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Ruthenium carbonyl

Product Name
Ruthenium carbonyl
CAS No.
15243-33-1
Chemical Name
Ruthenium carbonyl
Synonyms
Ru3(CO)12;TRIRUTHENIUM DODECACARBONYL;DODECACARBONYLTRIRUTHENIUM;pentaoxonium;RUTHENIUM CARBONYL;Rutheniumcarbonyl,99%;Ruthenium carbonyl 99%;carbon monoxide ruthenium;DIRUTHENIUM DODECACARBONYL;Ruthenium,dodecacarbonyltri-
CBNumber
CB9426890
Molecular Formula
C12O12Ru3
Formula Weight
639.33
MOL File
15243-33-1.mol
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Ruthenium carbonyl Property

Melting point:
150 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
form 
crystal
color 
orange
CAS DataBase Reference
15243-33-1(CAS DataBase Reference)
EPA Substance Registry System
Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-20-2017/11/20
Safety Statements 
24/25
RIDADR 
1325
WGK Germany 
3
Hazard Note 
Flammable/Harmful
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245011
Product name
Triruthenium dodecacarbonyl
Purity
99%
Packaging
1g
Price
$140
Updated
2024/03/01
Sigma-Aldrich
Product number
245011
Product name
Triruthenium dodecacarbonyl
Purity
99%
Packaging
5g
Price
$418
Updated
2024/03/01
TCI Chemical
Product number
T2181
Product name
Triruthenium Dodecacarbonyl
Packaging
100mg
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
T2181
Product name
Triruthenium Dodecacarbonyl
Packaging
1g
Price
$334
Updated
2024/03/01
Alfa Aesar
Product number
010507
Product name
Dodecacarbonyltriruthenium, 99%
Packaging
1g
Price
$127
Updated
2024/03/01
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Ruthenium carbonyl Chemical Properties,Usage,Production

Description

Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

Chemical Properties

The substance appears as orange plates or powder and is soluble in non-polar organic solvents.

Uses

Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Reactions

  1. Catalyst for the conversion of enynes to catechol derivatives.
  2. Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
  3. 3-Component couplings.
  4. Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
  5. Ester decarboxylation.
  6. Catalyst for hydroamination and C-H bond activation.
  7. Used in sp3 C-H bond arylation and carbonylation.
  8. Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
  9. Amination of α-hydroxy amides.

General Description

Atomic number of base material: 44 Ruthenium

Ruthenium carbonyl Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ruthenium carbonyl manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Ruthenium Carbonyl 15243-33-1
Price
US $0.00/g
Min. Order
1g
Purity
98%min Ru:46.45%
Supply Ability
500g
Release date
2021-08-10
Hebei Guanlang Biotechnology Co., Ltd.
Product
Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99
Supply Ability
300kg
Release date
2021-01-13
Career Henan Chemical Co
Product
RUTHENIUM CARBONYL 15243-33-1
Price
US $1.00/g
Min. Order
100g
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-20

15243-33-1, Ruthenium carbonylRelated Search:

Benzeneruthenium(II) chloride dimer [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Tris(triphenylphosphine)ruthenium(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro(p-cymene)ruthenium(II) dimer Rhodium(II) acetate dimer Ruthenium(II) chloride mesitylene dimer Tris(triphenylphosphine)rhodiu Rhodium(III) 2,4-pentanedionate Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium TPP Tungsten hexacarbonyl Molybdenum hexacarbonyl RUBIDIUM Dihydridotris(triphenylphosphine)ruthenium carbonyl Ruthenium carbonyl Ruthenium

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