4-FLUORO-5-NITROBENZENE-1,2-DIAMINE

Product Name: 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE
CAS No.: 113269-06-0
Chemical Name: 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE
Synonyms: 4-fluoro-5-nitro-2-aMino-aniline;4,5-Diamine-2-fluoronitrobenzene;4-FLUORO-5-NITROBENZENE-1,2-DIAMINE;4-Fluoro-5-nitro-1,2-benzenediamine;1,2-Benzenediamine, 4-fluoro-5-nitro-;4-Fluoro-5-nitrobenzene-1,2-diamine , Tech.;4,5-Diamino-2-fluoronitrobenzene, 4-Fluoro-5-nitrophenylene-1,2-diamine
CBNumber: CB9291070
Molecular Formula: C6H6FN3O2
Formula Weight: 171.13
MOL File: 113269-06-0.mol

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4-FLUORO-5-NITROBENZENE-1,2-DIAMINE Property

Boiling point:: 438.4±40.0 °C(Predicted)
Density: 1.555±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 1.95±0.10(Predicted)
Appearance: Brown to reddish brown Solid
InChI: InChI=1S/C6H6FN3O2/c7-3-1-4(8)5(9)2-6(3)10(11)12/h1-2H,8-9H2
InChIKey: QZNALIMEKAACKP-UHFFFAOYSA-N
SMILES: C1(N)=CC([N+]([O-])=O)=C(F)C=C1N

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Safety

HS Code: 2921511990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: F621980
Product name: 4-Fluoro-5-nitrobenzene-1,2-diamine
Packaging: 1g
Price: $350
Updated: 2021/12/16

Matrix Scientific

Product number: 097037
Product name: 4-Fluoro-5-nitrobenzene-1,2-diamine
Purity: 95+%
Packaging: 1g
Price: $588
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0023800
Product name: 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE
Purity: 95.00%
Packaging: 1G
Price: $691.02
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0023800
Product name: 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE
Purity: 95.00%
Packaging: 5G
Price: $1201.89
Updated: 2021/12/16

Apolloscientific

Product number: PC31311
Product name: 4-Fluoro-5-nitrobenzene-1,2-diamine
Packaging: 1g
Price: $176
Updated: 2021/12/16

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4-FLUORO-5-NITROBENZENE-1,2-DIAMINE Chemical Properties,Usage,Production

Synthesis

113269-03-7

113269-06-0

General procedure for the synthesis of 4-fluoro-5-nitrobenzene-1,2-diamine from N,N'-(4-fluoro-5-nitro-1,2-phenylene)bis(4-methylbenzenesulfonamide): 158 mg (0.33 mmol) N-[4-fluoro-5-nitro-2-(4-toluenesulfonylamino)-phenyl]-4-methylbenzenesulfonamide was suspended in a mixture of 35 μL deionized water and 360 μL of concentrated sulfuric acid in a mixed solution, and the suspension was heated at 80 °C for 1 hour. Upon completion of the reaction, the reaction mixture was poured into 10 mL of deionized water and a yellow solid was precipitated. The aqueous suspension was heated to boiling to completely dissolve the solid and subsequently cooled to room temperature. The pH of the solution was adjusted to about 9 with concentrated ammonia, at which point an orange solid precipitated. The solid product was separated by filtration, washed with deionized water and dried in air. A final product of 49 mg was obtained in 88% yield.

References

[1] Heterocycles, 1987, vol. 26, # 9, p. 2433 - 2442
[2] Patent: US2006/4197, 2006, A1. Location in patent: Page/Page column 12/16; 8; 16

4-FLUORO-5-NITROBENZENE-1,2-DIAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-FLUORO-5-NITROBENZENE-1,2-DIAMINE Suppliers

Belgium 1 China 39 India 1 United Kingdom 2 United States 9 Global 52

Suzhou Skenoson Biological Technology Co. LTD

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J & K SCIENTIFIC LTD.

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Adamas Reagent, Ltd.

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Thermo Fisher Scientific

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9ding chemical ( Shanghai) Limited

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SynAsst Chemical.

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Bide Pharmatech Ltd.

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Yancheng KangdiSen Pharmaceutical Co., Ltd.

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113269-06-0, 4-FLUORO-5-NITROBENZENE-1,2-DIAMINERelated Search:

4-Fluoronitrobenzene N(ALPHA)-(2 4-DINITRO-5-FLUOROPHENYL)- FDNP-VAL-NH2 6-FLUORO-7-NITRO-2(1H)-QUINOXALINONE 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-D-LEUCINAMIDE 3-(5-FLUORO-2,4-DINITROANILINO)-PROXYL NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-L-LEUCINAMIDE 1,2-DITOSYLAMINO-4-FLUORO-5-NITROBENZENE (5-FLUORO-2,4-DINITRO-PHENYL)-METHYL-PHENYL-AMINE 4-(2-AMINO-5-FLUORO-4-NITROANILINO)PENT-3-EN-2-ONE (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide 2,4-DINITRO-5-FLUOROACETANILIDE FDNP-D-ALA-NH2 2,4-DINITRO-5-FLUOROANILINE 1-(5-FLUORO-2,4-DINITROPHENYL)-4-METHYLPIPERAZINE

4-FLUORO-5-NITROBENZENE-1,2-DIAMINE

4-Fluoro-5-nitrobenzene-1,2-diamine , Tech.

4,5-Diamine-2-fluoronitrobenzene

4-fluoro-5-nitro-2-aMino-aniline

4,5-Diamino-2-fluoronitrobenzene, 4-Fluoro-5-nitrophenylene-1,2-diamine

1,2-Benzenediamine, 4-fluoro-5-nitro-

4-Fluoro-5-nitro-1,2-benzenediamine

113269-06-0

C6H6FN3O2