ChemicalBook > CAS DataBase List > Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Application Reaction- Product Name
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
- CAS No.
- 12131-44-1
- Chemical Name
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
- Synonyms
- Cinnamylpalladium chloride dimer;PalladiuM(II)(π-cinnaMyl) Chloride DiMer;adium(π-cinnamyL;Palladium(π-cinnamyl;Di-mu-chlorobis[(1,2,3-η;BIS[CINNAMYL PALLADIUM(II) CHLORIDE];Palladium(pi-cinnamyl) chloride dimer;Palladium(II)(2-cinnamyl) Chloride Dimer;PalladiuM(II)(pi-cinnaMyl) Chloride DiMer;PalladiuM(pi-cinnaMyl) chloride diMer 97%
- CBNumber
- CB92521021
- Molecular Formula
- C18H12Cl2Pd2
- Formula Weight
- 512.03
- MOL File
- 12131-44-1.mol
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Property
- Melting point:
- 218-220°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- yellow
- Sensitive
- air sensitive
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H318Causes serious eye damage
H331Toxic if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P284Wear respiratory protection.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 720526
- Product name
- Palladium(π-cinnamyl) chloride dimer
- Purity
- 97%
- Packaging
- 1g
- Price
- $158
- Updated
- 2024/03/01
TCI Chemical
- Product number
- P2017
- Product name
- Palladium(II)(π-cinnamyl) Chloride Dimer
- Purity
- >97.0%(T)
- Packaging
- 200mg
- Price
- $73
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 46-0295
- Product name
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98%
- Packaging
- 500mg
- Price
- $74
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 46-0295
- Product name
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(II), 98%
- Packaging
- 2g
- Price
- $224
- Updated
- 2024/03/01
TRC
- Product number
- D438900
- Product name
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium
- Packaging
- 100mg
- Price
- $70
- Updated
- 2021/12/16
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Chemical Properties,Usage,Production
Application
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.
Reaction
- Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
- Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
- Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
- Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .
Uses
Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
- Ammonia cross-coupling reactions to synthesize arylamines.
- Conversion of aryl triflates to fluorides.
It can also be used as a source of palladium in the asymmetric α-arylation of amides.
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
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View Lastest Price from Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-16
henan kanbei chemical co.,ltd
- Product
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
Longyan Tianhua Biological Technology Co., Ltd
- Product
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) 12131-44-1
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-10
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