Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester
Uses- Product Name
- Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester
- CAS No.
- 147905-77-9
- Chemical Name
- Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester
- Synonyms
- Ethyl1-Methyl-4-oxocyclohexanecarboxylate;ethyl 1-methyl-4-oxocyclohexane-1-carboxylate;1-Methyl-4-oxocyclohexanecarboxylic acid ethyl ester;Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester
- CBNumber
- CB92518229
- Molecular Formula
- C10H16O3
- Formula Weight
- 184.23
- MOL File
- 147905-77-9.mol
Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester Property
- Boiling point:
- 252.9±33.0 °C(Predicted)
- Density
- 1.049±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- Appearance
- Colorless to off-white Liquid
- InChI
- InChI=1S/C10H16O3/c1-3-13-9(12)10(2)6-4-8(11)5-7-10/h3-7H2,1-2H3
- InChIKey
- GYDKHYAZKCAMAS-UHFFFAOYSA-N
- SMILES
- C1(C)(C(OCC)=O)CCC(=O)CC1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- E938828
- Product name
- Ethyl1-methyl-4-oxocyclohexanecarboxylate
- Packaging
- 50mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- E938828
- Product name
- Ethyl1-methyl-4-oxocyclohexanecarboxylate
- Packaging
- 100mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 7363AA
- Product name
- Ethyl1-methyl-4-oxocyclohexanecarboxylate
- Packaging
- 1g
- Price
- $197
- Updated
- 2021/12/16
- Product number
- 7363AA
- Product name
- Ethyl1-methyl-4-oxocyclohexanecarboxylate
- Packaging
- 5g
- Price
- $491
- Updated
- 2021/12/16
- Product number
- A298163
- Product name
- Ethyl1-methyl-4-oxocyclohexanecarboxylate
- Purity
- 97%
- Packaging
- 100mg
- Price
- $41
- Updated
- 2021/12/16
Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester Chemical Properties,Usage,Production
Uses
Ethyl 1-methyl-4-oxocyclohexanecarboxylate is a useful research chemical.
Synthesis
24730-88-9
147905-77-9
To a mixed solution of ethyl 8-methyl-1,4-dioxaspiro[4.5]decane-8-carboxylate (7.3 g, 32.0 mmol) in acetonitrile (50 mL) and water (50 mL) was added cerium ammonium nitrate (CAN, 2.11 g, 3.85 mmol). The reaction mixture was heated to 70 °C and stirred for 2 hours. After completion of the reaction, the mixture was cooled to room temperature and partitioned with ethyl acetate (50 mL) and water (50 mL). The aqueous layer was further extracted with ethyl acetate (50 mL x 2). The combined organic layers were washed with saturated brine (50 mL × 2), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford ethyl 1-methyl-4-oxocyclohexanoate (5 g, 85% yield) as a yellow oil, which was used directly in the subsequent reaction.
References
[1] Australian Journal of Chemistry, 1994, vol. 47, # 10, p. 1833 - 1841
[2] Patent: US2018/305320, 2018, A1. Location in patent: Paragraph 0228; 0231
[3] Patent: CN105566324, 2016, A. Location in patent: Paragraph 0337; 0341; 0342; 0343
[4] Patent: US2016/96841, 2016, A1. Location in patent: Paragraph 0333
[5] Patent: WO2011/2887, 2011, A1. Location in patent: Page/Page column 70-71
Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester Suppliers
- Tel
- 021-18800336901 18800336901
- muyouren139@163.com
- Country
- China
- ProdList
- 179
- Advantage
- 58
- Tel
- 13526569071
- sales@leadmedpharm.com
- Country
- China
- ProdList
- 7892
- Advantage
- 64
- Tel
- +86057186818502 13588463833
- Fax
- Pls mail us for more information!
- info@sagechem.com
- Country
- China
- ProdList
- 10266
- Advantage
- 58
- Tel
- 021-31261262/ 49 (0)17662837245
- Fax
- (0)21-33250524
- sales@novochemy.com
- Country
- Germany
- ProdList
- 6328
- Advantage
- 58
- Tel
- 021-58170097
- info@topbiochem.com
- Country
- China
- ProdList
- 9510
- Advantage
- 58
- Tel
- 18652989687
- Fax
- +86-25-52131256
- sales@norris-pharm.com
- Country
- China
- ProdList
- 8878
- Advantage
- 55
- Tel
- 0512-56316828 4008675858
- Fax
- +86-512-56316826
- sales@amateksci.com
- Country
- China
- ProdList
- 9874
- Advantage
- 55
- Tel
- 0512-62857507
- Fax
- +86-512-62857507
- sales@sinorarechem.com
- Country
- China
- ProdList
- 991
- Advantage
- 58
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 39966
- Advantage
- 60
- Tel
- 025-66028182 18626450290
- yftan@aikonchem.com
- Country
- China
- ProdList
- 16679
- Advantage
- 50
View Lastest Price from Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester manufacturers
- Product
- Cyclohexanecarboxylic acid, 1-methyl-4-oxo-, ethyl ester 147905-77-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-11