BENZYLBORONIC ACID PINACOL ESTER

Product Name: BENZYLBORONIC ACID PINACOL ESTER
CAS No.: 87100-28-5
Chemical Name: BENZYLBORONIC ACID PINACOL ESTER
Synonyms: pinacol benzylboronate;benzylboronic acidolester;Benzylboronic acid pinacol est;Benzylboronic acid pinacol ester 96%;2-BENZYL-4,4,5,5-TETRAMETHYL-(1,3,2)DIOXABOROLANE;2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >4,4,5,5-Tetramethyl-2-(phenylmethyl)-1,3,2-dioxaborolane;3-hydroxy-2,3-dimethylbutan-2-yl hydrogen benzylboronate;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethyl)-
CBNumber: CB9386657
Molecular Formula: C13H19BO2
Formula Weight: 218.1
MOL File: 87100-28-5.mol

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BENZYLBORONIC ACID PINACOL ESTER Property

Boiling point:: 65 °C0.15 mm Hg
Density: 0.980 g/mL at 25 °C
refractive index: n20/D 1.490
Flash point:: >230 °F
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: clear liquid
color: Colorless to Light yellow to Light orange
Water Solubility: Insoluble in water.
InChI: InChI=1S/C13H19BO2/c1-12(2)13(3,4)16-14(15-12)10-11-8-6-5-7-9-11/h5-9H,10H2,1-4H3
InChIKey: YCNQPAVKQPLZRS-UHFFFAOYSA-N
SMILES: O1C(C)(C)C(C)(C)OB1CC1=CC=CC=C1
CAS DataBase Reference: 87100-28-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Safety Statements: 23-24/25
WGK Germany: 3
Hazard Note: Irritant
HS Code: 2931900090
Storage Class: 10 - Combustible liquids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 659207
Product name: Benzylboronic acid pinacol ester
Purity: 96%
Packaging: 1g
Price: $58.1
Updated: 2023/06/20

TCI Chemical

Product number: B3448
Product name: 2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity: >97.0%(GC)
Packaging: 1g
Price: $42
Updated: 2026/03/19

TCI Chemical

Product number: B3448
Product name: 2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity: >97.0%(GC)
Packaging: 5g
Price: $117
Updated: 2026/03/19

TRC

Product number: B233083
Product name: Benzylboronic acid pinacol ester
Packaging: 1g
Price: $85
Updated: 2021/12/16

TRC

Product number: B233083
Product name: Benzylboronic acid pinacol ester
Packaging: 5g
Price: $140
Updated: 2021/12/16

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BENZYLBORONIC ACID PINACOL ESTER Chemical Properties,Usage,Production

Uses

Benzylboronic acid pinacol ester finds application in Pd (0)-mediated [11 C] carbonylation reaction.

Synthesis

The compound benzyl bromide (2 g, 11.7 mmol) was dissolved in anhydrous DMF (40 mL), and after the addition of pinacol ester of biboronic acid (4.45 g, 17.5 mmol), cuprous bromide (340 mg, 2.3 mmol), and sodium tert-butoxide (1.69 g, 17.5 mmol), it was protected by exchanging the air in the reaction flask with argon, and the reaction was carried out for 10 hours at 80 C. The reaction was carried out at 80C for 10 hours. The reaction was cooled to room temperature, filtered to remove the insoluble material, the filter cake was washed with a small amount of ethyl acetate, the filtrates were combined and extracted with ethyl acetate by adding an appropriate amount of water. The organic layer was collected and dried with anhydrous sodium sulfate, concentrated under reduced pressure and purified by silica gel column chromatography (eluent PE/EtOAc = 40:1) to obtain the product colorless oily 1.78 g, yield 70%.

BENZYLBORONIC ACID PINACOL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZYLBORONIC ACID PINACOL ESTER Suppliers

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View Lastest Price from BENZYLBORONIC ACID PINACOL ESTER manufacturers

Career Henan Chemical Co

Product: BENZYLBORONIC ACID PINACOL ESTER 87100-28-5
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

87100-28-5, BENZYLBORONIC ACID PINACOL ESTERRelated Search:

N,N-Dimethylformamide Phenylboronic acid (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE DIBENZYL SULFOXIDE p-Toluidine 2-Methylindole Benzylacetone Tetramethylammonium chloride 2-(4-Hexyl-2-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 4,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,1,3-benzothiadiazole

2-BENZYL-4,4,5,5-TETRAMETHYL-(1,3,2)DIOXABOROLANE

Benzylboronic acid pinacol est

4,4,5,5-Tetramethyl-2-(phenylmethyl)-1,3,2-dioxaborolane

Benzylboronic acid pinacol ester 96%

3-hydroxy-2,3-dimethylbutan-2-yl hydrogen benzylboronate

2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane &gt

1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethyl)-

pinacol benzylboronate

benzylboronic acidolester

87100-28-5

Organometallic Reagents

Boronic Acids and Derivatives

Boronate Esters

Alkyl

Alkyl Boronate Esters

Boronate Esters

Boronic Acids and Derivatives

Chemical Synthesis

Organometallic Reagents

Heterocyclic Compounds

Aryl

Boronic ester

Organoborons