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Camphene

Product Name
Camphene
CAS No.
79-92-5
Chemical Name
Camphene
Synonyms
CAMPHENE 90;CAMPHENE 46;D,L-CAMPHENE;Camphene(DOT);Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-;FEMA 2229;2,2-Dimethyl-3-methylene-bicyclo[2.2.1]heptane;NA 9011;CAMPHENE;78.0%(GC)
CBNumber
CB9303627
Molecular Formula
C10H16
Formula Weight
136.23
MOL File
79-92-5.mol
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Camphene Property

Melting point:
48-52 °C (lit.)
Boiling point:
159-160 °C (lit.)
Density 
0.85 g/mL at 25 °C (lit.)
vapor pressure 
3.99 hPa (20 °C)
refractive index 
1.4551
FEMA 
2229 | CAMPHENE
Flash point:
94 °F
storage temp. 
2-8°C
solubility 
0.0042g/l
form 
Crystalline Low Melting Solid
Specific Gravity
0.85
color 
White
PH
5.5 (H2O, 22℃)(saturated aqueous solution)
Odor
at 10.00 % in dipropylene glycol. woody herbal fir needle camphor terpenic
Odor Type
woody
Odor Threshold
0.88ppm
Water Solubility 
practically insoluble
Merck 
14,1730
JECFA Number
1323
Dielectric constant
2.7（20℃）
InChIKey
CRPUJAZIXJMDBK-DTWKUNHWSA-N
LogP
4.22 at 20℃
CAS DataBase Reference
79-92-5(CAS DataBase Reference)
NIST Chemistry Reference
Camphene(79-92-5)
EPA Substance Registry System
Camphene (79-92-5)
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Safety

Hazard Codes 
F,N
Risk Statements 
11-10-50/53-36
Safety Statements 
16-33-61-60-26
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
2
RTECS 
EX1055000
Autoignition Temperature
265 °C
HS Code 
2902 19 00
HazardClass 
4.1
PackingGroup 
III
Hazardous Substances Data
79-92-5(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H319Causes serious eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20254
Product name
(+)-Camphene
Purity
forsynthesis
Packaging
100g
Price
$40.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20254
Product name
(+)-Camphene
Purity
forsynthesis
Packaging
1kg
Price
$172
Updated
2024/03/01
Sigma-Aldrich
Product number
456055
Product name
Camphene
Purity
95%
Packaging
1kg
Price
$221
Updated
2024/03/01
Sigma-Aldrich
Product number
442505
Product name
Camphene
Purity
analytical standard
Packaging
1000mg
Price
$27.8
Updated
2024/03/01
Sigma-Aldrich
Product number
01410590
Product name
Camphene
Purity
primary reference standard
Packaging
100mg
Price
$369
Updated
2024/03/01
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Camphene Chemical Properties,Usage,Production

Description

Camphene is a colorless to white crystallinesolid with camphor-like odor. It may be shipped as a liquid.Freezing/Melting point=50℃. Molecular weight=136.24;Boiling point=159℃; Melting point=37℃; Flashpoint=42℃ (oc); 33℃ (cc). Hazard Identification (basedon NFPA-704 M Rating System): Health 2, Flammability 3,Reactivity 0. Insoluble in water.

Chemical Properties

Camphene is a colorless to white crystalline solid, Camphor, or turpentine odor. It may be shipped as a liquid. Freezing/Melting point 5 50C.

Chemical Properties

WHITE CRYSTALLINE LOW MELTING SOLID

Chemical Properties

Camphene has a terpene, camphoraceous taste.

Occurrence

Reported found in carrot, dill, fennel, marjoram, nutmeg, parsley, pepper, tarragon and thyme.

Uses

Camphene is used in the preparation of fragrances and as a food additive for flavoring.

Uses

Manufacture of synthetic camphor, camphor substitute.

Preparation

From pinene by catalytic isomerization or from bornyl chloride by heating with alkali in the presence of abietenesulfonic acid.

Definition

ChEBI: A monoterpene with a bicyclic skeleton that is bicyclo[2.2.1]heptane substituted by geminal methyl groups at position 2 and a methylidene group at position 3. It is a widespread natural product found in many essential oils.

Aroma threshold values

Detection at 10%: camphoraceous, cooling, piney woody with terphy nuances. It has citrus and green minty and green spicy notes.

Taste threshold values

Taste characteristics at 50–100 ppm: camphoraceous, cooling, minty, with citrus and green spicy nuances.

General Description

A colorless to white crystalline solid with an insipid camphor-like odor. Dust and crystals are irritants to the eyes, nose and throat. Emits flammable vapors when heated. Emits acrid smoke and irritating fumes at high temperature. Used for the manufacture of synthetic camphor.

