Carboxin

ChemicalBook > CAS DataBase List > Carboxin

Product Name: Carboxin
CAS No.: 5234-68-4
Chemical Name: Carboxin
Synonyms: v4x;d735;Dmoc;f735;DCMO;d-735;f 735;d 735;Kisvax;OXATIN
CBNumber: CB9267538
Molecular Formula: C12H13NO2S
Formula Weight: 235.3
MOL File: 5234-68-4.mol

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Carboxin Property

Melting point:: 91.1-91.7°C
Boiling point:: 420.6±45.0 °C(Predicted)
Density: 1.45
vapor pressure: 2.5 x 10^-5 Pa (25 °C)
refractive index: 1.6000 (estimate)
Flash point:: 100 °C
storage temp.: Sealed in dry,2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 14.31±0.70(Predicted)
form: Crystals
color: White
Water Solubility: 10.095 g/100 mL
Merck: 13,1837
BRN: 983249
LogP: 2.140
NIST Chemistry Reference: Carboxin(5234-68-4)
EPA Substance Registry System: Carboxin (5234-68-4)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 21/22-36/37/38-20/21/22
Safety Statements: 36-26
RIDADR: UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.)
WGK Germany: 3
RTECS: RP4550000
HS Code: 29349990
Hazardous Substances Data: 5234-68-4(Hazardous Substances Data)
Toxicity: LD50 in rats, mice (mg/kg): 430, 3200 orally (Dyadicheva)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45371
Product name: Carboxine
Purity: PESTANAL
Packaging: 250mg
Price: $32.4
Updated: 2024/03/01

TCI Chemical

Product number: C3482
Product name: Carboxin
Packaging: 5G
Price: $230
Updated: 2024/03/01

TCI Chemical

Product number: C3482
Product name: Carboxin
Packaging: 25G
Price: $793
Updated: 2024/03/01

TRC

Product number: C177730
Product name: Carboxine
Packaging: 25g
Price: $645
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: PST0000018
Product name: CARBOXIN
Purity: 95.00%
Packaging: 1G
Price: $679.14
Updated: 2021/12/16

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Carboxin Chemical Properties,Usage,Production

Description

Carboxin is a white crystalline solid.Molecular weight=235.32; Freezing/Meltingpoint=91.5-95℃ (depending on crystal structure); Vaporpressure=1.78 x 10 2 7 mmHg. Practically insoluble inwater; solubility=25 mg/L; 0.15 g/L at 20℃.

Chemical Properties

Carboxin is a white crystalline solid

Uses

Carboxine is an fungicide used for the control of fruit rot of custard apple.

Uses

Systemic plant fungicide.

Uses

Carboxin is used as a seed treatment for cereals and as a seedling treatment on many cereals, beans, and vegetable crops and cotton. It is also used for the treatment of turf.

Definition

ChEBI: An anilide obtained by formal condensation of the amino group of aniline with the carboxy group of 2-methyl-5,6-dihydro-1,4-oxathiine-3-carboxylic acid. A fungicide for control of bunts and smuts normally that is normally used as a seed treatment.

General Description

Off-white crystals. Systemic fungicide and seed protectant.

Agricultural Uses

Fungicide: Carboxin is a General Use Pesticide (GUP) and is used as a seed protectant. It is often used in combination with other fungicides such as thiram or captan. Carboxin is a systemic anilide fungicide. It is used as a seed treatment for control of smut, rot, and blight on barley, oats, rice, cotton, vegetables, corn and wheat. It is also used to control fairy rings on turf grass. Carboxin may be used to prevent the formation of these diseases or may be used to cure existing plant diseases. Also used as a wood preservative.

Trade name

CADAN®; CARBOXIN OXATHION PESTICIDE®; CASWELL No. 165 A®; D-735®; F-735®; FLO PRO V SEED PROTECTANT®[C]; KEMIKAR®; OXALIN®; PADAN®; SANVEX®; THIOBEL®; VEGETOX®; VITAFLO®; VITAVAX® 200FF; V 4X®

Safety Profile

Poison by ingestion. Moderately toxic by skin contact and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Potential Exposure

A potential danger to those involved in the production, Formulation and application of this systemic fungicide, seed protectant and wood preservative

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. The sulfoxidation of carboxin to carboxin sulfoxide by the fungus Ustilago maydis was reported by Bollag and Liu (1990).
Soil. Carboxin oxidized in soil forming carboxin sulfoxide. The half-life in soil was reported to be 24 hours (Worthing and Hance, 1991).
Plant. In plants (barley, cotton and wheat) and water, carboxin oxidizes to the corresponding sulfoxide (Worthing and Hance, 1991).

