9,9-Diphenylfluorene-2-Boronic acid pinacol ester
- Product Name
- 9,9-Diphenylfluorene-2-Boronic acid pinacol ester
- CAS No.
- 462128-39-8
- Chemical Name
- 9,9-Diphenylfluorene-2-Boronic acid pinacol ester
- Synonyms
- diphenylfluorene;uoren-2-yL;2-(9,9-DiphenyL;9,9-Diphenylfluoren-2-borate pinacol ester;9,9-Diphenylfluorene-2-Boronic acid picol ester;9,9-Diphenylfluorene-2-Boronic acid pinacol ester;9,9-Diphenyl-9H-fluoren-2-ylboronic acid pinacol ester;(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine);2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-diphenylfluorene;9,9-Diphenylfluorene-2-Boronic acid pinacol ester ISO 9001:2015 REACH
- CBNumber
- CB92737589
- Molecular Formula
- C31H29BO2
- Formula Weight
- 444.37
- MOL File
- 462128-39-8.mol
9,9-Diphenylfluorene-2-Boronic acid pinacol ester Property
- Melting point:
- 198.0 to 202.0 °C
- Boiling point:
- 556.2±29.0 °C(Predicted)
- Density
- 1.17±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder to crystal
- color
- White to Almost white
Safety
- HS Code
- 2934.99.4400
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D5009
- Product name
- 2-(9,9-Diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Purity
- >97.0%(HPLC)(T)
- Packaging
- 200mg
- Price
- $45
- Updated
- 2025/07/31
- Product number
- D5009
- Product name
- 2-(9,9-Diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Purity
- >97.0%(HPLC)(T)
- Packaging
- 1g
- Price
- $132
- Updated
- 2025/07/31
- Product number
- D493993
- Product name
- 2-(9,9-Diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Packaging
- 25mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 9599AL
- Product name
- 2-(9,9-Diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Packaging
- 250mg
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 9599AL
- Product name
- 2-(9,9-Diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Packaging
- 5g
- Price
- $157
- Updated
- 2021/12/16
9,9-Diphenylfluorene-2-Boronic acid pinacol ester Chemical Properties,Usage,Production
Synthesis
73183-34-3
474918-32-6
462128-39-8
The general procedure for the synthesis of 2-(9,9-diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane from biphenylpinacol ester and 2-bromo-9,9-diphenylfluorene was carried out in the following manner: in a single-necked round-bottomed flask, 2-bromo-9,9-diphenyl-9H-fluorene (40 g, 100.67 mmol), biphenylpinacol ester (51.1 g, 201.34 mmol), PdCl2(dppf) (2.2 g, 3.02 mmol), KOAc (29.6 g, 302.01 mmol) and DMF (400 ml) were mixed and the reaction was carried out at reflux. Upon completion of the reaction, the mixture was extracted with dichloromethane and the organic phase was dried with anhydrous MgSO4, followed by removal of the solvent DMF under reduced pressure by rotary evaporator.The crude product was purified by column chromatography (silica gel as stationary phase, eluent hexane and dichloromethane in a 1:1 ratio, v/v/v/v) to afford the white solid product 2-(9,9-diphenyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl- 1,3,2-dioxaborolane (41 g, 91% yield).
References
[1] Patent: CN105408333, 2016, A. Location in patent: Paragraph 0212; 0213; 0214
9,9-Diphenylfluorene-2-Boronic acid pinacol ester Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9,9-Diphenylfluorene-2-Boronic acid pinacol ester manufacturers
- Product
- 9,9-Diphenylfluorene-2-Boronic acid pinacol ester 462128-39-8
- Price
- US $5.00/kg
- Min. Order
- 1kg
- Purity
- 97%
- Supply Ability
- 100kg
- Release date
- 2025-04-01
- Product
- 9,9-Diphenylfluorene-2-Boronic acid pinacol ester 462128-39-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-12
- Product
- 9,9-Diphenylfluorene-2-Boronic acid pinacol ester 462128-39-8
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-02