ChemicalBook > CAS DataBase List > DI-O-TOLYLCHLOROPHOSPHINE

DI-O-TOLYLCHLOROPHOSPHINE

Product Name: DI-O-TOLYLCHLOROPHOSPHINE
CAS No.: 36042-94-1
Chemical Name: DI-O-TOLYLCHLOROPHOSPHINE
Synonyms: DI-O-TOLYLCHLOROPHOSPHINE;CHLORODI(O-TOLYL)PHOSPHINE;DI(2-TOLYL)CHLOROPHOSPHINE;BIS(O-TOLYL)CHLOROPHOSPHINE;Chlorobis(o-tolyl)phosphine;Di-(o-tolyl)phosphinchlorid;Di-o-tolylphosphinouschloride;Di-o-tolylchlorophosphine,min.98%;Chlorodi(o-tolyl)phosphine;Di-tert-methoxyphosphorophosphine
CBNumber: CB9268025
Molecular Formula: C14H14ClP
Formula Weight: 248.69
MOL File: 36042-94-1.mol

Less

DI-O-TOLYLCHLOROPHOSPHINE Property

Melting point:: 57°C
Boiling point:: 174-178°C/3mm
Flash point:: 174-178°C/3mm
storage temp.: 2-8°C
form: liquid
color: white to yellow
Water Solubility: Not miscible or difficult to mix in water.
Sensitive: Moisture Sensitive
InChI: InChI=1S/C14H14ClP/c1-11-7-3-5-9-13(11)16(15)14-10-6-4-8-12(14)2/h3-10H,1-2H3
InChIKey: KAAGXBGJRWFWPT-UHFFFAOYSA-N
SMILES: P(C1=CC=CC=C1C)(C1=CC=CC=C1C)Cl

Less

Safety

Hazard Codes: F,C
Risk Statements: 17-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2845 4.2/PG 1
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 686697
Product name: Chlorodi(o-tolyl)phosphine
Packaging: 1g
Price: $96.1
Updated: 2025/07/31

Sigma-Aldrich

Product number: 686697
Product name: Chlorodi(o-tolyl)phosphine
Packaging: 5g
Price: $263
Updated: 2025/07/31

Strem Chemicals

Product number: 15-1815
Product name: Di-o-tolylchlorophosphine, min. 98%
Packaging: 1g
Price: $80
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1815
Product name: Di-o-tolylchlorophosphine, min. 98%
Packaging: 5g
Price: $276
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FD149765
Product name: Di(o-tolyl)chlorophosphine
Packaging: 1g
Price: $74
Updated: 2021/12/16

Less

DI-O-TOLYLCHLOROPHOSPHINE Chemical Properties,Usage,Production

Uses

Chlorodi(o-tolyl)phosphine is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Purification Methods

It is purified by fractional distillation in a vacuum (b 179-183o/7mm, 253-257o/15mm,) and the distillate solidifies (m 36o, also reported is m 37o). [Weinberg J Org chem. 40 3586 1975, McEwen et al. J Am Chem Soc 100 7304 1978, Beilstein 16 H 769, 16 IV 970 for chlorodi(p-tolyl)phosphine.]

DI-O-TOLYLCHLOROPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

DI-O-TOLYLCHLOROPHOSPHINE Suppliers

China 63 Germany 2 Japan 1 Russia 1 Switzerland 1 United Kingdom 2 United States 8 Global 78

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 263
Advantage: 64

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12984
Advantage: 57

Shanghai Xingui Biotechnology Co., Ltd.

Tel: 15121041756
Email: xingui2022@126.com
Country: China
ProdList: 9986
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Shanghai Qiao Chemical Science Co., Ltd

Tel: 021-58892003
Email: info@qiaochem.com
Country: China
ProdList: 6059
Advantage: 65

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 976
Advantage: 55

Zhengzhou AnMusi Chemical Products Co., Ltd.

