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BENZENEMETHANOL, 2-BROMO-6-NITRO-

Product Name
BENZENEMETHANOL, 2-BROMO-6-NITRO-
CAS No.
861106-91-4
Chemical Name
BENZENEMETHANOL, 2-BROMO-6-NITRO-
Synonyms
(2-BROMO-6-NITROPHENYL)METHANOL;(2-Bromo-6-nitrophenyl);2-Bromo-6-nitrobenzyl alcohol;(2-BroMo-6-notrophenyl)Methanol;2-bromo-6-nitro benzenemethanol;2-Bromo-6-nitrobenzyl alcohol 97%;BENZENEMETHANOL, 2-BROMO-6-NITRO-
CBNumber
CB92464601
Molecular Formula
C7H6BrNO3
Formula Weight
232.03
MOL File
861106-91-4.mol
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BENZENEMETHANOL, 2-BROMO-6-NITRO- Property

Boiling point:
332.6±27.0 °C(Predicted)
Density 
1.767
refractive index 
1.633
storage temp. 
Sealed in dry,Room Temperature
form 
crystalline powder
pka
13.36±0.10(Predicted)
color 
Gold to faint cream
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Safety

HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
B698033
Product name
(2-Bromo-6-nitrophenyl)methanol
Packaging
1g
Price
$60
Updated
2021/12/16
TRC
Product number
B698033
Product name
(2-Bromo-6-nitrophenyl)methanol
Packaging
10g
Price
$330
Updated
2021/12/16
ChemScene
Product number
CS-W006110
Product name
(2-Bromo-6-nitrophenyl)methanol
Packaging
1g
Price
$53
Updated
2021/12/16
Apolloscientific
Product number
OR962824
Product name
2-Bromo-6-nitrobenzylalcohol
Purity
97%
Packaging
1g
Price
$66
Updated
2021/12/16
SynQuest Laboratories
Product number
4654-9-0A
Product name
2-Bromo-6-nitrobenzyl alcohol
Packaging
1g
Price
$72
Updated
2021/12/16
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BENZENEMETHANOL, 2-BROMO-6-NITRO- Chemical Properties,Usage,Production

Synthesis

861106-90-3

861106-91-4

General procedure for the synthesis of 2-bromo-6-nitrobenzyl ester (536 mg, 1.96 mmol) as raw material for 2-bromo-6-nitrobenzyl alcohol: 2-bromo-6-nitrobenzyl ester was dissolved in 10% aqueous acetic acid (20 mL) and 1.5 mL of acetic acid was added. The reaction mixture was heated to reflux overnight. After the reaction was completed, it was cooled to room temperature and the reaction mixture was extracted with ethyl acetate. The organic phases were combined, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give 2-bromo-6-nitrobenzenemethanol (389 mg, 86% yield) as a yellow solid.1H NMR (CDCl3, 300 MHz) δ: 4.93 (d, J = 7.43 Hz), 7.354 (t, J = 8.10 Hz), 7.84 (dd, J = 1.23 Hz, 8.17 Hz), 7.89 (dd, J = 1.22 Hz, 8.03 Hz).

References

[1] Patent: WO2005/67933, 2005, A1. Location in patent: Page/Page column 62-63
[2] Patent: US2011/288086, 2011, A1. Location in patent: Page/Page column 29-30
[3] Patent: EP2592083, 2013, A1. Location in patent: Paragraph 0264
[4] Patent: WO2014/125408, 2014, A2. Location in patent: Page/Page column 21
[5] Patent: CN108191871, 2018, A. Location in patent: Paragraph 0245; 0252-0254

BENZENEMETHANOL, 2-BROMO-6-NITRO- Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZENEMETHANOL, 2-BROMO-6-NITRO- Suppliers

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View Lastest Price from BENZENEMETHANOL, 2-BROMO-6-NITRO- manufacturers

Henan Bao Enluo International TradeCo.,LTD
Product
BENZENEMETHANOL, 2-BROMO-6-NITRO- 861106-91-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
50000tons
Release date
2023-08-18

861106-91-4, BENZENEMETHANOL, 2-BROMO-6-NITRO-Related Search:


  • (2-BROMO-6-NITROPHENYL)METHANOL
  • BENZENEMETHANOL, 2-BROMO-6-NITRO-
  • (2-BroMo-6-notrophenyl)Methanol
  • (2-Bromo-6-nitrophenyl)
  • 2-Bromo-6-nitrobenzyl alcohol
  • 2-Bromo-6-nitrobenzyl alcohol 97%
  • 2-bromo-6-nitro benzenemethanol
  • 861106-91-4