VALENCENE

Product Name: VALENCENE
CAS No.: 4630-07-3
Chemical Name: VALENCENE
Synonyms: Valencen;(1R,7R,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,8a-dimethyl-7-(1-methylethenyl)naphthalene;FEMA 3443;(3R,4aS,5R)-4a,5-Dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene;Naphthalene, 1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-, (1R,7R,8aS)-;VALENCENE;NSC 148969;Valencene T;VALENCENE 85;VALENCENE775
CBNumber: CB9420232
Molecular Formula: C15H24
Formula Weight: 204.35
MOL File: 4630-07-3.mol

More

Less

VALENCENE Property

Boiling point:: 274 °C(lit.)
Density: 0.92 g/mL at 25 °C(lit.)
FEMA: 3443 | VALENCENE
refractive index: n20/D 1.504(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form: Oil
color: Colourless
Specific Gravity: 0.92
Odor: at 10.00 % in dipropylene glycol. sweet fresh citrus grapefruit woody orange asprin dry green oily
Odor Type: citrus
optical activity: [α]22/D +90°, neat
Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems
JECFA Number: 1337
BRN: 3539153
Stability:: Light Sensitive
LogP: 6.29
EPA Substance Registry System: Naphthalene, 1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-, (1R,7R,8aS)- (4630-07-3)

More

Less

Safety

Safety Statements: 23-24/25
WGK Germany: 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H304May be fatal if swallowed and enters airways

Precautionary statements

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W344303
Product name: Valencene
Purity: natural, ≥65%
Packaging: 25g
Price: $91.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: W344303
Product name: Valencene
Purity: natural, ≥65%
Packaging: 100g
Price: $168
Updated: 2024/03/01

Sigma-Aldrich

Product number: W344303
Product name: Valencene
Purity: natural, ≥65%
Packaging: 1kg
Price: $1130
Updated: 2024/03/01

Sigma-Aldrich

Product number: 75056
Product name: (+)-Valencene
Purity: technical, ≥70%
Packaging: 10g
Price: $135
Updated: 2024/03/01

Sigma-Aldrich

Product number: 75056
Product name: (+)-Valencene
Purity: technical, ≥70%
Packaging: 50g
Price: $351
Updated: 2024/03/01

More

Less

VALENCENE Chemical Properties,Usage,Production

Description

(+)-Valencene is a sesquiterpene that has been found in C. sativa and is an aromatic component of orange essence oil. (+)-Valencene (50 μM) induces heme oxgenase-1 (HO-1) expression in macrophages and inhibits the expression of inducible nitric oxide synthase (iNOS), the production of nitric oxide (NO), and the release of high-mobility group box-1 (HMGB1) in RAW 264.7 cells stimulated with LPS. It also increases the survival rate in a mouse model of sepsis induced by cecal ligation and puncture. (+)-Valencene has been used in the synthesis of nootkatone .

Chemical Properties

clear colorless to yellowish liquid

Occurrence

Reported found in citrus fruits, orange peel, orange juice, bitter orange peel oil, lemon peel oil, grapefruit juice, grapefruit peel oil, kumquat peel oil, leaves and stalk of celery, clove stem, Thymus vulgaris L., fresh mango, globe artichoke, cardamom, mangosteen and cocoa.

Uses

Valencene is a sesquiterpene and an essential oil component found in a variety of plants, and has been shown to have functional antioxidant, antiradical and antimicrobial properties.

Uses

(+)-Valencene can be used as a precursor to prepare:

(+)-Nootkatone (a sesquiterpene) by dark singlet oxygenation.
Benzoyloxyvalencene by reacting with tert-butyl peroxy benzoate via Kharasch?Sosnovsky allylic oxidation method.
(+)-Lineariifolianone, a natural product.

Definition

ChEBI: A carbobicyclic compound and sesquiterpene that is 1,2,3,4,4a,5,6,7-octahydronaphthalene which is substituted a prop-1-en-2-yl group at position 3 and by methyl groups at positions 4a and 5 (the 3R,4aS,5R diastereoisomer).

Preparation

By a Wolf–Kishner reduction of nootkatone.

General Description

Valencene is the major sesquiterpene aroma constituent of orange peel oil. It is mainly used as a starting material to synthesize nootkatone, an important flavor compound of grapefruit.

