TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

ChemicalBook > CAS DataBase List > TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Reaction

Product Name: TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
CAS No.: 64443-05-6
Chemical Name: TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Synonyms: tetrakis(acetonitrile)copper(I);e)copper(I) hexafL;acetonitrile,copper(1+),hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophos;tetrakis(acetonitrile)copper hexa-fluorophosph;tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Cuprous tetrakis(acetonitrile) hexafluorophosphate;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
CBNumber: CB9262957
Molecular Formula: C8H12CuF6N4P
Formula Weight: 372.72
MOL File: 64443-05-6.mol

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Property

Melting point:: 160 °C (dec.) (lit.)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: solid
color: white to light blue
Sensitive: air sensitive, moisture sensitive

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 346276
Product name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity: 97%
Packaging: 5g
Price: $71.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 346276
Product name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity: 97%
Packaging: 25g
Price: $337
Updated: 2024/03/01

TCI Chemical

Product number: T2665
Product name: Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
Purity: >97.0%(T)
Packaging: 5g
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 29-6700
Product name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging: 5g
Price: $94
Updated: 2024/03/01

Strem Chemicals

Product number: 29-6700
Product name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging: 25g
Price: $368
Updated: 2024/03/01

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Reaction

Useful catalyst for the Ullmann synthesis.
Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.

Uses

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

For the formation of Cu₂S/CdS nanorod junctions by cationic exchange process.
To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF₆]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
For the synthesis of [Cu(NHC)₂]PF₆ complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Suppliers

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64443-05-6, TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATERelated Search:

Trisodium hexafluoroaluminate Lithium hexafluorophosphate Silver hexafluoroantimonate Ammonium hexafluorophosphate BARIUM HEXAFLUOROACETYLACETONATE CALCIUM HEXAFLUOROACETYLACETONATE DIHYDRATE PRASEODYMIUM HEXAFLUOROACETYLACETONATE ZINC HEXAFLUOROACETYLACETONATE DIHYDRATE CHROMIUM (III) HEXAFLUOROACETYLACETONATE Bis(hexafluoroacetylacetonato)magnesium LEAD (II) HEXAFLUOROACETYLACETONATE NEODYMIUM HEXAFLUOROPENTANEDIONATE, DIHYDRATE COPPER(I) HEXAFLUORO-2,4-PENTANEDIONATE-CYCLOOCTADIENE COMPLEX YTTRIUM HEXAFLUOROACETYLACETONATE ALUMINUM HEXAFLUORO-2,4-PENTANEDIONATE Copper TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE COPPER PHOSPHORUS

tetrakis(acetonitrile)copper(I) hexa-fluorophosph

Tetrakis(acetonitrle)copper(I) Hexafluorophosphate

Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate

Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%

tetrakis(acetonitrile)copper(I)

tetrakis(acetonitrile)copper hexa-fluorophosph

Tetrakis(acetonitrile)copper [] hexafluorophosphate

acetonitrile,copper(1+),hexafluorophosphate

Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%

Copper(I) tetrakis(acetonitrile) hexafluorophosphate

Cuprous tetrakis(acetonitrile) hexafluorophosphate

Copper(1+), tetrakis(acetonitrile)-, (T-4)-, hexafluorophosphate(1-)

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Tetrakis(acetonitrile)copper(I)hexafluorophos

e)copper(I) hexafL

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH

64443-05-6

C8H12CuF6N4P

CH3CN4CuPF6

4C2H3NCuF6P

Catalysis and Inorganic Chemistry

organometallic complex

Copper

Catalysis and Inorganic Chemistry

Chemical Synthesis