ChemicalBook > CAS DataBase List > Ruthenium carbonyl

Ruthenium carbonyl

Product Name: Ruthenium carbonyl
CAS No.: 15243-33-1
Chemical Name: Ruthenium carbonyl
Synonyms: Ru3(CO)12;TRIRUTHENIUM DODECACARBONYL;DODECACARBONYLTRIRUTHENIUM;pentaoxonium;RUTHENIUM CARBONYL;Rutheniumcarbonyl,99%;Ruthenium carbonyl 99%;carbon monoxide ruthenium;DIRUTHENIUM DODECACARBONYL;Ruthenium,dodecacarbonyltri-
CBNumber: CB9426890
Molecular Formula: C12O12Ru3
Formula Weight: 639.33
MOL File: 15243-33-1.mol

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Ruthenium carbonyl Property

Melting point:: 150 °C
storage temp.: Inert atmosphere,Room Temperature
solubility: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
form: crystal
color: orange
InChI: InChI=1S/12CO.3Ru/c12*1-2;;;
InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
SMILES: [O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[Ru].[Ru].[Ru]
CAS DataBase Reference: 15243-33-1(CAS DataBase Reference)
EPA Substance Registry System: Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)

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Safety

Hazard Codes: F,Xn
Risk Statements: 11-20-2017/11/20
Safety Statements: 24/25
RIDADR: 1325
WGK Germany: 3
Hazard Note: Flammable/Harmful
TSCA: Yes
HazardClass: 6.1
PackingGroup: II
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 245011
Product name: Triruthenium dodecacarbonyl
Purity: 99%
Packaging: 1g
Price: $121
Updated: 2025/07/31

Sigma-Aldrich

Product number: 245011
Product name: Triruthenium dodecacarbonyl
Purity: 99%
Packaging: 5g
Price: $432
Updated: 2025/07/31

TCI Chemical

Product number: T2181
Product name: Triruthenium Dodecacarbonyl
Packaging: 100mg
Price: $72
Updated: 2025/07/31

TCI Chemical

Product number: T2181
Product name: Triruthenium Dodecacarbonyl
Packaging: 1g
Price: $334
Updated: 2025/07/31

Strem Chemicals

Product number: 44-1850
Product name: Ruthenium carbonyl, 99%
Packaging: 1g
Price: $116
Updated: 2024/03/01

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Ruthenium carbonyl Chemical Properties,Usage,Production

Description

Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

Chemical Properties

The substance appears as orange plates or powder and is soluble in non-polar organic solvents.

Uses

Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Reactions

Catalyst for the conversion of enynes to catechol derivatives.
Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
3-Component couplings.
Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
Ester decarboxylation.
Catalyst for hydroamination and C-H bond activation.
Used in sp3 C-H bond arylation and carbonylation.
Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
Amination of α-hydroxy amides.

General Description

Atomic number of base material: 44 Ruthenium

reaction suitability

core: ruthenium
reaction type: C-H Activation
reagent type: catalyst

Ruthenium carbonyl Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ruthenium carbonyl manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Ruthenium Carbonyl 15243-33-1
Price: US $0.00/g
Min. Order: 1g
Purity: 98%min Ru:46.45%
Supply Ability: 500g
Release date: 2021-08-10

Hebei Chuanghai Biotechnology Co., Ltd

Product: Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 300kg
Release date: 2025-03-07

Career Henan Chemical Co

Product: RUTHENIUM CARBONYL 15243-33-1
Price: US $1.00/g
Min. Order: 100g
Purity: 99%
Supply Ability: G/KG/T
Release date: 2019-12-20

15243-33-1, Ruthenium carbonylRelated Search:

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15243-33-1

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C12H12Ru3

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Ru3C12O12

Ru Catalysts

Transition Metal Compounds

Classes of Metal Compounds

Ru (Ruthenium) Compounds

Catalysis and Inorganic Chemistry

Classes of Metal Compounds

Ru (Ruthenium) Compounds

Transition Metal Compounds

metal carbonyl complexes