ChemicalBook > CAS DataBase List > 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester
1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester
- Product Name
- 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester
- CAS No.
- 35095-07-9
- Chemical Name
- 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester
- Synonyms
- Methyl bicyclo[4.2.0]octa-1,3;Benzocyclobutene-1-carboxylic acid methyl ester;Methyl bicyclo[4.2.0]octa-1,3,5-triene-7-carboxylate;Methyl bicyclo[4.2.0]octa-1,3,5,7-tetraene-7-carboxylate;1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester;Bicyclo[4.2.0]octa-1,3,5-triene-7-carboxylic acid methyl ester
- CBNumber
- CB92444872
- Molecular Formula
- C10H10O2
- Formula Weight
- 162.19
- MOL File
- 35095-07-9.mol
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1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester Property
- Boiling point:
- 68℃ (25 Torr)
- Density
- 1.171±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- InChI
- InChI=1S/C10H10O2/c1-12-10(11)9-6-7-4-2-3-5-8(7)9/h2-5,9H,6H2,1H3
- InChIKey
- XWGYSWFRKUQSLL-UHFFFAOYSA-N
- SMILES
- C12C(C(C(OC)=O)C1)=CC=CC=2
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N-Bromosuccinimide Price
AK Scientific
- Product number
- 5704CT
- Product name
- Methylbicyclo[4.2.0]octa-1,3,5-triene-7-carboxylate
- Packaging
- 1g
- Price
- $354
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM1049409
- Product name
- METHYL BICYCLO-[4,2,0]-OCTA-1,3,5,7-TETRAENE-7-CARBOXYLATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $500.32
- Updated
- 2021/12/16
Ambeed
- Product number
- A165798
- Product name
- Methylbicyclo[4.2.0]octa-1,3,5-triene-7-carboxylate
- Purity
- 95+%
- Packaging
- 100mg
- Price
- $25
- Updated
- 2021/12/16
Ambeed
- Product number
- A165798
- Product name
- Methylbicyclo[4.2.0]octa-1,3,5-triene-7-carboxylate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $38
- Updated
- 2021/12/16
Ambeed
- Product number
- A165798
- Product name
- Methylbicyclo[4.2.0]octa-1,3,5-triene-7-carboxylate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $82
- Updated
- 2021/12/16
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1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester Chemical Properties,Usage,Production
Synthesis
88284-48-4
292638-85-8
35095-07-9
GENERAL METHOD: A mixture of 2-(trimethylmethylsilyl)phenyl trifluoromethanesulfonate (3 mmol, 2.0 eq.), compound (CAS:292638-85-8, 1.0 eq.) and anhydrous cesium fluoride (6.0 eq.) was dissolved in dry acetonitrile (15 mL). The reaction mixture was stirred at room temperature for 12 hours. Upon completion of the reaction, 20 mL of water was added to the mixture and extracted with dichloromethane (3 x 20 mL). The organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: petroleum ether) to afford the target product methyl benzocyclobutene-1-carboxylate (3c-6c). Compound 5c: pale yellow oil.1H NMR (400 MHz, CDCl3): δ 7.26-7.24 (m, 2H), 7.18 (d, 1H, J = 4 Hz), 7.11 (d, 1H, J = 4 Hz), 4.32 (t, 1H, J = 4 Hz), 3.73 (d, 3H, J = 8 Hz), 3.48 (d, 2H, J = 4 Hz). These data are in good agreement with literature values [14].
References
[1] Chinese Chemical Letters, 2014, vol. 25, # 12, p. 1535 - 1539
1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester manufacturers
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
- Product
- 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester 35095-07-9
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-30
Shaanxi Dideu Medichem Co. Ltd
- Product
- 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester 35095-07-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-09
Career Henan Chemical Co
- Product
- 1,2-Dihydrobenzocyclobutene-1-carboxylic acid methyl ester 35095-07-9
- Price
- US $7.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2018-12-14
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