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2-Bromophenylboronic acid

Product Name
2-Bromophenylboronic acid
CAS No.
244205-40-1
Chemical Name
2-Bromophenylboronic acid
Synonyms
o-BBBA;2-broMoborate;AKOS BRN-0929;RARECHEM AH PB 0074;2-Bromophenylboronic;2-BROMOPHENYLBORONIC ACID;O-BROMOPHENYLBORONIC ACID;(2-bromophenyl)boronicaci;2-BROMOBENZENEBORONIC ACID;2-Bromobenzeneboronicacid,98%
CBNumber
CB9421532
Molecular Formula
C6H6BBrO2
Formula Weight
200.83
MOL File
244205-40-1.mol
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2-Bromophenylboronic acid Property

Melting point:
113 °C(lit.)
Boiling point:
329.2±44.0 °C(Predicted)
Density 
1.67±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly)
form 
Powder
pka
8.25±0.58(Predicted)
color 
White to off-white
Water Solubility 
Soluble in methanol. Slightly soluble in water.
BRN 
8542615
CAS DataBase Reference
244205-40-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
473804
Product name
2-Bromophenylboronic acid
Purity
≥95.0%
Packaging
5g
Price
$31.6
Updated
2024/03/01
Sigma-Aldrich
Product number
473804
Product name
2-Bromophenylboronic acid
Purity
≥95.0%
Packaging
25g
Price
$150
Updated
2024/03/01
TCI Chemical
Product number
B2889
Product name
2-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$64
Updated
2024/03/01
Alfa Aesar
Product number
L18581
Product name
2-Bromobenzeneboronic acid, 98%
Packaging
1g
Price
$30.65
Updated
2024/03/01
Alfa Aesar
Product number
L18581
Product name
2-Bromobenzeneboronic acid, 98%
Packaging
5g
Price
$78.65
Updated
2024/03/01
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2-Bromophenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Uses

2-Bromobenzeneboronic acid is a boronic acid derivative that is widely used in organic synthesis for carbon-carbon bond formation. In Suzuki coupling, aryl halides and boronic acid aryl or vinyl esters or boronic acids are coupled using Pd(PPh3)4.

Application

2-Bromophenylboronic Acid is used as an inhibitor of the hormone sensitive lipase.
Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
It is also an important intermediate for Organic Light-Emitting Diod ( OLED) .

Preparation

2-Bromophenylboronic acid synthesis: take 2-bromoaniline as raw material, synthesize the intermediate 1-Bromo-2-iodobenzene through diazotization and iodination, and then carry out magnesium iodide exchange with isopropylmagnesium bromide to synthesize o-bromophenylmagnesium bromide, It is then subjected to substitution reaction with trimethyl borate to synthesize methyl o-bromophenylboronic acid, and then hydrolyzed to synthesize 2-bromophenylboronic acid.

2-Bromophenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromophenylboronic acid Suppliers

Shanghai Arbor Chemical Co., Ltd.
Tel
021-60451683 15021268886
Fax
+86-21-60451682
Email
sales@arborchemical.com
Country
China
ProdList
853
Advantage
55
Hebei Maison Chemical Co.,Ltd.
Tel
0311-85381176 15511852758
Fax
0311-83832777
Email
ruby@maisonchem.com.cn
Country
China
ProdList
547
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
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View Lastest Price from 2-Bromophenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-Bromophenylboronic acid 244205-40-1
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Guangzhou Sunton Biotechnology Co., Ltd.
Product
2-Bromophenylboronic acid 244205-40-1
Price
US $48.00-40.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200tons
Release date
2021-04-16
LY Global chemicals co.,ltd .
Product
2-Bromophenylboronic acid 244205-40-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%Min
Supply Ability
1000kg
Release date
2023-03-12

244205-40-1, 2-Bromophenylboronic acidRelated Search:


  • 2-broMoborate
  • o-BBBA
  • 2-Bromophenylboronic acid >=95.0%
  • Boronic acid,B-(2-bromophenyl)-
  • AKOS BRN-0929
  • RARECHEM AH PB 0074
  • O-BROMOPHENYLBORONIC ACID
  • 2-BROMOPHENYLBORONIC ACID
  • 2-BROMOBENZENEBORONIC ACID
  • 2-Bromophenylboronic
  • 2-Bromophenylboronic Acid (contains varying amounts of Anhydride)
  • 2-Bromobenzeneboronicacid,98%
  • 2-Bromophenylboronic acid,97%
  • 2-BroMophenylboronic Acid&nbsp
  • 2-BroMophenylboronic acid, 97% 5GR
  • VLOOKUP(C12,[1]Export!$D:$H,5,0)
  • 2-Bromophenylboronic acid ,98%
  • 2-Bromobenzeneboronic acid 98%
  • (2-bromophenyl)boronicaci
  • Boronic acid, B-(2-bromopheny!)-
  • 244205-40-1
  • C6H6BBrO2
  • Organometallic Reagents
  • Aryl
  • Boronic Acids
  • Boronic Acids and Derivatives
  • Boronic Acids and Derivatives
  • Boronate Ester
  • Boronic Acid
  • Potassium Trifluoroborate
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  • blocks
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  • Bromides
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Aryl
  • Boronic Acids