N-Methylformanilide

Product Name: N-Methylformanilide
CAS No.: 93-61-8
Chemical Name: N-Methylformanilide
Synonyms: NSC 3828;formaniL;METHYLFORMANILIDE;N-MethylforManilid;N-METHYLFORMANILIDE;N-methylform aniline;Methylphenylformamide;Formanilide, N-methyl-;N-METHYL-N-FORMANILIDE;DiMethyl forMylaniline
CBNumber: CB9450453
Molecular Formula: C8H9NO
Formula Weight: 135.16
MOL File: 93-61-8.mol

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N-Methylformanilide Property

Melting point:: 8-13 °C (lit.)
Boiling point:: 243-244 °C (lit.)
Density: 1.095 g/mL at 25 °C (lit.)
vapor pressure: 2.66 Pa (25 °C)
refractive index: n20/D 1.561(lit.)
Flash point:: 260 °F
storage temp.: Store below +30°C.
solubility: 10.3g/l
form: Liquid
pka: 0.53±0.50(Predicted)
color: Clear colorless to yellow
PH: 3.5-5.5 (H2O, 20℃)(saturated aqueous solution)
Water Solubility: immiscible
BRN: 636496
Dielectric constant: 17.210000000000001
InChI: 1S/C8H9NO/c1-9(7-10)8-5-3-2-4-6-8/h2-7H,1H3
InChIKey: JIKUXBYRTXDNIY-UHFFFAOYSA-N
SMILES: CN(C=O)c1ccccc1
LogP: 1.41 at 25℃
CAS DataBase Reference: 93-61-8(CAS DataBase Reference)
NIST Chemistry Reference: Formamide, N-methyl-N-phenyl-(93-61-8)
EPA Substance Registry System: Formamide, N-methyl-N-phenyl- (93-61-8)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-43-38
Safety Statements: 36/37
WGK Germany: 2
TSCA: TSCA listed
HS Code: 29242995
Storage Class: 10 - Combustible liquids
Hazard Classifications: Acute Tox. 4 Oral
Skin Sens. 1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M46802
Product name: N-Methylformanilide
Purity: 99%
Packaging: 100g
Price: $73.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: M46802
Product name: N-Methylformanilide
Purity: 99%
Packaging: 500g
Price: $147
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.06169
Product name: N-Methylformanilide
Purity: for synthesis
Packaging: 250ML
Price: $86.9
Updated: 2025/07/31

TCI Chemical

Product number: M0552
Product name: N-Methylformanilide
Purity: >99.0%(GC)
Packaging: 25g
Price: $18
Updated: 2025/07/31

TCI Chemical

Product number: M0552
Product name: N-Methylformanilide
Purity: >99.0%(GC)
Packaging: 100g
Price: $26
Updated: 2025/07/31

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N-Methylformanilide Chemical Properties,Usage,Production

Chemical Properties

clear colourless to yellow liquid

Uses

Organic synthesis.

Uses

N-Methylformanilide is used as a formylating reagent for certain organometallics. It is in combination with phosphoryl chloride used for Vilsmeier-Haack reactions and in heterocycle syntheses. Further, it acts as a swelling agent in the dyeing process of meta-aramid fibers.

Flammability and Explosibility

Not classified

Synthesis

21.4 mg (0.2 mmol) of N-methylaniline, 81.2 mg of ethyl bromodifluoroacetate (0.4 mmol), 2.5 mg (0.02 mmol) of cuprous acetate, 19.1 mg (0.04 mmol) of X-phos, and 32.7 mg (0.2 mmol) of cesium carbonate were added to 2 mLDMF solvent. The reaction was carried out at 110 ??C for 12 h. At the end of the reaction, it was cooled, filtered, and the filtrate was rotary evaporated to remove the solvent, and the residue was chromatographed on a silica gel column, drenched with a mixture of petroleum ether and ethyl acetate in a volume ratio of 8:1, the effluent was collected according to the actual gradient, detected by TLC, and the effluents containing the product were combined, and the solvent was removed by distillation in a rotary evaporator, and the solution was dried in vacuum to give the yellow liquid methanoylanilide 22.2 mg The yield was 82%.

N-Methylformanilide Preparation Products And Raw materials

Raw materials

carbanilic acid Potassium hydroxide solution FORMANILIDE

Preparation Products

5-Ethyl-2-thiophenecarboxaldehyde 3-(CYANOMETHYL)-2,4,5-TRIMETHYLTHIOPHENE Buprofezin 5-DIMETHYLAMINO-THIOPHENE-2-CARBALDEHYDE 3-IODO-2,4,5-TRIMETHYLTHIOPHENE N-CHLOROMETHYL-N-PHENYLCARBAMOYL CHLORIDE 5-Bromothiophene-2-carbaldehyde 2,3,5-Trimethylthiophene O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE 3-METHYLBENZO[B]THIOPHENE-2-CARBOXALDEHYDE 2-Chloro-5-thiophenecarboxaldehyde 1-METHYL-1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBALDEHYDE 4,5-DIMETHYLTHIOPHENE-2-CARBOXALDEHYDE

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N-Methylformanilide Suppliers

Americas 1 Belgium 2 China 265 China Hong Kong 1 Europe 4 France 2 Germany 9 Hungary 3 India 19 Italy 1 Japan 9 Slovakia 1 Switzerland 2 United Kingdom 9 United States 31 Global 359

Changde Changlian Chemical Company Limited

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Jay Chemicals

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J & K SCIENTIFIC LTD.

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future industrial shanghai co., ltd

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Email: sales@jonln.com
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Alfa Aesar

Tel: 400-6106006
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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
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Beijing Ouhe Technology Co., Ltd

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Fax: +86-10-82967029
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ProdList: 11776
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View Lastest Price from N-Methylformanilide manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: N-Methylformanilide 93-61-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-19

Hebei Chuanghai Biotechnology Co., Ltd

Product: N-Methylformanilide 93-61-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-19

Hebei Zhuanglai Chemical Trading Co Ltd

Product: N-Methylformanilide 93-61-8
Price: US $79.00-38.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-12-16

93-61-8, N-MethylformanilideRelated Search:

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FORMIC ACID N-METHYLANILIDE

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N-FORMYL-N-METHYLANILINE

N-METHYL-N-FORMANILIDE

N-METHYL-N-PHENYLFORMAMIDE

N-METHYLFORMANILIDE

N-Methylformanilide,99%

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(Methylphenylamino)formaldehyde

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N-METHYLFORMANILIDE FOR SYNTHESIS

N-MethylforManilid

NSC 3828

DiMethyl forMylaniline

N - Methyl forMyl aniline

<i>N</i>-Methylformanilide

formaniL

N-Methylformanilide&gt

N-Methylformanilide ISO 9001：2015 REACH

93-61-8,N-Methylformanilide

N-Methylformanilide, ≥ 99.0%

N-methylform aniline

93-61-8

HCONCH3C6H5

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