Fenarimol

ChemicalBook > CAS DataBase List > Fenarimol

Product Name: Fenarimol
CAS No.: 60168-88-9
Chemical Name: Fenarimol
Synonyms: Bloc;EL-222;BLOC(R);RUBIGAN;Rimidin;FENARIMOL;RUBIGAN-4;RUBIGAN(R);RUBIGAN12EC;Fenarimol Standard
CBNumber: CB9431616
Molecular Formula: C17H12Cl2N2O
Formula Weight: 331.2
MOL File: 60168-88-9.mol

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Fenarimol Property

Melting point:: 117-119°C
Boiling point:: 0°C
Density: 1.3886 (rough estimate)
vapor pressure: 6.5 x 10^-5 Pa at 25 °C
refractive index: 1.5490 (estimate)
Flash point:: 0°C
storage temp.: 0-6°C
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 2.58
Water Solubility: 14.6 mg l^-1 (pH 3), 13.7 mg l^-1 (pH 7), 13.8 mg l^-1 (pH 10) at 25 °C
color: Off-White to Light Yellow
Merck: 13,3986
BRN: 5972869
CAS DataBase Reference: 60168-88-9(CAS DataBase Reference)
NIST Chemistry Reference: 5-Pyrimidinemethanol, «alpha»-(2-chlorophenyl)-«alpha»-(4-chlorophenyl)-(60168-88-9)
EPA Substance Registry System: Fenarimol (60168-88-9)

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Safety

Hazard Codes: Xn;N,N,Xn
Risk Statements: 51/53-62-63-64
Safety Statements: 36/37-61
RIDADR: UN 3017/3077
WGK Germany: 2
RTECS: UV9279400
Toxicity: LD50 in mice, rats (mg/kg): 4500, 2500 orally (Beraud)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H362May cause harm to breast-fed children

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P263Avoid contact during pregnancy/while nursing.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45484
Product name: Fenarimol
Purity: PESTANAL
Packaging: 250mg
Price: $175
Updated: 2024/03/01

TRC

Product number: F245735
Product name: Fenarimol
Packaging: 100mg
Price: $295
Updated: 2021/12/16

TRC

Product number: F245735
Product name: Fenarimol
Packaging: 250mg
Price: $605
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AGR0000077
Product name: FENARIMOL
Purity: 95.00%
Packaging: 100MG
Price: $650
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AGR0000077
Product name: FENARIMOL
Purity: 95.00%
Packaging: 5G
Price: $10900
Updated: 2021/12/16

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Fenarimol Chemical Properties,Usage,Production

Uses

Fenarimol is a broad spectrum pyrimidine carbinol fungicide with protective, curative and eradicative activities against powdery mildew (Erysiphe spp., Pudusphaera leucutricha, Uncinula necatur, Sphaerutheca spp., Leveillula spp.) and scab (Venturia spp.) in many crops. It also controls powdery mildew (Sphaerutheca pannusa) in ornamentals and Fusarium patch (Micruduccium niuale), Take-all patch (Laefisaria fuciformis), Dollar spot (Sderutina humeucavpa) and red thread (Gaeumannumyces graminis) in turf and amenity grasses.

Uses

Fenarimol is a pyrimidine based fungicide which acts against rusts, blackspot and mildew fungi and it works by inhibiting the fungus’s biosynthesis of important steroid molecules.

Uses

Plant fungicide.

Definition

ChEBI: (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol is a member of the class of pyrimidines that is pyrimidin-5-ylmethanol in which one of the hydrogens attached to the carbon bearing the hydroxy group is replaced by a 2-chlorophenyl group while the other is replaced by a 4-chlorophenyl group. It is a tertiary alcohol, a member of monochlorobenzenes and a member of pyrimidines.

General Description

Pure white crystalline solid. Used as a fungicide. Irritates skin and mucous membranes.

Reactivity Profile

Fenarimol produces toxic gases when heated to decomposition.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland NOx.

Metabolic pathway

The primary dissipation mechanism of fenarimol in the environment involves photolysis on plants/soil surfaces and water. More than 80 photoproducts have been observed, resulting from the reduction of the pyrimidine ring, hydrolysis, ring migration and cleavage of the phenyl and pyrimidine ring moieties. Under laboratory conditions in the dark, fenarimol is relatively persistent in soil, but a more rapid dissipation was observed under field conditions with DT₅₀ values of 18-140 days, attributed to photolysis of fenarimol on the soil surface. Fenarimol degrades in/on plant foliage/fruit surfaces mainly by photochemical processes. In animals, fenarimol is metabolised extensively to yield hydroxylated, cleavage and dechlorination products. The primary photolytic and metabolic pathways of fenarimol are presented in Schemes 1 and 2.

