(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

Reaction

Product Name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
CAS No.: 443965-14-8
Chemical Name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms: (S)-SIPHOS;(R)-SIPHOS;(R)-SIPHOS 97%;(R)-SIPHOS（WS200888）;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%;N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS
CBNumber: CB9285479
Molecular Formula: C19H20NO2P
Formula Weight: 325.34
MOL File: 443965-14-8.mol

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Property

Melting point:: 95-96°C
Boiling point:: 429.6±55.0 °C(Predicted)
alpha: +505° (c 0.5, CH2Cl2)
form: solid
pka: 2.19±0.20(Predicted)
color: white
optical activity: [α]22/D +480°, c = 1 in chloroform
Sensitive: moisture sensitive

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Safety

WGK Germany: 3
HS Code: 29299090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-5150
Product name: (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS
Packaging: 100mg
Price: $107
Updated: 2024/03/01

Strem Chemicals

Product number: 15-5150
Product name: (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS
Packaging: 500mg
Price: $421
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ING0001116
Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Purity: 95.00%
Packaging: 50MG
Price: $607.95
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0001116
Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Purity: 95.00%
Packaging: 250MG
Price: $788.29
Updated: 2021/12/16

AK Scientific

Product number: 7382AJ
Product name: (11AR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-De:1',7'-Fg][1,3,2]dioxaphosphocin-5-dimethylamine
Packaging: 50mg
Price: $258.8
Updated: 2021/12/16

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Usage,Production

Reaction

Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.

Chemical Properties

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

Benzyl chloride Ethanol Acetone Sodium bromide Methanesulfonic acid Hydrogen peroxide Sodium chloride Toluene N,N-Diisopropylethylamine Nickel Cinchonidine Boron tribromide Palladium 3-Hydroxybenzaldehyde Hexamethylphosphorous triamide (R)-1,1'-SPIROBIINDANE-7,7'-DIOL Ethyl acetate Hydrochloric acid Sodium bicarbonate Hydrogen Dichloromethane Sodium hydroxide PETROLEUM ETHER

Preparation Products

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers

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443965-14-8, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINERelated Search:

Indene Dimethylamine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE

N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE

(R)-SIPHOS

(S)-SIPHOS

(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(R)-SIPHOS

N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(R)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite

N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%

(11aR)-10,11,12,13-Tetrahydro-N,N-dimethyldiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine

(11aR)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (R)-SIPHOS

(R)-SIPHOS（WS200888）

Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine, 10,11,12,13-tetrahydro-N,N-dimethyl-, (11aR)-

(R)-SIPHOS 97%

(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11aR)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine

(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98%

443965-14-8

C19H20NO2P

Chiral Phosphine

Chiral Spiro Ligand

CPN