ChemicalBook > CAS DataBase List > CHLOROTRIS(TRIMETHYLSILYL)SILANE
CHLOROTRIS(TRIMETHYLSILYL)SILANE
- Product Name
- CHLOROTRIS(TRIMETHYLSILYL)SILANE
- CAS No.
- 5565-32-2
- Chemical Name
- CHLOROTRIS(TRIMETHYLSILYL)SILANE
- Synonyms
- CHLOROTRIS(TRIMETHYLSILYL)SILANE;Tris(Trimethylsilyl) Chlorosilane;Tris(trimethylsilyl)silyl Chloride;Chlorotris(trimethylsilyl)silane 97%;Chlorotris(trimethylsilyl)silane >Chlorotris(trimethylsilyl)silane solution ;1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane;Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- CBNumber
- CB9343881
- Molecular Formula
- C9H27ClSi4
- Formula Weight
- 283.11
- MOL File
- 5565-32-2.mol
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CHLOROTRIS(TRIMETHYLSILYL)SILANE Property
- Melting point:
- 50-52 °C (lit.)
- Boiling point:
- 93°C/1.8mmHg(lit.)
- Density
- 0.877 g/mL at 25 °C
- Flash point:
- 87 °F
- form
- powder to lump
- color
- White to Almost white
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
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Safety
- Hazard Codes
- F,C,Xn,Xi
- Risk Statements
- 11-29-34-67-65-48/20-36/37/38-63
- Safety Statements
- 16-26-36/37/39-43-45-7/8-62-36/37-Neverusewater.
- RIDADR
- UN 2925 4.1/PG 2
- WGK Germany
- 3
- HS Code
- 2931.90.9010
- HazardClass
- 4.1/8
- PackingGroup
- II
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H261In contact with water releases flammable gas
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232Handle under inert gas. Protect from moisture.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 409405
- Product name
- Chlorotris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 10g
- Price
- $134
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 409405
- Product name
- Chlorotris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 25g
- Price
- $776
- Updated
- 2023/06/20
TCI Chemical
- Product number
- C2411
- Product name
- Chlorotris(trimethylsilyl)silane
- Purity
- >95.0%(GC)(T)
- Packaging
- 5g
- Price
- $119
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 706523
- Product name
- Chlorotris(trimethylsilyl)silane solution
- Purity
- 50 wt. % in toluene
- Packaging
- 10ml
- Price
- $105
- Updated
- 2022/05/15
TRC
- Product number
- C382090
- Product name
- Chlorotris(trimethylsilyl)silane
- Packaging
- 500mg
- Price
- $90
- Updated
- 2021/12/16
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CHLOROTRIS(TRIMETHYLSILYL)SILANE Chemical Properties,Usage,Production
Uses
Super Silyl Protecting Groups
Used for:
- Insertion into a P-P bond
- Diastereoselective aldol and cascade reactions
- Preparation of hypersilyl substituted monophosphines and diphosphines
General Description
Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.
CHLOROTRIS(TRIMETHYLSILYL)SILANE Preparation Products And Raw materials
Raw materials
Preparation Products
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5565-32-2, CHLOROTRIS(TRIMETHYLSILYL)SILANERelated Search:
Bis(trimethylsilyl)trifluoroacetamide
Trisilane
CHLOROTRIS(TRIMETHYLSILYL)SILANE
TRIS(TRIMETHYLSILYL)SILANE