ChemicalBook > CAS DataBase List > (R)-(-)-Benzyl glycidyl ether

(R)-(-)-Benzyl glycidyl ether

Product Name
(R)-(-)-Benzyl glycidyl ether
CAS No.
14618-80-5
Chemical Name
(R)-(-)-Benzyl glycidyl ether
Synonyms
tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na
CBNumber
CB9320637
Molecular Formula
C10H12O2
Formula Weight
164.2
MOL File
14618-80-5.mol
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(R)-(-)-Benzyl glycidyl ether Property

Melting point:
88-93°C
Boiling point:
130 °C (0.1 mmHg)
alpha 
-5.4 º (c=5 in toluene)
Density 
1.077 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.517(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
paste (yellow)
Specific Gravity
1.077
color 
Colorless to Almost colorless
optical activity
[α]20/D 5.4°, c = 5 in toluene
Water Solubility 
Soluble in water.
BRN 
3588399
CAS DataBase Reference
14618-80-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
RTECS 
TX2860020
HS Code 
29109000
Toxicity
mic-sat 660 nmol/plate MUREAV 298,197,1993
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
791547
Product name
Titania paste, transparent
Packaging
10G
Price
$225
Updated
2024/03/01
Sigma-Aldrich
Product number
791547
Product name
Titania paste, transparent
Packaging
20G
Price
$326
Updated
2024/03/01
Sigma-Aldrich
Product number
720429
Product name
1H-Pyrazol-3-ylboronic acid hydrate
Packaging
1g
Price
$251
Updated
2023/06/20
Sigma-Aldrich
Product number
363529
Product name
(R)-(?)-Glycidyl benzyl ether
Purity
99%
Packaging
1g
Price
$42.4
Updated
2023/06/20
TCI Chemical
Product number
B2238
Product name
Benzyl (R)-(-)-Glycidyl Ether
Purity
>98.0%(GC)
Packaging
1g
Price
$19
Updated
2024/03/01
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(R)-(-)-Benzyl glycidyl ether Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.

Synthesis Reference(s)

Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6

General Description

1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Sodium hydride (S)-Oxiranemethanol N,N-Dimethylformamide Benzyl bromide Ethyl acetate PETROLEUM ETHER

Preparation Products

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View Lastest Price from (R)-(-)-Benzyl glycidyl ether manufacturers

Hebei Duling International Trade Co. LTD
Product
(R)-(-)-Benzyl glycidyl ether 14618-80-5
Price
US $51.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2023-03-16
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-()-Glycidyl benzyl ether 14618-80-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(R)-(-)-Benzyl glycidyl ether 14618-80-5
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-12

14618-80-5, (R)-(-)-Benzyl glycidyl etherRelated Search:

Epichlorohydrin Benzyl chloride Benzyl isocyanate Dimethyl ether Glycidyl acrylate Isobutylene oxide Styrene oxide ETHYLENE OXIDE (R)-Styrene oxide Benzyl alcohol Ethylbenzene Propylene oxide Benzyl nicotinate Benzyl benzoate Benzyl VERPROSIDE (R)-(+)-Trityl glycidyl ether Diethyl ether

  • (R)-(-)-BENZYL GLYCIDYL ETHER
  • (R)-BENZYL GLYCIDYL ETHER
  • (R)-BENZYLOXYMETHYL-OXIRANE
  • RARECHEM AK HZ 0049
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  • benzyl 4-hydroxyazepane-1-carboxylate
  • benzyl 4-oxoazepane-1-carboxylate
  • benzyl azepan-4-ylcarbamate
  • benzyl piperidin-3-ylcarbamate
  • dicyclopropylmethanamine
  • (S)-Morpholine-3-carboxylic acid AldrichCPR
  • [Ir(dtbbpy)(ppy)2][PF6] AldrichCPR
  • [Ir{dF(CF3)ppy}2(dtbpy)]PF6 AldrichCPR
  • 1-(2,2,2-trifluoroethyl)piperazine AldrichCPR
  • 1-(Tetrahydro-2H-pyran-2-yl)-3-pyrazole boronic acid MIDA ester 97%
  • 1H-Pyrazol-3-ylboronic acid hydrate
  • 2-Hexyl-4-pentynoic acid AldrichCPR
  • 3-(2-thienyl)pyrazole AldrichCPR
  • 3-(TrifluoroMethyl)-1,2,4-triazolo[4,3-a]piperazine hydrochloride AldrichCPR
  • 4'-(1H-1,2,4-triazol-1-yl)phenol AldrichCPR
  • 4-(2-Chlorophenoxy)piperidine hydrochloride AldrichCPR
  • 4-(DiphenylaMino)phenylboronic acid pinacol ester 95%
  • Azide-fluor 488 >=90% (HPLC)
  • BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct May contain up to 1 Mole equivalent of MTBE, 97%
  • CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 525 nM, 6 nM diaMeter, 1 Mg/ML in H2O
  • CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 575 nM, 6 nM diaMeter, 1 Mg/ML in H2O
  • Dibenzocyclooctyne-acid storage teMp.: -20C, 95%
  • Graphene oxide 2 Mg/ML, dispersion in H2O
  • Graphene oxide sheets
  • Isoflurane AldrichCPR
  • N,N-bis(2-hydroxyethyl)-1,4-phenylenediaMine sulfate AldrichCPR
  • PCy3 Pd G2 95%
  • PlatinuM on graphitized carbon extent of labeling: 20 wt. % loading
  • R-95 RhaMnolipid 95%, AldrichCPR
  • SodiuM undecylenate AldrichCPR
  • SYLGARD(R) 184 5 g clip-pack
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  • 2-AMINO-3-HYDROXY-3-METHYLPROPANENITRILE
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  • (R)-Benzyl glycidyl ether 98%
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