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3-BENZYLOXYANILINE

Product Name
3-BENZYLOXYANILINE
CAS No.
1484-26-0
Chemical Name
3-BENZYLOXYANILINE
Synonyms
AKOS BC-2549;AKOS BBB/398;3-BENZYLOXYANILINE;TIMTEC-BB SBB000388;M-(BENZYLOXY)ANILINE;3-Benzyloxyaniline 98%;3-Benzyloxyaniline,98%;3-Benzyloxyaniline >3-(Phenylmethoxy)aniline;3-(benzyloxy)phenylamine
CBNumber
CB9282029
Molecular Formula
C13H13NO
Formula Weight
199.25
MOL File
1484-26-0.mol
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3-BENZYLOXYANILINE Property

Melting point:
63-67 °C (lit.)
Boiling point:
170 °C(Press: 3 Torr)
Density 
1.129±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
soluble in Methanol
pka
4.17±0.10(Predicted)
form 
Solid
color 
Pale brown
InChI
InChI=1S/C13H13NO/c14-12-7-4-8-13(9-12)15-10-11-5-2-1-3-6-11/h1-9H,10,14H2
InChIKey
IGPFOKFDBICQMC-UHFFFAOYSA-N
SMILES
C1(N)=CC=CC(OCC2=CC=CC=C2)=C1
CAS DataBase Reference
1484-26-0(CAS DataBase Reference)
EPA Substance Registry System
3-(Benzyloxy)aniline (1484-26-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
2811
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
100803
Product name
3-Benzyloxyaniline
Purity
98%
Packaging
10g
Price
$148.4
Updated
2025/07/31
TCI Chemical
Product number
B4197
Product name
3-Benzyloxyaniline
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$29
Updated
2025/07/31
TCI Chemical
Product number
B4197
Product name
3-Benzyloxyaniline
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$83
Updated
2025/07/31
TRC
Product number
B288573
Product name
3-Benzyloxyaniline
Packaging
500mg
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK188744
Product name
3-Benzyloxyaniline
Packaging
1g
Price
$18
Updated
2021/12/16
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3-BENZYLOXYANILINE Chemical Properties,Usage,Production

Chemical Properties

Beige to tan powder

Synthesis Reference(s)

Tetrahedron Letters, 23, p. 147, 1982 DOI: 10.1016/S0040-4039(00)86770-2

Synthesis

24318-00-1

1484-26-0

591-27-5

Using 1-(benzyloxy)-3-nitrobenzene as the starting material, the reaction was carried out using an experimental method similar to that of Example 59, in which ferrous acetate (II), nickel nitrate (II), or cobalt acetylacetonate (III) was chosen as the metal reducing agent. The experimental results are detailed in Table 11. The data of Examples 60 to 66 show that the reaction rate is significantly enhanced when metal compounds such as iron, nickel or cobalt salts and amine additives such as pyrrolidine are added to the catalytic reduction system of the present invention in the presence of a rhodium/carrier catalyst. Under this condition, functional groups such as benzyl ether, which are easy to reduce, are retained, and nitro is selectively reduced to amino, thereby increasing the yield of the target products 3-benzyloxyaniline and 3-aminophenol.

References

[1] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[2] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[3] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[4] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45
[5] Patent: EP1541582, 2005, A1. Location in patent: Page/Page column 45

3-BENZYLOXYANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BENZYLOXYANILINE Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from 3-BENZYLOXYANILINE manufacturers

Career Henan Chemical Co
Product
3-BENZYLOXYANILINE 1484-26-0
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
1kg; 10kg; 25kg
Release date
2020-01-07
Career Henan Chemical Co
Product
3-BENZYLOXYANILINE 1484-26-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98
Supply Ability
10t
Release date
2019-12-18

1484-26-0, 3-BENZYLOXYANILINERelated Search:


  • Benzenamine, 3-(phenylmethoxy)-
  • M-(BENZYLOXY)ANILINE
  • 3-BENZYLOXYANILINE
  • AKOS BBB/398
  • AKOS BC-2549
  • TIMTEC-BB SBB000388
  • 3-Aminophenyl benzyl ether
  • 3-Benzyloxyaniline 98%
  • 3-(benzyloxy)phenylamine
  • 3-(Phenylmethoxy)aniline
  • 3-Benzyloxyaniline,98%
  • 3-Amino-alpha-phenylanisole
  • 3-Benzyloxyaniline &gt
  • 3-BENZYLOXYANILINE ISO 9001:2015 REACH
  • 1484-26-0
  • Building Blocks
  • Amines
  • C11 to C37
  • Organic Building Blocks
  • Nitrogen Compounds
  • Anilines, Aromatic Amines and Nitro Compounds
  • Amines
  • C11 to C38
  • Nitrogen Compounds