Metabolic pathway

Carboxin is a systemic fungicide which is very stable to hydrolysis but is readily oxidised at sulfur to a sulfoxide and a sulfone. The latter, oxycarboxin, is itself a commercial fungicide. Metabolism is mainly by oxidation at sulfur in soil, plants and animals but hydroxylation of the phenyl ring is also important in animals. Hydrolysis has been convincingly demonstrated only in plants (peanut).

storage

Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with carboxin youshould be trained on its proper handling and storage. Storein tightly closed containers in a cool, well-ventilated area

Shipping

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Degradation

Carboxin is stable to hydrolysis (25 °C) at pH 5,7 and 9. Measurable rates are seen only at higher pH and occur by nucleophilic attack by hydroxyl ion at carbonyl. The half-life in 0.5 N NaOH is 107 days. Thus chemical hydrolysis is not expected to be significant under environmental conditions (El-Dib and Aly, 1976).
The compound is very labile to aqueous photolysis with a DT₅₀ of <3 hours (PM).

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Avoid heat and humidity. Thermal decomposition products may include cyanide gas and cyanide salts.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Carboxin Preparation Products And Raw materials

Raw materials

Acetoacetanilide 2-CHLORO-3-OXO-N-PHENYLBUTANAMIDE Sulfuryl chloride PARA TOLUENE Ethanol 95% 2-Mercaptoethanol

Preparation Products

OXYCARBOXIN

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View Lastest Price from Carboxin manufacturers

Longyan Tianhua Biological Technology Co., Ltd

Product: Carboxin 5234-68-4
Price: US $185.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 1000KG
Release date: 2020-11-17

Nanjing Liskon Biological Technology Co., Ltd

Product: Carboxin 5234-68-4
Price: US $0.00-0.00/Kg/Bag
Min. Order: 25KG
Purity: 98%
Supply Ability: 100tons
Release date: 2021-06-30

Career Henan Chemical Co

Product: Vitavax 5234-68-4
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-20

5234-68-4, CarboxinRelated Search:

Triadimefon Tebuconazole Cymoxanil Metalaxyl manganese zinc ETHYL VINYL SULFIDE Carboxin Dioxide of vitavax,Vitavax sulfone 2-[(2-AMINOETHYL)THIO]ETHAN-1-OL BUTOCARBOXIM 2-MERCAPTOACETANILIDE Carboxin W.P. Carboxin+Thiram,W.P. Imidacloprid+Thiram+Carboxin,seed coating

1,4-Oxathiin, 2,3-dihydro-5-carboxanilido-6-methyl-

1,4-Oxathiin-3-carboxamide, 5,6-dihydro-2-methyl-N-phenyl-

1,4-oxathiin-3-carboxamide,5,6-dihydro-2-methyl-n-phenyl

1,4-Oxathiin-3-carboxanilide, 5,6-dihydro-2-methyl-

1,4-oxathiin-3-carboxanilide,5,6-dihydro-2-methyl-

2,3-Dihydro-5-carboxanilido-6-methyl-1,4-oxathiin

d735

d-735

Dmoc

dualmurganicrpb

enhance

enhanceplus

f 735

f735

Flo pro v seed protectant

floprovseedprotectant

germateplus

Kisvax

mist-o-maticmurganic

murganic

pro-gro

rtvvitavax

v4x

Vitaflo 250

vitaflo250

vitaflow

Vitavax 100

Vitavax 735d

Vitavax 75w

vitavax100

vitavax-200

vitavax-300

vitavax30-c.

VITAVAX(R)

Vitavax(Uniroyal)

CARBOXIN PESTANAL (5,6-DIHYDRO- 2-METHYL

CARBOXIN, 1GM, NEAT

CARBOXIN (5,6-DIHYDRO-2-METHYL-N-PHENYL-1,4-OXATHIIN-3-CARBOXAMIDE)

5,6-Dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-caboxamide

carbathiine

carboxin (bsi,iso,ansi)

5,6-dihydro-2-methyl-1,4-oxathiin- 3-carbonic acid, anilide

2,3-DIHYDRO-5-CARBOXANILINO-6-METHYL-1,4-OXATHIIN

VITAVAXEC200

1,4-OXANTHIIN-3-CARBOXAMIDE,5,6-DIHYDRO-2-METHYL-N-PHENYL-

Fenoxan

Carboxin Standard

6-methyl-N-phenyl-2,3-dihydro-1,4-oxathiine-5-carboxamide

Carboxin 1g [5234-68-4]

Carboxine Standard

Carboxin Solution, 1000ppm

Vitavax-D5

2,3-dihydro-5-carboxanilido-6-methyl-4-oxathiin

2,3-Dihydro-6-methyl-1,4-oxathiin-5-carboxanilide

2,3-dihydro-6-methyl-1,4-oxathiine-5-carboxylicacidanilide

2,3-dihydro-6-methyl-5-phenylcarbamoyl-1,4-oxathiin

2-Methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide

5,6-Dihydro-2-methyl-3-carboxanilido-1,4-oxathiin