Reaction
ChemicalBook > CAS DataBase List > TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Reaction
Product Name
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
CAS No.
64443-05-6
Chemical Name
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Synonyms
tetrakis(acetonitrile)copper(I);e)copper(I) hexafL;acetonitrile,copper(1+),hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophos;tetrakis(acetonitrile)copper hexa-fluorophosph;tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Cuprous tetrakis(acetonitrile) hexafluorophosphate;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
CBNumber
CB9262957
Molecular Formula
C8H12CuF6N4P
Formula Weight
372.72
MOL File
64443-05-6.mol
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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Property

Melting point:
160 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
solid
color 
white to light blue
Sensitive 
air sensitive, moisture sensitive
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
346276
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity
97%
Packaging
5g
Price
$71.1
Updated
2024/03/01
Sigma-Aldrich
Product number
346276
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity
97%
Packaging
25g
Price
$337
Updated
2024/03/01
TCI Chemical
Product number
T2665
Product name
Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
Purity
>97.0%(T)
Packaging
5g
Price
$43
Updated
2024/03/01
Strem Chemicals
Product number
29-6700
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging
5g
Price
$94
Updated
2024/03/01
Strem Chemicals
Product number
29-6700
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging
25g
Price
$368
Updated
2024/03/01
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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Reaction

  1. Useful catalyst for the Ullmann synthesis.
  2. Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
  3. Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.

Uses

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Suppliers

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64443-05-6, TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATERelated Search:


  • tetrakis(acetonitrile)copper(I) hexa-fluorophosph
  • Tetrakis(acetonitrle)copper(I) Hexafluorophosphate
  • Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
  • Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%
  • tetrakis(acetonitrile)copper(I)
  • tetrakis(acetonitrile)copper hexa-fluorophosph
  • Tetrakis(acetonitrile)copper [] hexafluorophosphate
  • acetonitrile,copper(1+),hexafluorophosphate
  • Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%
  • Copper(I) tetrakis(acetonitrile) hexafluorophosphate
  • Cuprous tetrakis(acetonitrile) hexafluorophosphate
  • Copper(1+), tetrakis(acetonitrile)-, (T-4)-, hexafluorophosphate(1-)
  • TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
  • Tetrakis(acetonitrile)copper(I)hexafluorophos
  • e)copper(I) hexafL
  • TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE ISO 9001:2015 REACH
  • Tetrakis(acetonitrile)Copper (I) hexafluorophasphate
  • 64443-05-6
  • C8H12CuF6N4P
  • CH3CN4CuPF6
  • 4C2H3NCuF6P
  • Catalysis and Inorganic Chemistry
  • organometallic complex
  • Cu
  • Copper
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis