard Codes
- Xi,N
- Risk Statements
- 36-50
- Safety Statements
- 26-61
- RIDADR
- UN 3077 9 / PGIII
- WGK Germany
- 3
- HS Code
- 29309090
- Hazardous Substances Data
- 117337-19-6(Hazardous Substances Data)
- Toxicity
- LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Miyazawa)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
H400Very toxic to aquatic life
- Precautionary statements
-
P273Avoid release to the environment.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 32464
- Product name
- Fluthiacet-methyl
- Purity
- PESTANAL
- Packaging
- 25mg
- Price
- $80.9
- Updated
- 2022/05/15
- Product number
- F599440
- Product name
- Fluthiacet-methyl
- Packaging
- 5mg
- Price
- $330
- Updated
- 2021/12/16
- Product number
- AGR0000191
- Product name
- FLUTHIACET-METHYL
- Purity
- 98.00%
- Packaging
- 0.5G
- Price
- $1276
- Updated
- 2021/12/16
- Product number
- MT-51867
- Product name
- Fluthiacet-methyl
- Purity
- 98%
- Packaging
- 0.5g
- Price
- $590
- Updated
- 2021/12/16
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate Chemical Properties,Usage,Production
Uses
Herbicide.
Definition
ChEBI: Fluthiacet-methyl is a methyl ester resulting from the formal condensation of the carboxy group of fluthiacet with methanol. A proherbicide for fluthiacet, it is used for the control of broad-leaved weeds in crops such as maize and soya. It has a role as an agrochemical, an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor and a proherbicide. It is an organic sulfide, a methyl ester, a member of monochlorobenzenes, a member of monofluorobenzenes and a thiadiazolopyridazine. It is functionally related to a fluthiacet.
Metabolic pathway
Fluthiacet methyl is converted to its isomer, urazole, by
glutathione S-transferase (GST) and glutathione (GSH)
from some plants and rat liver microsomes. Fluthiacet
methyl inhibits Protox (protoporphyrinogen oxidase)
activity after conversion to the corresponding urazole by
GST and GSH. Fluthiacet methyl is chemically
converted to urazole with a thiol anion in media by the
nucleophilic reaction. It is also suggested that a free
acid of urazole, desulfated urazole, and the oxidative
ring-cleaved formyl degradation products result from
hydrolysis with esterase from soybean seedlings.
When fluthiacet methyl is administered orally to
rats in a single dose, 63-85% of the dose is excreted
in the feces and 10-23% in the urine, respectively,
after 48 h. The main metabolite is the isomer of
fluthiacet methyl (urazole) which is also identified in
the soil degradation products. Monohydroxylated
products on the pyridazine ring are identified as
metabolites by rats only.
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate Suppliers
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