Reaction
ChemicalBook > CAS DataBase List > TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

Reaction
Product Name
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
CAS No.
64443-05-6
Chemical Name
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Synonyms
tetrakis(acetonitrile)copper(I);e)copper(I) hexafL;acetonitrile,copper(1+),hexafluorophosphate;Tetrakis(acetonitrile)copper(I)hexafluorophos;tetrakis(acetonitrile)copper hexa-fluorophosph;tetrakis(acetonitrile)copper(I) hexa-fluorophosph;Cuprous tetrakis(acetonitrile) hexafluorophosphate;Tetrakis(acetonitrle)copper(I) Hexafluorophosphate;Tetrakis(acetonitrile)copper [] hexafluorophosphate;Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
CBNumber
CB9262957
Molecular Formula
C8H12CuF6N4P
Formula Weight
372.72
MOL File
64443-05-6.mol
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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Property

Melting point:
160 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
solid
color 
white to light blue
Sensitive 
air sensitive, moisture sensitive
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
346276
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity
97%
Packaging
5g
Price
$71.1
Updated
2024/03/01
Sigma-Aldrich
Product number
346276
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Purity
97%
Packaging
25g
Price
$337
Updated
2024/03/01
TCI Chemical
Product number
T2665
Product name
Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
Purity
>97.0%(T)
Packaging
5g
Price
$43
Updated
2024/03/01
Strem Chemicals
Product number
29-6700
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging
5g
Price
$94
Updated
2024/03/01
Strem Chemicals
Product number
29-6700
Product name
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 98+%
Packaging
25g
Price
$368
Updated
2024/03/01
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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Reaction

  1. Useful catalyst for the Ullmann synthesis.
  2. Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
  3. Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.

Uses

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Suppliers

China 98 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 2 United States 15 Global 121

64443-05-6, TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATERelated Search:

Trisodium hexafluoroaluminate Lithium hexafluorophosphate Silver hexafluoroantimonate Ammonium hexafluorophosphate BARIUM HEXAFLUOROACETYLACETONATE CALCIUM HEXAFLUOROACETYLACETONATE DIHYDRATE PRASEODYMIUM HEXAFLUOROACETYLACETONATE ZINC HEXAFLUOROACETYLACETONATE DIHYDRATE CHROMIUM (III) HEXAFLUOROACETYLACETONATE Bis(hexafluoroacetylacetonato)magnesium LEAD (II) HEXAFLUOROACETYLACETONATE NEODYMIUM HEXAFLUOROPENTANEDIONATE, DIHYDRATE COPPER(I) HEXAFLUORO-2,4-PENTANEDIONATE-CYCLOOCTADIENE COMPLEX YTTRIUM HEXAFLUOROACETYLACETONATE ALUMINUM HEXAFLUORO-2,4-PENTANEDIONATE Copper TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE COPPER PHOSPHORUS

  • tetrakis(acetonitrile)copper(I) hexa-fluorophosph
  • Tetrakis(acetonitrle)copper(I) Hexafluorophosphate
  • Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
  • Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%
  • tetrakis(acetonitrile)copper(I)
  • tetrakis(acetonitrile)copper hexa-fluorophosph
  • Tetrakis(acetonitrile)copper [] hexafluorophosphate
  • acetonitrile,copper(1+),hexafluorophosphate
  • Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%
  • Copper(I) tetrakis(acetonitrile) hexafluorophosphate
  • Cuprous tetrakis(acetonitrile) hexafluorophosphate
  • Copper(1+), tetrakis(acetonitrile)-, (T-4)-, hexafluorophosphate(1-)
  • TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
  • Tetrakis(acetonitrile)copper(I)hexafluorophos
  • e)copper(I) hexafL
  • TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH
  • 64443-05-6
  • C8H12CuF6N4P
  • CH3CN4CuPF6
  • 4C2H3NCuF6P
  • Catalysis and Inorganic Chemistry
  • organometallic complex
  • Cu
  • Copper
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis