4-BROMO-2-METHYLBENZYLAMINE

Product Name: 4-BROMO-2-METHYLBENZYLAMINE
CAS No.: 376646-62-7
Chemical Name: 4-BROMO-2-METHYLBENZYLAMINE
Synonyms: (4-BroMo-2-Methylphenyl)MethanaMine;RARECHEM AL BW 0436;(4-Bromo-2-methylphenyl);4-BROMO-2-METHYLBENZYLAMINE;4-bromo-2-methylbenzylaminie;4-Bromo-2-methylbenzenemethanamine;Benzenemethanamine, 4-bromo-2-methyl-;1-(4-bromo-2-methylphenyl)methanamine
CBNumber: CB9383924
Molecular Formula: C8H10BrN
Formula Weight: 200.08
MOL File: 376646-62-7.mol

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4-BROMO-2-METHYLBENZYLAMINE Property

Boiling point:: 270.9±25.0 °C(Predicted)
Density: 1.410±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 9.03±0.10(Predicted)
Appearance: Colorless to light yellow Liquid
Sensitive: Air Sensitive
InChI: InChI=1S/C8H10BrN/c1-6-4-8(9)3-2-7(6)5-10/h2-4H,5,10H2,1H3
InChIKey: CRDQDMSHRCFAAW-UHFFFAOYSA-N
SMILES: C1(CN)=CC=C(Br)C=C1C

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Safety

Hazard Codes: T

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific

Product number: 9535AF
Product name: (4-Bromo-2-methylphenyl)methanamine
Packaging: 5g
Price: $391
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0012911
Product name: 4-BROMO-2-METHYLBENZYLAMINE
Purity: 95.00%
Packaging: 5MG
Price: $501.93
Updated: 2021/12/16

Crysdot

Product number: CD12077459
Product name: (4-Bromo-2-methylphenyl)methanamine
Purity: 95+%
Packaging: 5g
Price: $253
Updated: 2021/12/16

Crysdot

Product number: CD12077459
Product name: (4-Bromo-2-methylphenyl)methanamine
Purity: 95+%
Packaging: 10g
Price: $379
Updated: 2021/12/16

AHH

Product number: MB-20939
Product name: (4-bromo-2-methylphenyl)methanamine
Purity: 97%
Packaging: 1g
Price: $466
Updated: 2021/12/16

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4-BROMO-2-METHYLBENZYLAMINE Chemical Properties,Usage,Production

Synthesis

67832-11-5

376646-62-7

Under nitrogen protection, 4-bromo-2-methylbenzonitrile (3.0 g, 15 mmol) was dissolved in anhydrous tetrahydrofuran (20 mL) and cooled to 0 °C. A tetrahydrofuran solution (46 mL) of 1.0 M borane was added slowly, keeping the reaction temperature at 0 °C. The reaction mixture was stirred at 0 °C for 1 h before being warmed to 80 °C and heated overnight. Upon completion of the reaction, the mixture was cooled to 0 °C and the reaction was quenched by slow addition of methanol and subsequently concentrated under vacuum. The crude product was treated with ethyl acetate (20 mL) and a 1,4-dioxane solution (8.0 mL, 32 mmol) of 4 M hydrochloric acid for 5 min. The solid was collected by filtration, washed with ether and dried to give 4-bromo-2-methylbenzenemethanamine as a white powder (3.24 g, yield: 100%). Liquid chromatography-mass spectrometry (LCMS) analysis: retention time (RT) 0.75 min, molecular ion peak (MH+) 200.0. nuclear magnetic resonance hydrogen spectrum (1H NMR, 300 MHz, DMSO-d6) δ: 8.28 (broad single peak, 2H), 7.42-7.54 (multiple peaks, 2H), 7.34 (double peak, J = 7.93 Hz, 1H) , 3.99 (double peak, J = 4.15 Hz, 2H), 2.35 (single peak, 3H).

References

[1] Patent: WO2015/89337, 2015, A1. Location in patent: Paragraph 0617
[2] Patent: WO2016/201271, 2016, A1. Location in patent: Paragraph 0114
[3] Patent: WO2015/89327, 2015, A1. Location in patent: Paragraph 0195

4-BROMO-2-METHYLBENZYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMO-2-METHYLBENZYLAMINE Suppliers

China 96 Germany 1 India 1 Switzerland 1 United Kingdom 2 United States 4 Global 105

Shanghai Ruipu Medical Technology Co., Ltd

Tel: 15895968936
Fax: qq 1018762393
Email: 1018762393@qq.com
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PharmaBlock Sciences (Nanjing),Inc.

Tel: 025-86918202 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 5000
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ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
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Country: China
ProdList: 2572
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Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
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Wuhan Arike Technology Co., Ltd.

Tel: 027- 51832457 94518350
Fax: E-Mail Inquiry
Country: China
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Shanghai Topbiochem Technology Co., Ltd

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Email: info@topbiochem.com
Country: China
ProdList: 9510
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Nanjing Norris-Pharm Technology Co., Ltd

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SynAsst Chemical.

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Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
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Suzhou Laing Biological Technology Co., LTD

Tel: 0512-62968256 18550502935
Fax: 0512-62968256
Email: export@laingbiotec.com
Country: China
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376646-62-7, 4-BROMO-2-METHYLBENZYLAMINERelated Search:

4-BROMO-2-METHYLBENZYLAMINE 3,4,5,6-TETRABROMOPHTHALIMIDE Pigment Green 36 4-Bromophthalimide 1,2-Bis(tetrabromophthalimido) ethane 2-BENZYL-5-BROMOISOINDOLINE-1,3-DIONE 3-(4-BROMO-2-METHYLPHENYL)-BETA-ALANINE (5-BROMO-1,3-DIOXO-1,3-DIHYDRO-ISOINDOL-2-YL)-ACETIC ACID 3-(5-BROMO-1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)PROPANOIC ACID ETHYL 3-AMINO-3-(4-BROMO-2-METHYLPHENYL)PROPANOATE HYDROCHLORIDE 4-(5-BROMO-1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)BUTANOIC ACID (6-BROMO-3-OXO-2,3-DIHYDRO-1 H-ISOINDOL-1-YL)-ACETIC ACID AURORA 17308 2-(5-BROMO-1,3-DIOXO-1,3-DIHYDRO-ISOINDOL-2-YL)-3-METHYL-BUTYRIC ACID AURORA 9580 4,5,6,7-TETRABROMO-2-(OXIRAN-2-YLMETHYL)ISOINDOLINE-1,3-DIONE AURORA 22131 N,N'-(methylenedi-p-phenylene)bis[3,4,5,6,-tetrabromophthalimide]

4-BROMO-2-METHYLBENZYLAMINE

RARECHEM AL BW 0436

(4-BroMo-2-Methylphenyl)MethanaMine

1-(4-bromo-2-methylphenyl)methanamine

4-Bromo-2-methylbenzenemethanamine

(4-Bromo-2-methylphenyl)

Benzenemethanamine, 4-bromo-2-methyl-

4-bromo-2-methylbenzylaminie

376646-62-7

Anilines, Aromatic Amines and Nitro Compounds