ChemicalBook > CAS DataBase List > 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

Product Name
3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
CAS No.
63160-13-4
Chemical Name
3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
Synonyms
Davis Oxaziridine;2-(benzenesulfonyl)-3-phenyloxaziridine;2-OXAZIRIDINE;3-PHENYL-2-(PHENYLSULFONYL)-1;N-(Phenylsulfonyl)phenyloxaziridine;3-Phenyl-N-phenylsulfonyloxaziridine;Oxaziridine, 3-phenyl-2-(phenylsulfonyl;3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE;trans-2-(Phenylsulfonyl)-3-phenyloxyaziridine;TRANS-2-(PHENYL SULFONYL)-3-PHENYL OXAZIRIDINE
CBNumber
CB9287428
Molecular Formula
C13H11NO3S
Formula Weight
261.3
MOL File
63160-13-4.mol
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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Property

Melting point:
96-97 °C
Boiling point:
394.4±45.0 °C(Predicted)
Density 
1.398±0.06 g/cm3(Predicted)
storage temp. 
-20°C Freezer
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly, Sonicated)
form 
Solid
pka
-13.47±0.40(Predicted)
color 
White to Off-White
InChI
InChI=1S/C13H11NO3S/c15-18(16,12-9-5-2-6-10-12)14-13(17-14)11-7-3-1-4-8-11/h1-10,13H
InChIKey
MKHGVMIXRPGHOO-UHFFFAOYSA-N
SMILES
O1C(C2=CC=CC=C2)N1S(C1=CC=CC=C1)(=O)=O
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Safety

HS Code 
2935909099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
D194900
Product name
DavisOxaziridine
Packaging
1g
Price
$180
Updated
2021/12/16
Synthonix
Product number
P5853
Product name
3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity
95%
Packaging
250mg
Price
$20
Updated
2021/12/16
Synthonix
Product number
P5853
Product name
3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity
95%
Packaging
1g
Price
$40
Updated
2021/12/16
Apolloscientific
Product number
OR961468
Product name
2-(Benzenesulfonyl)-3-phenyloxaziridine
Purity
98%
Packaging
1g
Price
$100
Updated
2021/12/16
Synthonix
Product number
P5853
Product name
3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine
Purity
95%
Packaging
5g
Price
$120
Updated
2021/12/16
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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Chemical Properties,Usage,Production

Uses

Davis Oxaziridine is an oxidizing agent used in the preparation of wide variety of pharmaceutical compounds.

Uses

3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine, is an oxidizing agent used in the preparation of wide variety of pharmaceutical compounds.

Preparation

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE can be readily prepared on a 100 g scale in 88% yield via oxidation of N-benzylidenebenzenesulfonamide with buffered m-Chloroperbenzoic Acid or more conveniently with Potassium Monoperoxysulfate (Oxone). This Baeyer-Villiger type of oxidation of sulfonimine affords only the trans-oxaziridine. A number of other (±)-trans-2-(arylsulfonyl)-3- aryloxaziridines (2) can also be prepared by these methods.

General Description

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE is a neutral, aprotic, electrophilic oxidizing agent for the chemoselective oxidation of many nucleophilic substrates[1].

storage

3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine can be stored in a brown bottle in the refrigerator for years without noticeable decomposition. Storage at rt for long periods of time, however, is potentially hazardous.[2] The nitro-substituted oxaziridines (2) are more thermally stable and are recommended for reactions at elevated temperatures.

References

1. (a) Davis, F. A.; Sherppard, A. C. T 1989, 45, 5703. (b) Davis, F. A.; Chen, B.-C. CRV 1992, 92, 912.
2. Vishwakarma, L. C.; Stringer, O. D.; Davis, F. A. OS 1988, 66, 203.

3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE Suppliers

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View Lastest Price from 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE 63160-13-4
Price
US $1.00/kg
Min. Order
1kg
Purity
98.00%
Supply Ability
20tons
Release date
2023-09-07
Career Henan Chemical Co
Product
3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE 63160-13-4
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-07

63160-13-4, 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINERelated Search:

BENZENESULFOHYDROXAMIC ACID 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE

  • TRANS-2-(PHENYL SULFONYL)-3-PHENYL OXAZIRIDINE
  • 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
  • Oxaziridine, 3-phenyl-2-(phenylsulfonyl
  • 2-(benzenesulfonyl)-3-phenyloxaziridine
  • trans-2-(Phenylsulfonyl)-3-phenyloxyaziridine
  • 3-Phenyl-N-phenylsulfonyloxaziridine
  • Davis Oxaziridine
  • N-(Phenylsulfonyl)phenyloxaziridine
  • 2-OXAZIRIDINE
  • 3-PHENYL-2-(PHENYLSULFONYL)-1
  • TIANFU-CHEM 3-PHENYL-2-(PHENYLSULFONYL)-1,2-OXAZIRIDINE
  • 3-Phenyl-2-(phenylsulfonyl)-1,2-oxaziridine - [P5853]
  • 63160-13-4
  • Aromatics
  • Heterocycles
  • Intermediates
  • Sulfur & Selenium Compounds