1-NAPHTHALENEACETAMIDE
- Product Name
- 1-NAPHTHALENEACETAMIDE
- CAS No.
- 86-86-2
- Chemical Name
- 1-NAPHTHALENEACETAMIDE
- Synonyms
- NAAM;Frufix;Rootone;dirigoln;Rosetone;NAA Amide;Amid-Thin;Dirigol N;ROOTONE(R);Amid-Thin W
- CBNumber
- CB9316489
- Molecular Formula
- C12H11NO
- Formula Weight
- 185.22
- MOL File
- 86-86-2.mol
1-NAPHTHALENEACETAMIDE Property
- Melting point:
- 180-183 °C (lit.)
- Boiling point:
- 319.45°C (rough estimate)
- Density
- 1.0936 (rough estimate)
- refractive index
- 1.5300 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 16.10±0.40(Predicted)
- color
- White to Off-White
- BRN
- 1945547
- CAS DataBase Reference
- 86-86-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-Naphthaleneacetamide(86-86-2)
- EPA Substance Registry System
- 1-Naphthaleneacetamide (86-86-2)
Safety
- Hazard Codes
- Xn,C,F
- Risk Statements
- 22-41-34-11
- Safety Statements
- 26-39-24/25-45-36/37/39-16
- WGK Germany
- 3
- RTECS
- QJ0590000
- TSCA
- Yes
- HS Code
- 29242990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H318Causes serious eye damage
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- CRM43557
- Product name
- 1-Naphthylacetamide
- Purity
- certified reference material, TraceCERT?
- Packaging
- 100MG
- Price
- $129
- Updated
- 2025/07/31
- Product number
- 36732
- Product name
- 1-Naphthylacetamide
- Purity
- PESTANAL , analytical standard
- Packaging
- 1g
- Price
- $52.9
- Updated
- 2022/05/15
- Product number
- N0624
- Product name
- 2-(1-Naphthyl)acetamide
- Purity
- >98.0%(N)
- Packaging
- 25g
- Price
- $39
- Updated
- 2025/07/31
- Product number
- N0624
- Product name
- 2-(1-Naphthyl)acetamide
- Purity
- >98.0%(N)
- Packaging
- 500g
- Price
- $317
- Updated
- 2025/07/31
- Product number
- 36732
- Product name
- 1-Naphthylacetamide
- Purity
- PESTANAL?, analytical standard
- Packaging
- 250mg
- Price
- $56.9
- Updated
- 2025/07/31
1-NAPHTHALENEACETAMIDE Chemical Properties,Usage,Production
Chemical Properties
white to cream powder
Uses
1-Naphthylacetamide (cas# 86-86-2) is a compound useful in organic synthesis.
Definition
ChEBI: 1-naphthaleneacetamide is a member of the class of naphthalenes that is naphthalene which is substituted by a 2-amino-2-oxoethyl group at position 1. It is a synthetic auxin that is widely used in agriculture to promote the growth of numerous fruits, for root cuttings and as a fruit thinning agent. It has a role as a synthetic auxin. It is a member of naphthalenes and a primary carboxamide.
Agricultural Uses
Plant growth regulator: 1-Naphthaleneacetamide is an agent for thinning fruit sets in apples and pear. Not currently registered for use in EU countries (pending). Registered for use in the U.S.
Trade name
AMACTONE®; AMID-THIN W®; FRUITONE®; ROOTONE® (component, with Indole-3-butyric acid and 1-Naphthaleneacetic acid); ROSETONE®; TRANSPLANTONE® (component, with 1-Naphthaleneacetic acid)
Synthesis
5121-00-6
86-86-2
The general procedure for the synthesis of 1-naphthaleneacetamide from naphthalen-1-ylacetyl chloride was as follows: 1-naphthaleneacetic acid (93.5 mg, 0.50 mmol) was dissolved in dichloromethane (0.8 mL), a catalytic amount of DMF was added, followed by the slow, dropwise addition of oxalyl chloride (135.6 mg, 1.00 mmol, 2.00 equiv.) under stirring. The reaction mixture was stirred at room temperature for 15 minutes. Upon completion of the reaction, the solution was concentrated under vacuum and the resulting residue was dissolved in tetrahydrofuran (0.8 mL). Ammonia (28%, 450.4 mg, 7.50 mmol, 15.0 eq.) was added to this solution at 0 °C, after which the reaction mixture was transferred to room temperature and stirred for 10 min. At the end of the reaction, the solution was concentrated in vacuum and purified by silica gel column chromatography (eluent: chloroform/methanol, 10/1, Rf = 0.50) to afford the target product 1-naphthaleneacetamide (Y-015) as a white solid in 72% yield.
References
[1] Patent: JP2015/89885, 2015, A. Location in patent: Paragraph 0146; 0147; 0162-0164
[2] Chimica e l'Industria (Milan, Italy), 1955, vol. 37, p. 857,860
[3] Bulletin de la Societe Chimique de France, 1965, p. 861 - 868
[4] Journal of Medicinal Chemistry, 2009, vol. 52, # 10, p. 3366 - 3376
[5] Chemistry Letters, 2015, vol. 44, # 5, p. 621 - 623
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View Lastest Price from 1-NAPHTHALENEACETAMIDE manufacturers
- Product
- 1-Naphthaleneacetamide 86-86-2
- Price
- US $0.00/g
- Min. Order
- 100g
- Purity
- ≥98.0%
- Supply Ability
- 100kg/month
- Release date
- 2021-09-28
- Product
- 1-NAPHTHALENEACETAMIDE 86-86-2
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-22
- Product
- 1-NAPHTHALENEACETAMIDE 86-86-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-29