TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Reaction- Product Name
- TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
- CAS No.
- 64443-05-6
- Chemical Name
- TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
- Synonyms
- tetrakis(acetonitrile)copper(I);e)copper(I) hexafL;acetonitrile,copper(1+),hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophos;tetrakis(acetonitrile)copper hexa-fluorophosph;tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Cuprous tetrakis(acetonitrile) hexafluorophosphate;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
- CBNumber
- CB9262957
- Molecular Formula
- C8H12CuF6N4P
- Formula Weight
- 372.72
- MOL File
- 64443-05-6.mol
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Property
- Melting point:
- 160 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- form
- solid
- color
- white to light blue
- Sensitive
- air sensitive, moisture sensitive
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 346276
- Product name
- Tetrakis(acetonitrile)copper(I) hexafluorophosphate
- Purity
- 97%
- Packaging
- 5g
- Price
- $71.1
- Updated
- 2024/03/01
- Product number
- 346276
- Product name
- Tetrakis(acetonitrile)copper(I) hexafluorophosphate
- Purity
- 97%
- Packaging
- 25g
- Price
- $337
- Updated
- 2024/03/01
- Product number
- T2665
- Product name
- Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $43
- Updated
- 2024/03/01
- Product number
- 29-6700
- Product name
- Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
- Packaging
- 5g
- Price
- $94
- Updated
- 2024/03/01
- Product number
- 29-6700
- Product name
- Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
- Packaging
- 25g
- Price
- $368
- Updated
- 2024/03/01
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production
Reaction
- Useful catalyst for the Ullmann synthesis.
- Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
- Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.
Uses
Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
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