MENTHOFURAN

ChemicalBook > CAS DataBase List > MENTHOFURAN

Product Name: MENTHOFURAN
CAS No.: 494-90-6
Chemical Name: MENTHOFURAN
Synonyms: Menthofurane;4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN;Benzofuran, 4,5,6,7-tetrahydro-3,6-dimethyl-;FEMA 3235;MENTHOFURA;MENTHOFURAN;Menthofuran,95%;MENTHOFURAN(SG);UNII:LK024V9U3C;MENTHOFURAN WITH GC
CBNumber: CB9407301
Molecular Formula: C10H14O
Formula Weight: 150.22
MOL File: 494-90-6.mol

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MENTHOFURAN Property

Melting point:: 86°C
Boiling point:: 80-82 °C13 mm Hg(lit.)
Density: 0.97 g/mL at 25 °C(lit.)
refractive index: n20/D 1.485(lit.)
FEMA: 3235 | 4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN
Flash point:: 168 °F
storage temp.: Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form: Liquid
color: Clear light yellow
Odor: at 1.00 % in dipropylene glycol. pungent musty nutty earthy coffee
Odor Type: musty
optical activity: [α]25/D +90°, c = 10 in methanol
JECFA Number: 758
Stability:: Not stable in solution
LogP: 4.02
CAS DataBase Reference: 494-90-6(CAS DataBase Reference)
EPA Substance Registry System: Benzofuran, 4,5,6,7-tetrahydro-3,6-dimethyl- (494-90-6)

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Safety

Safety Statements: 24/25
WGK Germany: 2
RTECS: DF7995750
TSCA: Yes
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Hazard statements: H227Combustible liquid
Precautionary statements: P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W323500
Product name: 4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity: ≥95%
Packaging: sample
Price: $54.6
Updated: 2023/06/20

Alfa Aesar

Product number: A17192
Product name: Menthofuran, 95%
Packaging: 1g
Price: $42.65
Updated: 2024/03/01

Alfa Aesar

Product number: A17192
Product name: Menthofuran, 95%
Packaging: 5g
Price: $91.65
Updated: 2024/03/01

Sigma-Aldrich

Product number: W323500
Product name: 4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity: ≥95%
Packaging: 100g
Price: $142
Updated: 2023/06/20

Sigma-Aldrich

Product number: W323500
Product name: 4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Purity: ≥95%
Packaging: 25g
Price: $71
Updated: 2023/01/07

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MENTHOFURAN Chemical Properties,Usage,Production

Chemical Properties

CLEAR LIGHT YELLOW LIQUID

Chemical Properties

Menthofuran occurs as the (+) isomer, in peppermint essential oils. It is a colorless liquid with a minty odor.

Chemical Properties

4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran has an odor very similar to that of menthol.

Occurrence

Reported found in peppermint oil, corn mint oil, spearmint oil, Scotch spearmint oil, pennyroyal oil and other Mentha oils and buchu oil.

Uses

Menthofuran is a toxin found in vairety of essential oils and is believed to be the compound responsible for the potentially fatal effects of Pennyroyal. Menthofuran is known to produce hepatotoxic intermediates via oxidation process.

Definition

ChEBI: Menthofuran is a monoterpenoid that is 4,5,6,7-tetrahydro-1-benzofuran substituted by methyl groups at positions 3 and 6. It has a role as a nematicide and a plant metabolite. It is a member of 1-benzofurans and a monoterpenoid.

Preparation

(+)-Menthofuran [17957-94-7] is isolated fromMentha oils or is prepared synthetically, for example, by treatment of (+)-pulegone with fuming sulfuric acid in acetic anhydride and pyrolysis of the resulting sultone.

Taste threshold values

Taste characteristics at 10 ppm: musty, nutty, coffee, raw and legume

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 2442, 1983 DOI: 10.1021/jo00162a037

Synthesis

By thermal decomposition of the sulfone of 3-hydroxy-3,8(9)-methadiene-9-sulfonic acid; the latter is obtained by sulfonapulegone in acetic anhydride.

MENTHOFURAN Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from MENTHOFURAN manufacturers

PNP Biotech Co. Ltd

Product: Menthofurane 494-90-6
Price: US $0.00-0.00/KG
Min. Order: 25KG
Purity: 98%
Supply Ability: Inquiry
Release date: 2022-10-25

Hebei Yanxi Chemical Co., Ltd.

Product: MENTHOFURAN 494-90-6
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-10

Hebei Guanlang Biotechnology Co., Ltd.

Product: MENTHOFURAN 494-90-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-02-02

494-90-6, MENTHOFURANRelated Search:

Geneticin Ethanol Citric acid Salicylic acid Furazolidone Carbofuran FURFURYL ALCOHOL RESIN Edible essence 2(4H)-Benzofuranone, 5,6-dihydro-3,6-dimethyl-, (6R)- MENTHOFURAN 3,6,6-TRIMETHYL-4-OXO-4,5,6,7-TETRAHYDRO-BENZOFURAN-2-CARBOXYLIC ACID (2,6,6-TRIMETHYL-4-OXO-4,5,6,7-TETRAHYDRO-BENZOFURAN-3-YL)-ACETIC ACID 3-ACETYL-2,6,6-TRIMETHYL-5,6,7-TRIHYDROOXAINDEN-4-ONE (R)-(+)-MENTHOFURAN,(+)-MENTHOFURAN,(+)-MENTHOFURAN, TERPENE STANDARD 4-HYDROXY-3,6,6-TRIMETHYL-4,5,6,7-TETRAHYDRO-1-BENZOFURAN-2-CARBOXYLIC ACID 6,6-DIMETHYL-4-OXO-4,5,6,7-TETRAHYDRO-1-BENZOFURAN-3-CARBOXYLIC ACID menthofuran synthase MENTHOFURAN(4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN)

3,6-Dimethyl-4,5,6,7-tetrahydro-1-benzofuran

3,9-Epoxy-p-mentha-3,8-diene

4,5,6,7-tetrahydro-3,6-dimethyl-benzofura

Benzofuran, 4,5,6,7-tetrahydro-3,6-dimethyl-

Menthofurane

p-Mentha-3,8-diene, 3,9-epoxy-

FEMA 3235

MENTHOFURAN

4,5,6,7-TETRAHYDRO-3,6-DIMETHYLBENZOFURAN

4 5 6 7-TETRAHYDRO-3 6-DIMETHYLBENZOFUR&

Menthofuran,95%

3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran

MENTHOFURAN(SG)

MENTHOFURAN WITH GC

MENTHOFURAN, NATURAL

(6R)-3,6-Dimethyl-4,5,6,7-tetrahydrobenzofuran

(R)-4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran

4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran,Menthofuran

Menthofuran, 95% 10GR

MENTHOFURA

UNII:LK024V9U3C

MENTHOFURAN Extra Pure

Inhibitor,peppermint oil biosynthesis,inhibit,monoterpene reductase,Menthofuran,Drug Metabolite

494-90-6