VALENCENE Preparation Products And Raw materials

Raw materials

NOOTKATONE(SG)

Preparation Products

NOOTKATONE

More

Less

VALENCENE Suppliers

China 119 Germany 2 India 2 Israel 1 Switzerland 2 United Kingdom 6 United States 35 Global 167

BOC Sciences

Tel: 1-631-485-4226; 16314854226
Email: info@bocsci.com
Country: United States
ProdList: 14059
Advantage: 65

TargetMol Chemicals Inc.

Tel: +1-781-999-5354 +1-00000000000
Email: marketing@targetmol.com
Country: United States
ProdList: 19892
Advantage: 58

Alfa Chemistry

Tel: +1-5166625404
Fax: 1-516-927-0118
Email: Info@alfa-chemistry.com
Country: United States
ProdList: 21317
Advantage: 58

Aladdin Scientific

Tel: +1-833-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57511
Advantage: 58

More

Less

View Lastest Price from VALENCENE manufacturers

Hebei Kingfiner Technology Development Co.Ltd

Product: VALENCENE 4630-07-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 50000kg
Release date: 2024-05-20

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: VALENCENE 4630-07-3
Price: US $32.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000kg/week
Release date: 2024-05-15

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: VALENCENE 4630-07-3
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99.10%
Supply Ability: 50000kg
Release date: 2024-04-28

4630-07-3, VALENCENERelated Search:

(1alpha,2beta,4beta)-1-methyl-2,4-bis(methylvinyl)-1-vinylcyclohexane (METHYL SULFOXIDE)-D6, 99.89 ATOM% Diethanolamine Diethylenetriamine Rosemary Herb Extract Carbodiimide 1-Decanol (1S)-(-)-alpha-Pinene VALENCENE(SG) VALENCENE, TECH. VALENCENE(SECONDARY STANDARD) VALENCENE NOOTKATONE

7beta,8aalpha)]-theta-(1alph

Valencen

(3R,4AS,5R)-3-ISOPROPENYL-4A,5-DIMETHYL-1,2,3,4,4A,5,6,7-OCTAHYDRO-NAPHTHALENE

(3R,4AS,5R)-4A,5-DIMETHYL-3-ISOPROPENYL-1,2,3,4,4A,5,6,7-OCTAHYDRONAPHTHALENE

FEMA 3443

(+)-VALENCENE

VALENCENE

VALENCENE 85

VALENCENE 65+%

VALENCENE 85 (NATURAL)

(1R)-1,2,3,5,6,7,8,8a-Octahydro-1,8aα-dimethyl-7β-isopropenylnaphthalene

(1R)-1α,8aα-Dimethyl-7β-isopropenyl-1,2,3,5,6,7,8,8a-octahydronaphthalene

valencene,(+)-Valencene

Naphthalene, 1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-, (1R,7R,8aS)-

Naphthalene,1,2,3,5,6,7,8,

VALENCENE, NATURAL

(+)-Valencene, (3R,4aS,5R)-4a,5-Dimethyl-3-isopropenyl-1,2,3,4,4a,5,6,7-octahydronaphthalene

(R)-Valencene

Valencene,70%,tech.

Valencene,(+)-Valencene, (3R,4aS,5R)-4a,5-Dimethyl-3-isopropenyl-1,2,3,4,4a,5,6,7-octahydronaphthalene

(1R,7R,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,8a-dimethyl-7-(1-methylethenyl)naphthalene

1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-,[1R-(1.alpha.,7.beta.,8a.alpha.)]-Naphthalene

1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-naphthalen[1

3-Isopropenyl-4a,5-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalene

4.alpha.,10.alpha.-Dimethyl-6.beta.-isopropyl-.delta.-1,9-octalin

4alpha,10alpha-Dimethyl-6beta-isopropyl-delta1,9-octalin

4betaH,5alpha-Eremophila-1(10),11-diene

NSC 148969

(+)-Valencene technical, >=70%

Valencene Tech@100 μg/mL in Methanol

VALENCENE USP/EP/BP

VALENCENE775

(3R,4aS,5R)-4a,5-Dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene

(+)-valencene

(+)-Valencene 1000 μg/mL in Isopropanol

Valencene Natural Fermentation

Valencene T

4630-07-3

C15H24C15H24C15H24

Organic Building Blocks

Chiral Building Blocks

Asymmetric Synthesis

Alkenes

Plant Oils, Toxins, Phenolic Acids & Derivatives