(chlorodifluoroMethyl)triMethylsilane
- Product Name
- (chlorodifluoroMethyl)triMethylsilane
- CAS No.
- 115262-00-5
- Chemical Name
- (chlorodifluoroMethyl)triMethylsilane
- Synonyms
- Chlordifluormethyltrimethylsilan;(chlorodifluoroMethyl)triMethylsilane;Silane, (chlorodifluoromethyl)trimethyl-
- CBNumber
- CB92644986
- Molecular Formula
- C4H9ClF2Si
- Formula Weight
- 158.65
- MOL File
- 115262-00-5.mol
(chlorodifluoroMethyl)triMethylsilane Property
- Boiling point:
- 90.0±40.0 °C(Predicted)
- Density
- 1.039±0.06 g/cm3(Predicted)
- form
- liquid
- color
- colorless
N-Bromosuccinimide Price
- Product number
- JK1578319
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Purity
- 98%
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 50mg
- Price
- $80
- Updated
- 2021/12/16
- Product number
- 300936
- Product name
- (Chlorodifluoromethyl)trimethylsilane, 97%
- Packaging
- 1g
- Price
- $104.5
- Updated
- 2021/12/16
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 100mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 250mg
- Price
- $200
- Updated
- 2021/12/16
(chlorodifluoroMethyl)triMethylsilane Chemical Properties,Usage,Production
Uses
(Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry.
Uses
(chlorodifluoroMethyl)triMethylsilane，also known as Hu reagent，it can be used to generate difluorocarbene at higher temperatures catalyzed by chloride ion.
Reactions
(1) Difluoromethylenation of alkenes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(2) Difluoromethylenation of alkynes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(3) Difluoromethylenation of TMSCN.
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(4) Difluoromethylenation of benzyl and alkylzinc halides.
Ref. Org. Lett. 2013, 15, 917 – 919.
(5) Fluorination aminocarbonylation of aldehydes
Ref. Angew. Chem. Int. Ed. 2022, e202115467
References
[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
(chlorodifluoroMethyl)triMethylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
(chlorodifluoroMethyl)triMethylsilane Suppliers
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View Lastest Price from (chlorodifluoroMethyl)triMethylsilane manufacturers
- Product
- (chlorodifluoroMethyl)triMethylsilane 115262-00-5
- Price
- US $0.10/kg
- Min. Order
- 0.004999999888241291kg
- Purity
- 99.99%
- Supply Ability
- 20 tons
- Release date
- 2024-04-15
- Product
- (chlorodifluoroMethyl)triMethylsilane 115262-00-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- [Chloro(difluoro)methyl](trimethyl)silane 115262-00-5
- Price
- US $9.80/KG
- Min. Order
- 1KG
- Purity
- ＞98%HPLC
- Supply Ability
- 20 tons
- Release date
- 2020-02-06