Degradation

Fenarimol(1) is stable in sterile buffered water in the dark at pH 3,6 and 9 at 25 °C, 37 °C and 52 °C for 28 days (Decker and Sullivan, 1975) but is readily degraded via photolysis. The photolytic DT₅₀ in distilled water under natural sunlight and clear sky conditions at 40°N in mid-summer was approximately 12 hours (Day, 1975). The primary aqueous photolysis reaction involved the migration of the pyrimidine ring to one of the chlorophenyl rings, followed by the oxidation of the carbinol moiety to the corresponding ketone to yield 4-chloro-2-(5-pyrimidyl)-2'-chlorobenzophenone (2).
Fenarimol was extensively photodegraded on solid surfaces. More than 80 photodegradation products were formed when fenarimol was exposed to sunlight on a stainless steel surface for up to 200 hours (Althaus and Bewley, 1978a). All photoproducts were formed at very low levels (less than 3% each) and 14 were identified. An abbreviated photogradation pathway of fenarimol is presented in Scheme 1. These products were generated from the following reactions: the migration of the pyrimidine ring to one of the chlorophenyl rings, followed by the oxidation of the carbinol moiety to yield compound 2; cleavage of either one of the chlorophenyl (to yield 3,4) or pyrimidine rings (5,6); aryl hydroxylation of one of the chlorophenyl rings (7); carbinol dehydroxylation reaction to yield 8 and a bridged fluorene product (9) from the dechlorination reaction. Various cleavage products (carboxylic acids) derived from the chlorophenyl (10-13) and the pyrimidine moieties (14) were also observed.

Fenarimol Preparation Products And Raw materials

Raw materials

n-Butyllithium 2-Chlorobenzoyl chloride

Preparation Products

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View Lastest Price from Fenarimol manufacturers

Hebei Zhanyao Biotechnology Co. Ltd

Product: 2-Chloronicotinamide 60168-88-9
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 Tons
Release date: 2021-10-14

Career Henan Chemical Co

Product: Fenarimol 60168-88-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 1ton
Release date: 2020-01-03

60168-88-9, FenarimolRelated Search:

Uracil Sulfadiazine Dichlorodiphenylsilane Silver sulfadiazine 1,3-Diphenyl-2-thiourea Diphenylphosphine Pyrimidine Benzhydrol 2,4-Diphenylimidazole Diphenylsilane tert-Butylchlorodiphenylsilane p-Naphtholbenzein 1,3-Dichlorobenzene Chlorphenamine maleate Diphenylmethane Chlorodiphenylphosphine 5-Pyrimidinemethanol Ancymidol

(2-Chlorophenyl)(4-chlorophenyl)5-pyrimidinylmethanol

(2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethanol

.alpha.-(2-chlorophenyl)-.alpha.-(4-chlorophenyl)-5-Pyrimidinemethanol

2,4’-dichloro-alpha-(pyrimidin-5-yl)benzhydrylalcohol

5-Pyrimidinemethanol, alpha-(2-chlorophenyl)-alpha-(4-chlorophenyl)-

2，4-Dichloro-α-(pyrimidin-5-y1)diphenylmethanol

2,4'-DICHLORO-A-(PYRIMIDIN-5-YL)DIPHENYLMETHANOL

2,4'-dichloro-alpha-(5-pyrimidinyl)benzhydryl alcohol

EL-222

FENARIMOL

BLOC(R)

A-(2-CHLOROPHENYL)-A-(4-CHLOROPHENYL)-5-(PYRIMIDINEMETHANOL)

RUBIGAN

RUBIGAN(R)

(±)2-(2-chlorophenyl)-2-(4-chlorophenyl)-5-pyrimidinemethanol

(±)2,4-dichloro-α-(pyrimidin-5-yl)benzhydryl alcohol

FENARIMOL, 100MG, NEAT

FENARIMOL PESTANAL (2,4'-DICHLORO- A-(PY

fenarimol (bsi,iso,ansi)

RUBIGAN-4

RUBIGAN12EC

.alpha.-(2-chlorophenyl)-.alpha.-(4-chlorophenyl)-5-Pyrimidinemethanol .alpha.-(2-Chlorophenyl)-.alpha.-(4-chlorophenyl)-5-pyrimidinemethanol

fenarimol (ISO) 2,4'-dichloro-α-(pyrimidin-5-yl)benzhydryl alcohol

alpha-(2-chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethano

alpha-(2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidinemethanol

Bloc

Rimidin

2，4'-dichloro-α-(pyrimidin-5-yl) dipehenylmethanol

(2-Chlorophenyl)-(4-chlorophenyl)-pyrimidin-5-yl-methanol

alpha-(2-Chlorophenyl)-alpha-(4-chlorophenyl)-5-pyrimidineme

α-(2-Chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol

α-(2-Chlorophenyl)α-(4-chlorophenyl)-5-pyrimidinemethanol

Fenarimol 100mg [60168-88-9]

Fenarimol Standard

Fenarimol Solution, 1000ppm

Bloc @100 μg/mL in MeOH

Fenarimol@1000 μg/mL in Acetone

5-Pyrimidinemethanol, α-(2-chlorophenyl)-α-(4-chlorophenyl)-

Fenarimol ISO 9001：2015 REACH

Fenarimol in Acetone

Fenarimol 100 μg/ml Acetonitrile

L13430000CY FenarimoL10μg/mLin Cyclohexane

L13430000EA FenarimoL10μg/mLin EthyLacetate

XA13430000CY FenarimoL100μg/mLin Cyclohexane

Pioglitazone Impurity 33

60168-88-9

C17H12Cl2NO

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