Reactivity Profile

Camphene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Hazard

Toxic by ingestion.

Health Hazard

Inhalation causes irritation of nose and throat. Contact with eyes or skin causes irritation.

Flammability and Explosibility

Flammable

Pharmacology

Oral administration of camphene (260 mmols/kg) to rats increased bile flow by 50% 4 hr after administration (M?rsdorf, 1966). Development of atheromatosis of the aorta in rabbits fed 1 g cholesterol/day for 3 months was considerably inhibited by simultaneous administration of a mixture of terpenes including camphene, injected sc in a dose of 1 ml every other day for 6 wk and then given orally in doses of 2 ml/day (Benk?, Macher, Szarvas & Tiboldi, 1961). The effect of 1 g cholesterol/day for 8 wk in the diet of rabbits in increasing the number and volume of mast cells in the aortic adventitia and increasing the total lipid content of the aortic wall was slightly enhanced by the simultaneous addition of 11 g camphene/day (Lesznyak, Benko, Szabo & Muller, 1972). This camphene treatment also decreased the lipid accumulation in the liver, but had no effect on the cholesterol-induced atheromatosis of the aorta (Benko, Szabo, Muller & Lesznyak, 1972).

Anticancer Research

This was tested against melanoma cells in a syngeneic model, and there was promisingantitumor activity (Ma et al. 2016).

Safety Profile

Mutation data reported. Combustible; yields flammable vapors when heated and can react with oxidizing materials. To fight fire, use water spray, foam, fog, CO2. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

Camphene is used to manufacture synthetic camphor; for making moth-proofing and in the cosmetics, perfume, and food flavoring industries.

First aid

f this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at leastCamphene 54715 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Red: Flammability Hazard: Storein a flammable liquid storage area or approved cabinetaway from ignition sources and corrosive and reactivematerials. Prior to working with camphene you shouldbe trained on its proper handling and storage. Camphenemust be stored to avoid contact with strong oxidizers(such as chlorine, bromine, and fluorine) since violentreactions occur. Store in tightly closed containers in acool, well-ventilated area. Sources of ignition, such assmoking and open flames, are prohibited where Campheneis used, handled, or stored in a manner that could create apotential fire or explosion hazard. Use only nonsparkingtools and equipment, especially when opening and closingcontainers of camphene.

Shipping

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN2319 Terpene hydrocarbons, n.o.s., Hazard Class: 3; Labels: 3- Flammable liquid

Incompatibilities

Forms explosive mixture with air. Emulsions in xylene may violently decompose on contact with iron or aluminum above 70C. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause exothermic reaction, releasing flammable hydrogen gas

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Camphene Preparation Products And Raw materials

Raw materials

Metatitanic acid Turpentine oil ALPHA-PINENE Rutile alpha-Pinene

Preparation Products

Terpinyl cyclohexanol mixture
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Camphene Suppliers

Americas 1 Austria 3 Belgium 1 Brazil 2 China 154 Europe 4 Finland 2 France 4 Germany 14 India 28 Italy 1 Japan 7 Mexico 1 Russia 2 Singapore 1 Spain 4 Switzerland 4 Ukraine 1 United Kingdom 10 United States 54 Global 299
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
Akshaya Laboratories Pvt. Ltd
Tel
--
Fax
--
Country
India
ProdList
125
Advantage
58
Redox Life Science
Tel
--
Fax
--
Email
info@redoxsci.com
Country
India
ProdList
21
Advantage
58
Kanchi Karpooram Ltd
Tel
--
Fax
--
Country
India
ProdList
2
Advantage
58
Gyan Flavours Export Pvt. Ltd.
Tel
--
Fax
--
Email
sales@gyanflavoursexport.com
Country
India
ProdList
19
Advantage
58
Dujodwala Products Limited
Tel
--
Fax
--
Country
India
ProdList
2
Advantage
58
Ghaziabad Aromatics
Tel
--
Fax
--
Email
ghaziabad_aromatics@yahoo.com
Country
India
ProdList
17
Advantage
58
Aamirav Ingredients & Specialties Pvt. Ltd.
Tel
--
Fax
--
Email
mails@aamirav.co.in
Country
India
ProdList
63
Advantage
58
Indenta Chemicals (India) Pvt., Ltd.
Tel
--
Fax
--
Email
indenta@indenta.com
Country
India
ProdList
27
Advantage
58
Himachal Terepene Products Pvt., Ltd.
Tel
--
Fax
--
Email
htppla1@gmail.com
Country
India
ProdList
2
Advantage
58
Camphor & Allied Products Limited
Tel
--
Fax
--
Country
India
ProdList
6
Advantage
58
Bhagat Aromatics Limited
Tel
--
Fax
--
Country
India
ProdList
9
Advantage
58
Mangalam Organics Limited.
Tel
--
Fax
--
Email
info@mangalamorganics.com
Country
India
ProdList
4
Advantage
58
Planters International Company
Tel
--
Fax
--
Country
India
ProdList
55
Advantage
58
Saptagir Camphor Limited
Tel
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Fax
--
Country
India
ProdList
1
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58
Trip Munendra International
Tel
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Fax
--
Country
India
ProdList
1
Advantage
58
Sodium Acetate Importers
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Fax
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Country
India
ProdList
2
Advantage
58
Khushi Chemworth
Tel
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Fax
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Country
India
ProdList
72
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58
Mangalam Organic Limited
Tel
--
Fax
--
Country
India
ProdList
2
Advantage
58
Musks & Fragrance
Tel
--
Fax
--
Email
musks@vsnl.com
Country
India
ProdList
124
Advantage
58
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View Lastest Price from Camphene manufacturers

