DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)

Product Name: DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
CAS No.: 40691-33-6
Chemical Name: DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
Synonyms: orobis(tri-o-toL;PdCl2[P(o-Tol)3]2;PalladiuM,dichloro;tris-o-tolylphosphane;bis(tris-o-tolylphosphane);DICHLOROBIS(TRI-O-TOLYLPHOSPHI;Dichlorobis(tri-ortho-toylphosphine);Dichlorobis(tri-ortho-tolylphosphine);Dichlorobis(tris(o-tolyl)phosphine)palladium;dichloropalladium bis(tris-o-tolylphosphane)
CBNumber: CB9355767
Molecular Formula: C42H44Cl2P2Pd
Formula Weight: 788.08
MOL File: 40691-33-6.mol

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DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Property

Melting point:: 280 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in ethanol, benzene, and ethereal solvents.
form: Crystalline Powder
color: Yellow to orange
Sensitive: Air & Moisture Sensitive
InChI: InChI=1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;
InChIKey: KFQYTZDYGOBBOE-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1C)(C1C=CC=CC=1C)(C1C=CC=CC=1C)[Pd+2]([Cl-])([Cl-])P(C1C=CC=CC=1C)(C1C=CC=CC=1C)C1C=CC=CC=1C

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Safety

Risk Statements: 53
Safety Statements: 22-24/25
WGK Germany: 3
TSCA: No
HS Code: 28439000
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H413May cause long lasting harmful effects to aquatic life
Precautionary statements: P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 453048
Product name: Dichlorobis(tri-o-tolylphosphine)palladium(II)
Purity: 97%
Packaging: 1g
Price: $68.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: 453048
Product name: Dichlorobis(tri-o-tolylphosphine)palladium(II)
Purity: 97%
Packaging: 5g
Price: $190
Updated: 2025/07/31

TCI Chemical

Product number: B2026
Product name: Bis(tri-o-tolylphosphine)palladium(II) Dichloride
Purity: >90.0%(T)
Packaging: 1g
Price: $71
Updated: 2025/07/31

TCI Chemical

Product number: B2026
Product name: Bis(tri-o-tolylphosphine)palladium(II) Dichloride
Purity: >90.0%(T)
Packaging: 5g
Price: $272
Updated: 2025/07/31

Strem Chemicals

Product number: 46-0525
Product name: trans-Dichlorobis(tri-o-tolylphosphine)palladium(II), min. 95%
Packaging: 1g
Price: $42
Updated: 2024/03/01

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DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Chemical Properties,Usage,Production

Chemical Properties

Yellow to orange crystalline powder

Uses

suzuki reaction

Uses

Dichlorobis(tri-o-tolylphosphine)palladium(II) is used in reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides, coupling reaction of aryl bromides with vinylic acetates.

General Description

Dichlorobis(tri-o-tolylphosphine)palladium(II) is a useful catalyst for C-C and C-N coupling reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

Synthesis

Under the protection of argon, 15.5 g of tetrakis(triphenylphosphine)palladium(0) (Pd (PPh3) 4) (4 mmol), 7 mmol of p-bromotoluene, 0.5246 g of triphenylmercury (PPh3) (2 mmol) and 35 mL of toluene were added into a 100 mL Schlenk vial with electromagnetic stirring and the reaction was carried out at 85C for 4 h. After the temperature was lowered to room temperature, the toluene was removed. Wash with ether (3X10mL), draw dry to get white powder; white powder was recrystallized by dichloromethane/ether to get 0.448 g of colorless crystals of trans-dichlorobis(tri-O-tolylphosphine)palladium, the yield was 55. 9%.

DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Suppliers

Americas 1 Belgium 3 China 178 Europe 1 France 2 Germany 5 India 6 Japan 2 Switzerland 2 United Kingdom 3 United States 24 Global 227

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View Lastest Price from DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: dichlorobis(tri-o-tolylphosphine)palladium(ii) 40691-33-6
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-08

henan kanbei chemical co.,ltd

Product: DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) 40691-33-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Longyan Tianhua Biological Technology Co., Ltd

Product: DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) 40691-33-6
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-10

40691-33-6, DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)Related Search:

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II) DICHLOROBIS(INDENYL)TITANIUM(IV) Ruthenium(II) chloride mesitylene dimer Bis(diphenylphosphinophenyl)ether palladium (II) dichloride DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) Bis(tricyclohexylphosphine)palladium(II) Dichloride dichlorobis(di-tert-butylphenylphosphine)palladium(II) Bis(triphenylphosphine)palladium(II) chloride BIS(TRIPHENYLPHOSPHINE)COPPE DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) DIPHENYL(O-TOLYL)PHOSPHINE Tri(o-tolyl)phosphine Phosphine Palladium chloride DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) BIS(O-TOLYL)PHOSPHINE CIS-DICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)PALLADIUM(II)

trans-Dichlorobis(tri-o-tolylphosphine)palladium(II), min. 95%

Dichlorobis(tri-o-tolylphosphine)palladium(II), Pd 17.6%

Dichlorobis(tri-ortho-toylphosphine)

tris-o-tolylphosphane

orobis(tri-o-toL

TRANS-DICHLOROBIS-(TRI-O-TOLYLPHOSPHINE)-PALLADIUM

TRANS-DICHLOROBIS(TRI-O-TOLYL-PHOSPHINE)PALLADIUM(II)

trans-dichlorobis(tri-o-tolylphosphine)palladium(II)95+%

trans-Dichlorobis(tri-o-tolylphosphine)palladium(II),min.95%

Dichlorobis(tri-o-tolylphsophine)palladium, 98%

bis(tris(2-methylphenyl)phosphane) palladium dichloride

Dichlorobis(tris(o-tolyl)phosphine)palladium

trans-Dichlorobis(tri-ortho-tolylphosphine) palladium(II), 95%

trans-Dichlorobis(tri-ortho-toylphosphine) pa

PalladiuM,dichloro

trans-Dichlorobis(tri-ortho-toylphosphine) palladium (II) ,95% [C%: 61.9 - 66.4 %]

trans-Dichlorobis(tri-o-tolylphosphine)palladium(Ⅱ)

palladiuM(2+) dichloride - tris(2-Methylphenyl)phosphane

DICHLOROBIS(TRI-O-TOLYLPHOSPHI

trans-Dichlorobis(tri-ortho-tolylphosphine) palladium(Ⅱ)

PalladiuM,dichlorobis[tris(2-Methylphenyl)phosphine]-

palladiuM(2+) dichloride-tris(2-Methylphenyl)phosphane (1:2)

PdCl2[P(o-Tol)3]2

DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)

Bis[tri(o-tolyl)phosphine]palladium(II) chloride

BIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) DICHLORIDE

Bis (tri-o-tolylphosphine) palladium dichloride (II)

Bis(tri-o-tolylphosphine)palladium(II) Dichloride &gt

Dichlorobis(tri-ortho-tolylphosphine)

DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) ISO 9001：2015 REACH

Dichlorobis[tris(2-methylphenyl)phosphine]palladium

TIANFU CHEM DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)

bis(tris-o-tolylphosphane)

Dichlorobis[tris(2- methylphenyl)phosphine]-palladium(II)

Dichlorobis(tri- ortho -tolylphosphine)palladium(II)

Dichlorobis(tri-<i>o</i>-tolylphosphine)palladium(II)

dichloropalladium bis(tris-o-tolylphosphane)

bis(triorthomethylphenylphosphino)dichloropaladium

40691-33-6

CH3C6H43P2PdCl2

C42H42Cl2P2Pd

C42H42P2PdCl2

PdCl2PCH3C6H432

Classes of Metal Compounds

Metal Complexes

Catalysts for Organic Synthesis

Homogeneous Catalysts

Transition Metal Compounds

Pd (Palladium) Compounds

Homogeneous Pd Catalysts

Catalysis and Inorganic Chemistry

Pd

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Metal Complexes

Pd (Palladium) Compounds

Synthetic Organic Chemistry