Tel: 0371-55289822 18737195735
Fax: QQ：2370407954
Email: 2370407954@qq.com
Country: China
ProdList: 1981
Advantage: 55

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2280
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Henan Alpha Chemical Co., Ltd.

Tel: 0371-55055611 18137792234
Fax: QQ：3002694073
Email: 3002694073@qq.com
Country: China
ProdList: 9987
Advantage: 58

Zhengzhou Alfa Chemical Co.,Ltd

Tel: +8618530059196
Email: sale04@alfachem.cn
Country: China
ProdList: 11784
Advantage: 58

Shanghai UCHEM Inc.

Tel: +862156762820 +86-13564624040
Email: sales@myuchem.com
Country: China
ProdList: 8460
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418671 +8618949823763
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34563
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

HUNAN CHEMFISH SCIENTIFIC CO.,LTD

Tel: +86-0731-85567275 13298656710
Fax: QQ:3554193828
Email: sales05@chemfish.com
Country: China
ProdList: 7448
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28172
Advantage: 58

Zhengzhou Edward Biology Co.,Ltd

Tel: 0371-63682289 15538176268
Fax: QQ：1875164801
Email: jacschem@163.com
Country: China
ProdList: 9926
Advantage: 58

CONIER CHEM AND PHARMA LIMITED

Tel: +8618523575427
Email: sales@conier.com
Country: China
ProdList: 49975
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: +86-29-81139210 +86-18192627656
Fax: +86-29-88380327
Email: 1059@dideu.com
Country: China
ProdList: 3588
Advantage: 58

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

Tel: +86-021-61551413 +8618813727289
Email: contact@trustwe.com
Country: China
ProdList: 5743
Advantage: 58

Beijing Aomi Jiade Pharmaceutical Technology Co., Ltd

Tel: +86-13522808617
Email: omichem@126.com
Country: China
ProdList: 6413
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: 029-029-81024372 17792795018
Fax: 029-88380327
Email: 1027@dideu.com
Country: China
ProdList: 9997
Advantage: 58

Henan Research New Material Co., Ltd.

Tel: 1890-3931531 18903931628
Email: sales036@researchvip.com
Country: China
ProdList: 348
Advantage: 58

Wuhan kamik Technology Co., Ltd

Tel: 18162538168
Email: 201981259@qq.com
Country: China
ProdList: 7743
Advantage: 58

Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-021-50706066 15221275939
Email: shenlinxing@macklin.cn
Country: China
ProdList: 29784
Advantage: 58

Shanghai Haohong Scientific Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

Shanghai Titan Enterprise Development Co., Ltd

Tel: 16621224781
Email: syy@titansci.com
Country: China
ProdList: 2896
Advantage: 58

Shanghai Aladdin Biochemical Technology Co.,Ltd.

Tel: 400-6206333 13167063860
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 48457
Advantage: 58

Merck KGaA

Tel: 21-20338288
Email: ordercn@merckgroup.com
Country: China
ProdList: 6394
Advantage: 58

Aikon International Limited

Tel: 025-58851090 13408877820
Email: 2850281427@qq.com
Country: China
ProdList: 10000
Advantage: 58

Biosynth Biological Technology (Suzhou) Co Ltd

Tel: 51288865780
Email: sales@biosynth.com
Country: China
ProdList: 6051
Advantage: 58

Santa Cruz Biotechnology Inc

Tel: 021-60936350
Email: scbt@scbt.com
Country: China
ProdList: 6594
Advantage: 58

Shanghai Daken Advanced Materials Co.,Ltd

Tel: +86-2158073036
Email: info@dakenam.com
Country: China
ProdList: 13595
Advantage: 58

ATK CHEMICAL COMPANY LIMITED

Tel: +undefined-21-51877795
Fax: +86 21 5161 9052/ 5187 7796
Email: ivan@atkchemical.com
Country: China
ProdList: 33024
Advantage: 60

Henan Research New Materials Co., Ltd.

