ChemicalBook > CAS DataBase List > (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Reactions- Product Name
- (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- CAS No.
- 185913-98-8
- Chemical Name
- (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- Synonyms
- )-5，5′(S)-CL-MEO-BIPHEP;(R)-CL-MEO-BIPHEP;min.(s)-cl-meo-biphep;(5,5'-Dichloro-6,6'-dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL;(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL;(+)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL;(-)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL;(S)-(-)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- CBNumber
- CB9337967
- Molecular Formula
- C38H30Cl2O2P2
- Formula Weight
- 651.5
- MOL File
- 185913-98-8.mol
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(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Property
- Melting point:
- 176-180 °C
- Boiling point:
- 678.2±55.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- yellow-white
- optical activity
- [α]20/D 59.0±4°, c = 1% in chloroform
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 76854
- Product name
- (S)-(−)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
- Purity
- ≥97.0%(H-NMR)
- Packaging
- 1g
- Price
- $1660
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1056
- Product name
- (S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP
- Packaging
- 250mg
- Price
- $119
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1056
- Product name
- (S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP
- Packaging
- 1g
- Price
- $414
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001349
- Product name
- (S)-(-)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $705.6
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FC139076
- Product name
- (S)-Cl-meo-biphep
- Packaging
- 100mg
- Price
- $260
- Updated
- 2021/12/16
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(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Usage,Production
Reactions
- Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls,and imines.
- Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes.
- Ligand used in the iridium-catalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines.
- Asymmetric Cu-catalyzed propargylic substitution with amines,4a and enamines.4b
- Catalytic desymmetrizing intramolecular Heck reaction.
- Assembly of 1,3-polyols.
- Pd-catalyzed diastereo/enantioselective allylic alkylations of ketone enolates.
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers
- Tel
- --
- Fax
- --
- sales@chemos-group.com
- Country
- Germany
- ProdList
- 6350
- Advantage
- 71
- Tel
- --
- Fax
- --
- info@abcr.de
- Country
- Germany
- ProdList
- 6831
- Advantage
- 75
185913-98-8, (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYLRelated Search:
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
Chloro[(S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct