ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE
- Product Name
- ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE
- CAS No.
- 66315-23-9
- Chemical Name
- ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE
- Synonyms
- Ethyl 3-amino-4-(methylamino);Thyl3-amino-4-(methylamino)benzoate;ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE;3-Amino-4-(methylamino)benzoic acid ethyl ester;Benzoic acid, 3-amino-4-(methylamino)-, ethyl ester
- CBNumber
- CB9445273
- Molecular Formula
- C10H14N2O2
- Formula Weight
- 194.23
- MOL File
- 66315-23-9.mol
ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE Property
- Melting point:
- 87 °C
- Boiling point:
- 357.4±32.0 °C(Predicted)
- Density
- 1.173±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 5.45±0.11(Predicted)
- Appearance
- Brown to black Solid
Safety
- HazardClass
- IRRITANT
- HS Code
- 2922498590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
N-Bromosuccinimide Price
- Product number
- E899533
- Product name
- Ethyl3-Amino-4-(methylamino)benzoate
- Packaging
- 2.5g
- Price
- $195
- Updated
- 2021/12/16
- Product number
- 052695
- Product name
- Ethyl 3-amino-4-(methylamino)benzoate
- Packaging
- 500mg
- Price
- $33
- Updated
- 2021/12/16
- Product number
- 052695
- Product name
- Ethyl 3-amino-4-(methylamino)benzoate
- Packaging
- 2.500g
- Price
- $104
- Updated
- 2021/12/16
- Product number
- W7729
- Product name
- Ethyl3-amino-4-(methylamino)benzoate
- Packaging
- 10g
- Price
- $424
- Updated
- 2021/12/16
- Product number
- CHM0029669
- Product name
- ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $837.38
- Updated
- 2021/12/16
ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE Chemical Properties,Usage,Production
Definition
ChEBI: Ethyl 3-amino-4-(methylamino)benzoate is a benzoate ester.
Synthesis
71254-71-2
66315-23-9
Step 1-1-3 Synthesis of ethyl 3-amino-4-methylaminobenzoate: Ethyl 4-methylamino-3-nitrobenzoate (6.80 g, 30.3 mmol) prepared in Step 1-1-2 was dissolved in methanol (200 mL), and 5% palladium carbon catalyst (1.10 g) was added to the solution. The reaction mixture was stirred overnight at room temperature under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated to afford ethyl 3-amino-4-methylaminobenzoate (4.85 g, 82% yield) as a light brown powder. The product was characterized by 1H-NMR (CDCl3): δ 7.92 (dd, J = 1.9, 8.5 Hz, 1H), 7.40 (d, J = 1.9 Hz, 1H), 6.58 (d, J = 8.5 Hz, 1H), 4.31 (q, J = 7.3 Hz, 2H), 3.99 (brs, 1H), 3.22 (brs, 2H), and 2.19 (s, 3H), 1.36 (t, J = 7.3 Hz, 3H). Mass spectral analysis showed m/z: 194 (M+, base peak), 149.
References
[1] Patent: US2013/79306, 2013, A1. Location in patent: Paragraph 0234; 0235; 0236; 0237
[2] Chem.Abstr., 1978, vol. 89, # 61044,
[3] Chem.Abstr., vol. 89, # 61044,
ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE manufacturers
- Product
- ETHYL 3-AMINO-4-(METHYLAMINO)BENZOATE 66315-23-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-02