BENZENEMETHANOL, 2-BROMO-6-NITRO-
- Product Name
- BENZENEMETHANOL, 2-BROMO-6-NITRO-
- CAS No.
- 861106-91-4
- Chemical Name
- BENZENEMETHANOL, 2-BROMO-6-NITRO-
- Synonyms
- (2-BROMO-6-NITROPHENYL)METHANOL;(2-Bromo-6-nitrophenyl);2-Bromo-6-nitrobenzyl alcohol;(2-BroMo-6-notrophenyl)Methanol;2-bromo-6-nitro benzenemethanol;2-Bromo-6-nitrobenzyl alcohol 97%;BENZENEMETHANOL, 2-BROMO-6-NITRO-
- CBNumber
- CB92464601
- Molecular Formula
- C7H6BrNO3
- Formula Weight
- 232.03
- MOL File
- 861106-91-4.mol
BENZENEMETHANOL, 2-BROMO-6-NITRO- Property
- Boiling point:
- 332.6±27.0 °C(Predicted)
- Density
- 1.767
- refractive index
- 1.633
- storage temp.
- Sealed in dry,Room Temperature
- form
- crystalline powder
- pka
- 13.36±0.10(Predicted)
- color
- Gold to faint cream
Safety
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B698033
- Product name
- (2-Bromo-6-nitrophenyl)methanol
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- B698033
- Product name
- (2-Bromo-6-nitrophenyl)methanol
- Packaging
- 10g
- Price
- $330
- Updated
- 2021/12/16
- Product number
- CS-W006110
- Product name
- (2-Bromo-6-nitrophenyl)methanol
- Packaging
- 1g
- Price
- $53
- Updated
- 2021/12/16
- Product number
- OR962824
- Product name
- 2-Bromo-6-nitrobenzylalcohol
- Purity
- 97%
- Packaging
- 1g
- Price
- $66
- Updated
- 2021/12/16
- Product number
- 4654-9-0A
- Product name
- 2-Bromo-6-nitrobenzyl alcohol
- Packaging
- 1g
- Price
- $72
- Updated
- 2021/12/16
BENZENEMETHANOL, 2-BROMO-6-NITRO- Chemical Properties,Usage,Production
Synthesis
861106-90-3
861106-91-4
General procedure for the synthesis of 2-bromo-6-nitrobenzyl ester (536 mg, 1.96 mmol) as raw material for 2-bromo-6-nitrobenzyl alcohol: 2-bromo-6-nitrobenzyl ester was dissolved in 10% aqueous acetic acid (20 mL) and 1.5 mL of acetic acid was added. The reaction mixture was heated to reflux overnight. After the reaction was completed, it was cooled to room temperature and the reaction mixture was extracted with ethyl acetate. The organic phases were combined, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give 2-bromo-6-nitrobenzenemethanol (389 mg, 86% yield) as a yellow solid.1H NMR (CDCl3, 300 MHz) δ: 4.93 (d, J = 7.43 Hz), 7.354 (t, J = 8.10 Hz), 7.84 (dd, J = 1.23 Hz, 8.17 Hz), 7.89 (dd, J = 1.22 Hz, 8.03 Hz).
References
[1] Patent: WO2005/67933, 2005, A1. Location in patent: Page/Page column 62-63
[2] Patent: US2011/288086, 2011, A1. Location in patent: Page/Page column 29-30
[3] Patent: EP2592083, 2013, A1. Location in patent: Paragraph 0264
[4] Patent: WO2014/125408, 2014, A2. Location in patent: Page/Page column 21
[5] Patent: CN108191871, 2018, A. Location in patent: Paragraph 0245; 0252-0254
BENZENEMETHANOL, 2-BROMO-6-NITRO- Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from BENZENEMETHANOL, 2-BROMO-6-NITRO- manufacturers
- Product
- BENZENEMETHANOL, 2-BROMO-6-NITRO- 861106-91-4
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99.99%
- Supply Ability
- 50000tons
- Release date
- 2023-08-18