N-Methylformanilide

Product Name: N-Methylformanilide
CAS No.: 93-61-8
Chemical Name: N-Methylformanilide
Synonyms: NSC 3828;formaniL;METHYLFORMANILIDE;N-MethylforManilid;N-METHYLFORMANILIDE;N-methylform aniline;Methylphenylformamide;Formanilide, N-methyl-;N-METHYL-N-FORMANILIDE;DiMethyl forMylaniline
CBNumber: CB9450453
Molecular Formula: C8H9NO
Formula Weight: 135.16
MOL File: 93-61-8.mol

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N-Methylformanilide Property

Melting point:: 8-13 °C (lit.)
Boiling point:: 243-244 °C (lit.)
Density: 1.095 g/mL at 25 °C (lit.)
vapor pressure: 2.66 Pa (25 °C)
refractive index: n20/D 1.561(lit.)
Flash point:: 260 °F
storage temp.: Store below +30°C.
solubility: 10.3g/l
form: Liquid
pka: 0.53±0.50(Predicted)
color: Clear colorless to yellow
PH: 3.5-5.5 (H2O, 20℃)(saturated aqueous solution)
Water Solubility: immiscible
BRN: 636496
Dielectric constant: 17.210000000000001
InChI: 1S/C8H9NO/c1-9(7-10)8-5-3-2-4-6-8/h2-7H,1H3
InChIKey: JIKUXBYRTXDNIY-UHFFFAOYSA-N
SMILES: CN(C=O)c1ccccc1
LogP: 1.41 at 25℃
CAS DataBase Reference: 93-61-8(CAS DataBase Reference)
NIST Chemistry Reference: Formamide, N-methyl-N-phenyl-(93-61-8)
EPA Substance Registry System: Formamide, N-methyl-N-phenyl- (93-61-8)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-43-38
Safety Statements: 36/37
WGK Germany: 2
TSCA: TSCA listed
HS Code: 29242995
Storage Class: 10 - Combustible liquids
Hazard Classifications: Acute Tox. 4 Oral
Skin Sens. 1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M46802
Product name: N-Methylformanilide
Purity: 99%
Packaging: 100g
Price: $73.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: M46802
Product name: N-Methylformanilide
Purity: 99%
Packaging: 500g
Price: $147
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.06169
Product name: N-Methylformanilide
Purity: for synthesis
Packaging: 250ML
Price: $86.9
Updated: 2025/07/31

TCI Chemical

Product number: M0552
Product name: N-Methylformanilide
Purity: >99.0%(GC)
Packaging: 25g
Price: $18
Updated: 2025/07/31

TCI Chemical

Product number: M0552
Product name: N-Methylformanilide
Purity: >99.0%(GC)
Packaging: 100g
Price: $26
Updated: 2025/07/31

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N-Methylformanilide Chemical Properties,Usage,Production

Chemical Properties

clear colourless to yellow liquid

Uses

Organic synthesis.

Uses

N-Methylformanilide is used as a formylating reagent for certain organometallics. It is in combination with phosphoryl chloride used for Vilsmeier-Haack reactions and in heterocycle syntheses. Further, it acts as a swelling agent in the dyeing process of meta-aramid fibers.

Flammability and Explosibility

Not classified

Synthesis

21.4 mg (0.2 mmol) of N-methylaniline, 81.2 mg of ethyl bromodifluoroacetate (0.4 mmol), 2.5 mg (0.02 mmol) of cuprous acetate, 19.1 mg (0.04 mmol) of X-phos, and 32.7 mg (0.2 mmol) of cesium carbonate were added to 2 mLDMF solvent. The reaction was carried out at 110 C for 12 h. At the end of the reaction, it was cooled, filtered, and the filtrate was rotary evaporated to remove the solvent, and the residue was chromatographed on a silica gel column, drenched with a mixture of petroleum ether and ethyl acetate in a volume ratio of 8:1, the effluent was collected according to the actual gradient, detected by TLC, and the effluents containing the product were combined, and the solvent was removed by distillation in a rotary evaporator, and the solution was dried in vacuum to give the yellow liquid methanoylanilide 22.2 mg The yield was 82%.

N-Methylformanilide Preparation Products And Raw materials

Raw materials

carbanilic acid Potassium hydroxide solution FORMANILIDE

Preparation Products

5-Ethyl-2-thiophenecarboxaldehyde 3-(CYANOMETHYL)-2,4,5-TRIMETHYLTHIOPHENE Buprofezin 5-DIMETHYLAMINO-THIOPHENE-2-CARBALDEHYDE 3-IODO-2,4,5-TRIMETHYLTHIOPHENE N-CHLOROMETHYL-N-PHENYLCARBAMOYL CHLORIDE 5-Bromothiophene-2-carbaldehyde 2,3,5-Trimethylthiophene O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE 3-METHYLBENZO[B]THIOPHENE-2-CARBOXALDEHYDE 2-Chloro-5-thiophenecarboxaldehyde 1-METHYL-1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBALDEHYDE 4,5-DIMETHYLTHIOPHENE-2-CARBOXALDEHYDE

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N-Methylformanilide Suppliers

Americas 1 Belgium 2 China 265 China Hong Kong 1 Europe 4 France 2 Germany 9 Hungary 3 India 19 Italy 1 Japan 9 Slovakia 1 Switzerland 2 United Kingdom 9 United States 31 Global 359

Changde Changlian Chemical Company Limited

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Jay Chemicals

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J & K SCIENTIFIC LTD.

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future industrial shanghai co., ltd

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
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Beijing Ouhe Technology Co., Ltd

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View Lastest Price from N-Methylformanilide manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: N-Methylformanilide 93-61-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-19

Hebei Chuanghai Biotechnology Co., Ltd

Product: N-Methylformanilide 93-61-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-19

Hebei Zhuanglai Chemical Trading Co Ltd

Product: N-Methylformanilide 93-61-8
Price: US $79.00-38.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-12-16

93-61-8, N-MethylformanilideRelated Search:

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FORMIC ACID N-METHYLANILIDE

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N-METHYL-N-PHENYLFORMAMIDE

N-METHYLFORMANILIDE

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N-METHYLFORMANILIDE FOR SYNTHESIS

N-MethylforManilid

NSC 3828

DiMethyl forMylaniline

N - Methyl forMyl aniline

<i>N</i>-Methylformanilide

formaniL

N-Methylformanilide&gt

N-Methylformanilide ISO 9001：2015 REACH

93-61-8,N-Methylformanilide

N-Methylformanilide, ≥ 99.0%

N-methylform aniline

93-61-8

HCONCH3C6H5

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