Weijer International Trade (Hebei) Co., Ltd
Product
Camphene 79-92-5
Price
US $1.00/KG
Min. Order
1KG
Purity
>99%
Supply Ability
1000T
Release date
2023-03-16
Anhui Rencheng Technology Co., Ltd
Product
Camphene 79-92-5
Price
US $1.00/KG
Min. Order
0.5KG
Purity
>99%
Supply Ability
20tons
Release date
2020-12-14
Shaanxi Dideu Medichem Co. Ltd
Product
Camphene 79-92-5
Price
US $0.00-0.00/Kg
Min. Order
100G
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-17

79-92-5, CampheneRelated Search:

ETHANE (+/-)-10-CAMPHORSULFONIC ACID SODIUM SALT White camphor oil Dimethyl phthalate Dimethyl sulfoxide Dimethyl sulfide Dimethyl ether 4,4'-Diphenylmethane diisocyanate Heptane Methylene Blue Dimethyl fumarate PROPYLENE Citral Camphene (contains ca 20% trycyclene),CAMPHENE(RG),(+-)-CAMPHENE (CONTAINS CA 20%RICYCLENE) 80+%,D,L-CAMPHENE,CAMPHENE 90,CAMPHENE 46 L-Camphen 5-ETHYLIDENE-2-NORBORNENE CHLORINATED CAMPHENE,Camphene, chlorinated,CHLORINATED CAMPHENE (TOXAPHENE) (CAMPHECHOR) Methylene Chloride

  • Camphene(DOT)
  • 2,2-Dimethyl-3-methylene-bicyclo[2.2.1]heptane
  • (n)-camphene
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  • DL-CAMPHENE, TECH
  • 2-Dimethyl-3-methylenenorbornane
  • CaMphene, reMainder Mainly alpha-fenchene, 75% 1LT
  • CAMPHENE WITH GC
  • (+/-)-Camphene (contains ca. 20% Tricyclene)
  • D,L-CAMPHENE
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  • CAMPHENE 46
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  • FEMA 2229
  • AKOS NCG1-0107
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  • 3,3-DIMETHYL-2-METHYLENENORCAMPHANE
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  • Camphene,~80%
  • Camphene, remainder mainly alpha-fenchene, 75%
  • camphene,2,2-dimethyl-3-methylene-bicyclo[2.2.1]heptane;2,2-dimethyl-3-methylenenorborane
  • JACS-79-92-5
  • D.L-CaMphene 0
  • 2-Dimethyl-3-methylenenorbornane 3,3-Dimethyl-2-methylenenorcamphane
  • 2,2-dimethyl-3-methylene-bicyclo(2.2.1)heptan
  • 2,2-dimethyl-3-methylene-bicyclo[2.2.1]heptan
  • 3,3-Dimethyl-2-methylenenorbornane
  • 3,3-dimethyl-2-methylenenorcamphene
  • Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-
  • camphene(2,2-dimethyl-3-methylene-norbornane)
  • NA 9011
  • (+)-Camphene for synthesis
  • (+/-)-Camphene (contains ca. 20% Tricyclene)&gt
  • DL-Camphene (contains up to 20% tricyclene)
  • 78.0%(GC)
  • (+)-CAMPHENE FOR SYNTHESIS 1 KG
  • (+)-CAMPHENE FOR SYNTHESIS 100 G
  • (+/-)-Camphene
  • (1S,4S)-3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane
  • 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane (camphene)
  • Camphene Solution in Methanol
  • C10945000 DL-Camphene
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  • 79-92-5
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