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MENTHOFURAN

Product Name
MENTHOFURAN
CAS No.
494-90-6
Chemical Name
MENTHOFURAN
Synonyms
Menthofurane;4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN;Benzofuran, 4,5,6,7-tetrahydro-3,6-dimethyl-;FEMA 3235;MENTHOFURA;MENTHOFURAN;Menthofuran,95%;MENTHOFURAN(SG);UNII:LK024V9U3C;MENTHOFURAN WITH GC
CBNumber
CB9407301
Molecular Formula
C10H14O
Formula Weight
150.22
MOL File
494-90-6.mol
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MENTHOFURAN Property

Melting point:
86°C
Boiling point:
80-82 °C13 mm Hg(lit.)
Density 
0.97 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.485(lit.)
FEMA 
3235 | 4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN
Flash point:
168 °F
storage temp. 
Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear light yellow
Odor
at 1.00 % in dipropylene glycol. pungent musty nutty earthy coffee
Odor Type
musty
optical activity
[α]25/D +90°, c = 10 in methanol
JECFA Number
758
Stability:
Not stable in solution
LogP
4.02
CAS DataBase Reference
494-90-6(CAS DataBase Reference)
EPA Substance Registry System
Benzofuran, 4,5,6,7-tetrahydro-3,6-dimethyl- (494-90-6)
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Safety

Safety Statements 
24/25
WGK Germany 
2
RTECS 
DF7995750
TSCA 
Yes
HS Code 
29329990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W323500
Product name
4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity
≥95%
Packaging
sample
Price
$54.6
Updated
2023/06/20
Alfa Aesar
Product number
A17192
Product name
Menthofuran, 95%
Packaging
1g
Price
$42.65
Updated
2024/03/01
Alfa Aesar
Product number
A17192
Product name
Menthofuran, 95%
Packaging
5g
Price
$91.65
Updated
2024/03/01
Sigma-Aldrich
Product number
W323500
Product name
4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity
≥95%
Packaging
100g
Price
$142
Updated
2023/06/20
Sigma-Aldrich
Product number
W323500
Product name
4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity
≥95%
Packaging
25g
Price
$71
Updated
2023/01/07
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MENTHOFURAN Chemical Properties,Usage,Production

Chemical Properties

CLEAR LIGHT YELLOW LIQUID

Chemical Properties

Menthofuran occurs as the (+) isomer, in peppermint essential oils. It is a colorless liquid with a minty odor.

Chemical Properties

4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran has an odor very similar to that of menthol.

Occurrence

Reported found in peppermint oil, corn mint oil, spearmint oil, Scotch spearmint oil, pennyroyal oil and other Mentha oils and buchu oil.

Uses

Menthofuran is a toxin found in vairety of essential oils and is believed to be the compound responsible for the potentially fatal effects of Pennyroyal. Menthofuran is known to produce hepatotoxic intermedaites via oxidation process.

Uses

Menthofuran is a toxin found in vairety of essential oils and is believed to be the compound responsible for the potentially fatal effects of Pennyroyal. Menthofuran is known to produce hepatotoxic intermediates via oxidation process.

Definition

ChEBI: Menthofuran is a monoterpenoid that is 4,5,6,7-tetrahydro-1-benzofuran substituted by methyl groups at positions 3 and 6. It has a role as a nematicide and a plant metabolite. It is a member of 1-benzofurans and a monoterpenoid.

Preparation

(+)-Menthofuran [17957-94-7] is isolated fromMentha oils or is prepared synthetically, for example, by treatment of (+)-pulegone with fuming sulfuric acid in acetic anhydride and pyrolysis of the resulting sultone.

Taste threshold values

Taste characteristics at 10 ppm: musty, nutty, coffee, raw and legume

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 2442, 1983 DOI: 10.1021/jo00162a037

Synthesis

By thermal decomposition of the sulfone of 3-hydroxy-3,8(9)-methadiene-9-sulfonic acid; the latter is obtained by sulfonapulegone in acetic anhydride.

MENTHOFURAN Preparation Products And Raw materials

Raw materials

Preparation Products

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MENTHOFURAN Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32344
Advantage
50
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11714
Advantage
57
Shanghai Nuohey Chemical Co., Ltd.
Tel
021-52212593 13761626812
Fax
+86 (21) 51062076
Email
sales@nuohey.com
Country
China
ProdList
7135
Advantage
60
BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14059
Advantage
65
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6139
Advantage
55
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View Lastest Price from MENTHOFURAN manufacturers

PNP Biotech Co. Ltd
Product
Menthofurane 494-90-6
Price
US $0.00-0.00/KG
Min. Order
25KG
Purity
98%
Supply Ability
Inquiry
Release date
2022-10-25
Hebei Yanxi Chemical Co., Ltd.
Product
MENTHOFURAN 494-90-6
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-10
Hebei Guanlang Biotechnology Co., Ltd.
Product
MENTHOFURAN 494-90-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-02-02

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