3-BENZYLOXYANILINE
- Product Name
- 3-BENZYLOXYANILINE
- CAS No.
- 1484-26-0
- Chemical Name
- 3-BENZYLOXYANILINE
- Synonyms
- AKOS BC-2549;AKOS BBB/398;3-BENZYLOXYANILINE;TIMTEC-BB SBB000388;M-(BENZYLOXY)ANILINE;3-Benzyloxyaniline 98%;3-Benzyloxyaniline,98%;3-Benzyloxyaniline >3-(Phenylmethoxy)aniline;3-(benzyloxy)phenylamine
- CBNumber
- CB9282029
- Molecular Formula
- C13H13NO
- Formula Weight
- 199.25
- MOL File
- 1484-26-0.mol
3-BENZYLOXYANILINE Property
- Melting point:
- 63-67 °C (lit.)
- Boiling point:
- 170 °C(Press: 3 Torr)
- Density
- 1.129±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- soluble in Methanol
- pka
- 4.17±0.10(Predicted)
- form
- Solid
- color
- Pale brown
- InChI
- InChI=1S/C13H13NO/c14-12-7-4-8-13(9-12)15-10-11-5-2-1-3-6-11/h1-9H,10,14H2
- InChIKey
- IGPFOKFDBICQMC-UHFFFAOYSA-N
- SMILES
- C1(N)=CC=CC(OCC2=CC=CC=C2)=C1
- CAS DataBase Reference
- 1484-26-0(CAS DataBase Reference)
- EPA Substance Registry System
- 3-(Benzyloxy)aniline (1484-26-0)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 100803
- Product name
- 3-Benzyloxyaniline
- Purity
- 98%
- Packaging
- 10g
- Price
- $148.4
- Updated
- 2025/07/31
- Product number
- B4197
- Product name
- 3-Benzyloxyaniline
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $29
- Updated
- 2025/07/31
- Product number
- B4197
- Product name
- 3-Benzyloxyaniline
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $83
- Updated
- 2025/07/31
- Product number
- B288573
- Product name
- 3-Benzyloxyaniline
- Packaging
- 500mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- JK188744
- Product name
- 3-Benzyloxyaniline
- Packaging
- 1g
- Price
- $18
- Updated
- 2021/12/16
3-BENZYLOXYANILINE Chemical Properties,Usage,Production
Chemical Properties
Beige to tan powder
Synthesis Reference(s)
Tetrahedron Letters, 23, p. 147, 1982 DOI: 10.1016/S0040-4039(00)86770-2
Synthesis
24318-00-1
1484-26-0
591-27-5
Using 1-(benzyloxy)-3-nitrobenzene as the starting material, the reaction was carried out using an experimental method similar to that of Example 59, in which ferrous acetate (II), nickel nitrate (II), or cobalt acetylacetonate (III) was chosen as the metal reducing agent. The experimental results are detailed in Table 11. The data of Examples 60 to 66 show that the reaction rate is significantly enhanced when metal compounds such as iron, nickel or cobalt salts and amine additives such as pyrrolidine are added to the catalytic reduction system of the present invention in the presence of a rhodium/carrier catalyst. Under this condition, functional groups such as benzyl ether, which are easy to reduce, are retained, and nitro is selectively reduced to amino, thereby increasing the yield of the target products 3-benzyloxyaniline and 3-aminophenol.
References
[1] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[2] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[3] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[4] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[5] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
3-BENZYLOXYANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-BENZYLOXYANILINE manufacturers
- Product
- 3-BENZYLOXYANILINE 1484-26-0
- Price
- US $0.01/KG
- Min. Order
- 1KG
- Purity
- 98%; 99%
- Supply Ability
- 1kg; 10kg; 25kg
- Release date
- 2020-01-07
- Product
- 3-BENZYLOXYANILINE 1484-26-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98
- Supply Ability
- 10t
- Release date
- 2019-12-18