DI-O-TOLYLCHLOROPHOSPHINE

Product Name: DI-O-TOLYLCHLOROPHOSPHINE
CAS No.: 36042-94-1
Chemical Name: DI-O-TOLYLCHLOROPHOSPHINE
Synonyms: DI-O-TOLYLCHLOROPHOSPHINE;CHLORODI(O-TOLYL)PHOSPHINE;DI(2-TOLYL)CHLOROPHOSPHINE;BIS(O-TOLYL)CHLOROPHOSPHINE;Chlorobis(o-tolyl)phosphine;Di-(o-tolyl)phosphinchlorid;Di-o-tolylphosphinouschloride;Di-o-tolylchlorophosphine,min.98%;Chlorodi(o-tolyl)phosphine;Di-tert-methoxyphosphorophosphine
CBNumber: CB9268025
Molecular Formula: C14H14ClP
Formula Weight: 248.69
MOL File: 36042-94-1.mol

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DI-O-TOLYLCHLOROPHOSPHINE Property

Melting point:: 57°C
Boiling point:: 174-178°C/3mm
Flash point:: 174-178°C/3mm
storage temp.: 2-8°C
form: liquid
color: white to yellow
Water Solubility: Not miscible or difficult to mix in water.
Sensitive: Moisture Sensitive
InChI: InChI=1S/C14H14ClP/c1-11-7-3-5-9-13(11)16(15)14-10-6-4-8-12(14)2/h3-10H,1-2H3
InChIKey: KAAGXBGJRWFWPT-UHFFFAOYSA-N
SMILES: P(C1=CC=CC=C1C)(C1=CC=CC=C1C)Cl

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Safety

Hazard Codes: F,C
Risk Statements: 17-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2845 4.2/PG 1
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
Storage Class: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Skin Corr. 1B

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 686697
Product name: Chlorodi(o-tolyl)phosphine
Packaging: 1g
Price: $102
Updated: 2026/04/30

Sigma-Aldrich

Product number: 686697
Product name: Chlorodi(o-tolyl)phosphine
Packaging: 5g
Price: $263
Updated: 2025/07/31

Strem Chemicals

Product number: 15-1815
Product name: Di-o-tolylchlorophosphine, min. 98%
Purity: min.98%
Packaging: 1g
Price: $82
Updated: 2026/04/30

Strem Chemicals

Product number: 15-1815
Product name: Di-o-tolylchlorophosphine, min. 98%
Purity: min.98%
Packaging: 5g
Price: $282
Updated: 2026/04/30

Strem Chemicals

Product number: 15-1815
Product name: Di-o-tolylchlorophosphine, min. 98%
Packaging: 1g
Price: $80
Updated: 2024/03/01

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DI-O-TOLYLCHLOROPHOSPHINE Chemical Properties,Usage,Production

Uses

Chlorodi(o-tolyl)phosphine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Purification Methods

It is purified by fractional distillation in a vacuum (b 179-183o/7mm, 253-257o/15mm,) and the distillate solidifies (m 36o, also reported is m 37o). [Weinberg J Org chem. 40 3586 1975, McEwen et al. J Am Chem Soc 100 7304 1978, Beilstein 16 H 769, 16 IV 970 for chlorodi(p-tolyl)phosphine.]

DI-O-TOLYLCHLOROPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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DI-O-TOLYLCHLOROPHOSPHINE Suppliers

China 63 Germany 2 Japan 1 Russia 1 Switzerland 1 United Kingdom 2 United States 8 Global 78

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 268
Advantage: 64

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44802
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12984
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Shanghai Xingui Biotechnology Co., Ltd.

Tel: 15121041756
Email: xingui2022@126.com
Country: China
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Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Shanghai Qiao Chemical Science Co., Ltd

Tel: 021-58892003 18601689453;
Email: info@qiaochem.com
Country: China
ProdList: 6071
Advantage: 65

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View Lastest Price from DI-O-TOLYLCHLOROPHOSPHINE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Di(o-tolyl)chlorophosphine 36042-94-1
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Career Henan Chemical Co

Product: DI-O-TOLYLCHLOROPHOSPHINE 36042-94-1
Price: US $1.00/KG
Min. Order: 1IU
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-02

36042-94-1, DI-O-TOLYLCHLOROPHOSPHINERelated Search:

METHYLPHENYLPHOSPHINIC CHLORIDE DI-P-TOLYLPHOSPHINE METHYLPHENYLCHLOROPHOSPHINE BIS(O-TOLYL)PHOSPHINE Chlorodiphenylphosphine DI-O-TOLYLCHLOROPHOSPHINE

Bis(2-methylphenyl)phosphinous chloride, Chlorobis(2-methylphenyl)phosphine

Di-o-tolylchlorophosphine, min. 98%

Chlorobis(o-tolyl)phosphine

Di(o-methylphenyl)phosphine chloride

BIS(O-TOLYL)CHLOROPHOSPHINE

BIS(2-METHYLPHENYL)PHOSPHINOUS CHLORIDE

DI(2-TOLYL)CHLOROPHOSPHINE

DI-O-TOLYLCHLOROPHOSPHINE

CHLORODI(O-TOLYL)PHOSPHINE

CHLOROBIS(2-METHYLPHENYL)PHOSPHINE

Di-(o-tolyl)phosphinchlorid

Di-o-tolylchlorophosphine,min.98%

chloro-bis(2-methylphenyl)phosphane

Phosphinous chloride, P,P-bis(2-methylphenyl)-

Chlorodi(<i>o</i>-tolyl)phosphine

Di-o-tolylphosphinouschloride

Di-tert-methoxyphosphorophosphine

Bis(2-methylphenyl)chlorophosphine

36042-94-1

CH3C6H42PCl

C14H14ClP

Catalysis and Inorganic Chemistry

Phosphorus Precursors

Phosphorus Compounds

organophosphine halide