Tel: +86-18903931628 +86-18903931531
Email: sales036@researchvip.com
Country: China
ProdList: 300
Advantage: 58

Shanghai Scibiotron Pharmaceutical Co., Ltd

Tel: +86-16621589600
Email: contact@scibiotron.com
Country: China
ProdList: 5535
Advantage: 58

Hangzhou Collab Medicine Co.,Ltd.

Tel: +8615936229464
Email: candice@collab-med.com
Country: China
ProdList: 986
Advantage: 58

Shaanxi Didu New Materials Co. Ltd

Tel: +86-89586680 +86-13289823923
Email: 1026@dideu.com
Country: China
ProdList: 9080
Advantage: 58

SUZHOU SENFEIDA CHEMICAL CO.,LTD

Tel: +86-0512-83500002 +8618662433356
Email: 3899766280@qq.com
Country: China
ProdList: 26362
Advantage: 58

XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.

Tel: +8618950047208
Email: ellena@amitychem.com
Country: China
ProdList: 43416
Advantage: 58

Anhuyan (Hainan) Biotechnology Co., LTD

Tel: +86-18163349544; +8618163349544
Email: mollylucking@foxmail.com
Country: China
ProdList: 3000
Advantage: 58

SHANGHAI KEAN TECHNOLOGY CO., LTD.

Tel: +8613817748580
Fax: 021-50175322
Email: cooperation@kean-chem.com
Country: China
ProdList: 40066
Advantage: 58

Shanghai Acmec Biochemical Technology Co., Ltd.

Tel: +86-18621343501; +undefined18621343501
Email: product@acmec-e.com
Country: China
ProdList: 33338
Advantage: 58

Less

View Lastest Price from DI-O-TOLYLCHLOROPHOSPHINE manufacturers

Shaanxi Didu New Materials Co. Ltd

Product: DI-O-TOLYLCHLOROPHOSPHINE 36042-94-1
Price: US $1.50/g
Min. Order: 1g
Purity: 99.0% Min
Supply Ability: 100 Tons
Release date: 2025-04-27

Shaanxi Dideu Medichem Co. Ltd

Product: Di(o-tolyl)chlorophosphine 36042-94-1
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Career Henan Chemical Co

Product: DI-O-TOLYLCHLOROPHOSPHINE 36042-94-1
Price: US $1.00/KG
Min. Order: 1IU
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-02

36042-94-1, DI-O-TOLYLCHLOROPHOSPHINERelated Search:

METHYLPHENYLPHOSPHINIC CHLORIDE DI-P-TOLYLPHOSPHINE METHYLPHENYLCHLOROPHOSPHINE BIS(O-TOLYL)PHOSPHINE Chlorodiphenylphosphine DI-O-TOLYLCHLOROPHOSPHINE

Bis(2-methylphenyl)phosphinous chloride, Chlorobis(2-methylphenyl)phosphine

Di-o-tolylchlorophosphine, min. 98%

Chlorobis(o-tolyl)phosphine

Di(o-methylphenyl)phosphine chloride

BIS(O-TOLYL)CHLOROPHOSPHINE

BIS(2-METHYLPHENYL)PHOSPHINOUS CHLORIDE

DI(2-TOLYL)CHLOROPHOSPHINE

DI-O-TOLYLCHLOROPHOSPHINE

CHLORODI(O-TOLYL)PHOSPHINE

CHLOROBIS(2-METHYLPHENYL)PHOSPHINE

Di-(o-tolyl)phosphinchlorid

Di-o-tolylchlorophosphine,min.98%

chloro-bis(2-methylphenyl)phosphane

Phosphinous chloride, P,P-bis(2-methylphenyl)-

Chlorodi(<i>o</i>-tolyl)phosphine

Di-o-tolylphosphinouschloride

Di-tert-methoxyphosphorophosphine

36042-94-1

CH3C6H42PCl

C14H14ClP

Catalysis and Inorganic Chemistry

Phosphorus Precursors

Phosphorus Compounds

organophosphine halide