ChemicalBook > CAS DataBase List > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Reaction- Product Name
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- CAS No.
- 443965-14-8
- Chemical Name
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- Synonyms
- (S)-SIPHOS;(R)-SIPHOS;(R)-SIPHOS 97%;(R)-SIPHOS(WS200888);N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%;N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS
- CBNumber
- CB9285479
- Molecular Formula
- C19H20NO2P
- Formula Weight
- 325.34
- MOL File
- 443965-14-8.mol
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Property
- Melting point:
- 95-96°C
- Boiling point:
- 429.6±55.0 °C(Predicted)
- alpha
- +505° (c 0.5, CH2Cl2)
- form
- solid
- pka
- 2.19±0.20(Predicted)
- color
- white
- optical activity
- [α]22/D +480°, c = 1 in chloroform
- Sensitive
- moisture sensitive
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Safety
- WGK Germany
- 3
- HS Code
- 29299090
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-5150
- Product name
- (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS
- Packaging
- 100mg
- Price
- $107
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-5150
- Product name
- (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS
- Packaging
- 500mg
- Price
- $421
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001116
- Product name
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- Purity
- 95.00%
- Packaging
- 50MG
- Price
- $607.95
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- ING0001116
- Product name
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- Purity
- 95.00%
- Packaging
- 250MG
- Price
- $788.29
- Updated
- 2021/12/16
AK Scientific
- Product number
- 7382AJ
- Product name
- (11AR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-De:1',7'-Fg][1,3,2]dioxaphosphocin-5-dimethylamine
- Packaging
- 50mg
- Price
- $258.8
- Updated
- 2021/12/16
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Usage,Production
Reaction
- Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
- Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
- Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
- Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
- Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
- Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Chemical Properties
White power
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials
Raw materials
Benzyl chloride
Ethanol
Acetone
Sodium bromide
Methanesulfonic acid
Hydrogen peroxide
Sodium chloride
Toluene
N,N-Diisopropylethylamine
Nickel
Cinchonidine
Boron tribromide
Palladium
3-Hydroxybenzaldehyde
Hexamethylphosphorous triamide
(R)-1,1'-SPIROBIINDANE-7,7'-DIOL
Ethyl acetate
Hydrochloric acid
Sodium bicarbonate
Hydrogen
Dichloromethane
Sodium hydroxide
PETROLEUM ETHER
Preparation Products
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers
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443965-14-8, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINERelated Search:
Indene
Dimethylamine
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE