ChemicalBook > CAS DataBase List > 2-(4-BROMO-PHENYL)-THIAZOLE

2-(4-BROMO-PHENYL)-THIAZOLE

Product Name
2-(4-BROMO-PHENYL)-THIAZOLE
CAS No.
27149-27-5
Chemical Name
2-(4-BROMO-PHENYL)-THIAZOLE
Synonyms
2-(4-BROMO-PHENYL)-THIAZOLE;Thiazole, 2-(4-bromophenyl)-;2-(4-bromophenyl)-1,3-thiazole
CBNumber
CB92453515
Molecular Formula
C9H6BrNS
Formula Weight
240.12
MOL File
27149-27-5.mol
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2-(4-BROMO-PHENYL)-THIAZOLE Property

Melting point:
52-53 °C
Boiling point:
324.3±44.0 °C(Predicted)
Density 
1.563±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
1.92±0.10(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
1142AJ
Product name
2-(4-Bromophenyl)-1,3-thiazole
Packaging
100mg
Price
$95
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0069450
Product name
2-(4-BROMO-PHENYL)-THIAZOLE
Purity
97.00%
Packaging
1G
Price
$632.1
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0069450
Product name
2-(4-BROMO-PHENYL)-THIAZOLE
Purity
97.00%
Packaging
2.5G
Price
$1473.14
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0069450
Product name
2-(4-BROMO-PHENYL)-THIAZOLE
Purity
97.00%
Packaging
5G
Price
$1928.08
Updated
2021/12/16
Ambeed
Product number
A155832
Product name
2-(4-Bromophenyl)thiazole
Purity
98%
Packaging
100mg
Price
$69
Updated
2021/12/16
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2-(4-BROMO-PHENYL)-THIAZOLE Chemical Properties,Usage,Production

Synthesis

3034-53-5

589-87-7

27149-27-5

GENERAL STEPS: 2-Bromothiazole (16.4 g) was dissolved in 50 ml of THF under nitrogen protection and cooled in an ice bath. 55 ml of 2M isopropylmagnesium chloride solution in THF was slowly added dropwise while stirring. After the dropwise addition was completed, stirring of the reaction mixture was continued for 1 hour. Subsequently, zinc chloride-tetramethylethylenediamine complex (30.3 g) was added and stirred at room temperature for 1 hour. Next, 1-bromo-4-iodobenzene (28.3 g) and Pd(PPh3)4 (3.5 g) were added, heated to reflux temperature and stirred for 1.5 hours. After completion of the reaction, it was cooled to room temperature. To remove metal ions from the catalyst, about 2 times the molar amount of ethylenediaminetetraacetic acid disodium salt (EDTA-4Na) aqueous solution was added. Subsequently, the organic phase was separated by extraction with toluene and the solvent was removed by distillation under reduced pressure. Finally, the target product 2-(4-bromophenyl)thiazole (18.3 g) was purified by silica gel column chromatography (eluent: toluene/ethyl acetate = 50/1, v/v).

References

[1] Patent: KR2015/138163, 2015, A. Location in patent: Paragraph 0333; 0334

2-(4-BROMO-PHENYL)-THIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(4-BROMO-PHENYL)-THIAZOLE Suppliers

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27149-27-5, 2-(4-BROMO-PHENYL)-THIAZOLERelated Search:

2-(4-BROMOPHENYL)THIAZOLE-5-CARBALDEHYDE 2-(4-BROMO-PHENYL)-4,5,6,7-TETRAHYDRO-THIAZOLO[4,5-C]PYRIDINE 2-(4-BROMO-PHENYL)-THIAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 1-(2-BENZOTHIAZOLYL)-4-BROMOBENZENE 2-(4-BROMO-PHENYL)-THIAZOLE-4-CARBOXYLIC ACID 2-(4-BROMO-PHENYL)-THIAZOLE-4-CARBALDEHYDE C-[2-(4-BROMO-PHENYL)-THIAZOL-4-YL]-METHYLAMINE 2-(4-BROMO-PHENYL)-4,5,6,7-TETRAHYDRO-THIAZOLO[5,4-C]PYRIDINE [2-(4-BROMO-PHENYL)-THIAZOL-4-YL]-METHANOL 2-(4-BROMO-2-METHYL-PHENYL)-THIAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 2-(4-BROMO-PHENYL)-THIAZOLE-5-CARBOXYLIC ACID ETHYL ESTER 3-(1,3-BENZOTHIAZOL-2-YL)-2,6-DIBROMO-4-CHLOROANILINE 2-(4-BROMO-2-METHYL-PHENYL)-THIAZOLE-4-CARBOXYLIC ACID 2-(4-BROMO-3-METHOXY-PHENYL)-THIAZOLE-5-CARBOXYLIC ACID ETHYL ESTER 2-(4-BROMO-3-METHOXY-PHENYL)-THIAZOLE-4-CARBOXYLIC ACID 2-(4-BROMO-PHENYL)-THIAZOLE-5-CARBOXYLIC ACID 2-(4-BROMO-2-METHYL-PHENYL)-THIAZOLE-5-CARBOXYLIC ACID ETHYL ESTER 4-BROMOMETHYL-2-(4-BROMO-PHENYL)-THIAZOLE

  • 2-(4-BROMO-PHENYL)-THIAZOLE
  • Thiazole, 2-(4-bromophenyl)-
  • 2-(4-bromophenyl)-1,3-thiazole
  • 27149-27-5