ChemicalBook > CAS DataBase List > (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID

Product Name
(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID
CAS No.
684270-46-0
Chemical Name
(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID
Synonyms
FMOC-AZA-OH;Fmoc-L-Aza-OH;Fmoc-Ala(N3)-OH;Fmoc-L-Dap(N3)-OH;Fmoc-L-azidoalanin;FMOC-L-AZIDOALANINE;FMoc-β-azidoalanine;Fmoc-β-azido-Ala-OH;Fmoc-β-azidoalanine;Fmoc-L-Aza-OH (solv.)
CBNumber
CB92455726
Molecular Formula
C18H16N4O4
Formula Weight
352.35
MOL File
684270-46-0.mol
More
Less

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Property

Melting point:
>155 (dec.)
storage temp. 
2-8°C
solubility 
DMF (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Solid
color 
White to Off-White
optical activity
[α]/D -10.0±1.0°, c = 1 in DMF
InChI
InChI=1/C18H16N4O4/c19-22-20-9-16(17(23)24)21-18(25)26-10-15-13-7-3-1-5-11(13)12-6-2-4-8-14(12)15/h1-8,15-16H,9-10H2,(H,21,25)(H,23,24)/t16-/s3
InChIKey
ZITYCUDVCWLHPG-QEIABERDNA-N
SMILES
C(C1C2=CC=CC=C2C2=CC=CC=C12)OC(=O)N[C@H](C(=O)O)CN=[N+]=[N-] |&1:18,r|
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
2924297099
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
714151
Product name
Fmoc-β-azido-Ala-OH
Purity
≥98.0% (HPLC)
Packaging
250mg
Price
$456
Updated
2025/07/31
TRC
Product number
F619935
Product name
Fmoc-L-azidoalanine
Packaging
50mg
Price
$50
Updated
2021/12/16
Chem-Impex
Product number
30526
Product name
Nα-Fmoc-Nβ-Azido-L-2,3-diaminopropionicacidSolvatewithDIPE,94-100%(Assaybytitration)
Purity
94-100%(Assaybytitration)
Packaging
250MG
Price
$99.01
Updated
2021/12/16
Iris Biotech GmbH
Product number
FAA1820
Product name
Fmoc-L-Aza-OH(solv.)
Packaging
500mg
Price
$109.35
Updated
2021/12/16
Apolloscientific
Product number
BIBP1080
Product name
Fmoc-Dap(N3)
Purity
>98%
Packaging
250mg
Price
$130
Updated
2021/12/16
More
Less

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystalline powder

Uses

Fmoc-β-azido-Ala-OH chloride is a general N-terminal protected reagent used in the solid phase peptide synthesis. Azido group allows it to undergo copper-mediated click chemistry reactions.
It can be used in:

  • Synthesis of α-N-acetylgalactosamine (α-GalNAc) linked antifreeze glycopeptides (AFGPs).
  • Synthesis of stimuli-responsive multifunctional peptide gatekeepers for drug delivery applications.
  • Synthesis of triazole-linked glycopeptides via Cu(I)-catalyzed 1,3-dipolar cycloaddition (CuAAC).

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis
reaction type: click chemistry

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Suppliers

China 62 France 1 Germany 1 Japan 1 United States 10 Global 75
Adachibio Inc.
Tel
+81-8027837258; +8108027837258
Fax
0081-80278372055
Email
sales@adachibio.com
Country
Japan
ProdList
992
Advantage
58

684270-46-0, (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACIDRelated Search:

FMOC-D-DAP(Z)-OH FMOC-D-DAP(MTT)-OH FMOC-D-DAB(MTT)-OH Fmoc-HomoArg(Boc)2-OH FMOC-ARG(ME,PBF)-OH Fmoc-D-homoArg(Boc)2-OH (S,E)-12-(9H-fluoren-9-yl)-3-(methylamino)-10-oxo-11-oxa-2,4,9-triazadodec-2-ene-8-carboxylic acid L-Lysine, N6-[[[(2,3-dihydro-2,2,4,6,7-pentamethyl-5-benzofuranyl)sulfonyl]amino]iminomethyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]- FMOC-b-Ala-OH FMOC-ALA-OPFP N-Fmoc-N'-(4-methoxy-2,3,6-trimethylbenzenesulfonyl)-L-arginine Fmoc-L-Arg(Pbf)-OH Fmoc-D-Arg(Pbf)-OH FMOC-D-alanine FMOC-L-Arginine (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-4-AZIDOBUTANOIC ACID FMOC-Ala-OH (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID

  • FMOC-L-BETA-AZIDOALANINE
  • 3-Azido-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-alanine
  • Fmoc-L-Dap(N3)-OH
  • 3-Azido-N-Fmoc-L-alanine
  • Fmoc-L-Aza-OH
  • 2-(S)-Fmoc-amino-3-azidopropanoic acid
  • Nα-Fmoc-Nβ-Azido-L-2,3-diaminopropionic acidSolvate with DIPE≥ 99% (HPLC)
  • (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID
  • FMoc-beta-azido-Ala-OH >=98.0% (HPLC)
  • FMOC-AZA-OH
  • FMOC-L-AZIDOALANINE
  • (9H-Fluoren-9-yl)MethOxy]Carbonyl Dap(N3)-OH
  • 3-azido-N-Fmoc-L-ala-OH
  • FMoc-β-azidoalanine
  • (2S)-3-azido-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid
  • Fmoc-L-Aza-OH (solv.)
  • Fmoc-Ala(N3)-OH
  • FMOC-3-azido-L-alanine
  • Fmoc-beta-azido-Ala-OH
  • Fmoc-L-azidoalanin
  • (2S)-3-azido-2-(9H-fluoren-9-ylmethoxycarbonylamino)propanoicaci
  • (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID USP/EP/BP
  • Nα-Fmoc-Nβ-Azido-L-2,3-diaminopropionic acid
  • Fmoc-β-azido-Ala-OH
  • (S)-2-(9-Fluorenylmethyloxycarbonylamino)-3-azidopropanoic acid hydrochloride
  • (S)-2-(((9H-fluoren-9-yl)methoxy)carbonyl)-3-azidopropanoic acid
  • Fmoc-β-azidoalanine
  • 684270-46-0
  • Fmoc Amino Acids
  • Fmoc-Amino Acids
  • amino acids