ChemicalBook > CAS DataBase List > 9,10-DIAMINOPHENANTHRENE

9,10-DIAMINOPHENANTHRENE

Product Name
9,10-DIAMINOPHENANTHRENE
CAS No.
53348-04-2
Chemical Name
9,10-DIAMINOPHENANTHRENE
Synonyms
Einecs 258-490-9;9,10-DIAMINOPHENANTHRENE;9,10-PHENANTHRENEDIAMINE;Phenanthrene-9,10-diamine;phenanthrene-9,10-diylamine;9,10-Diaminophenanthrene 97%;N-methyl-N-(1-oxopropyl)carbamic acid (2,2-dimethyl-1,3-benzodioxol-4-yl) ester
CBNumber
CB9669396
Molecular Formula
C14H12N2
Formula Weight
208.26
MOL File
53348-04-2.mol
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9,10-DIAMINOPHENANTHRENE Property

Melting point:
164-166 °C (lit.)
Boiling point:
457.6±25.0 °C(Predicted)
Density 
1.283±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
5.15±0.30(Predicted)
form 
solid
Appearance
Light yellow to brown Solid
InChI
InChI=1S/C14H12N2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H,15-16H2
InChIKey
VPRFQZSTJXHBHL-UHFFFAOYSA-N
SMILES
C1=C2C(C3C(C(N)=C2N)=CC=CC=3)=CC=C1
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
2921599090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D22908
Product name
9,10-Diaminophenanthrene
Purity
97%
Packaging
1g
Price
$315.4
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
CHM0114989
Product name
9,10-DIAMINOPHENANTHRENE
Purity
95.00%
Packaging
1G
Price
$838.61
Updated
2021/12/16
Crysdot
Product number
CD43000303
Product name
Phenanthrene-9,10-diamine
Purity
95+%
Packaging
250mg
Price
$58
Updated
2021/12/16
Ambeed
Product number
A134010
Product name
Phenanthrene-9,10-diamine
Purity
95%
Packaging
250mg
Price
$61
Updated
2021/12/16
Crysdot
Product number
CD43000303
Product name
Phenanthrene-9,10-diamine
Purity
95+%
Packaging
1g
Price
$144
Updated
2021/12/16
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9,10-DIAMINOPHENANTHRENE Chemical Properties,Usage,Production

Synthesis

15810-15-8

53348-04-2

The general procedure for the synthesis of 9,10-diaminophenanthrene from 9,10-dibromophenanthrene was as follows: 1-3,200 mmol of 9,10-dibromophenanthrene was added to the reaction vessel; 300 mmol of ammonia, 600 mmol of potassium tert-butoxide, and 32 mol of Pd2(dba)3 were subsequently added, and dissolved by stirring with deoxidized toluene with ultrasonic assistance. The air in the reaction system was displaced three times and the ligand tri-tert-butylphosphine (4%, 8 mmol) was added. After displacing the air again three times, the reaction mixture was refluxed for 6 hours. After completion of the reaction, it was cooled to room temperature and sufficient dichloromethane was added to completely dissolve the product. The product was filtered through a funnel containing a small amount of silica gel to remove the catalyst and salt. The filtrate was concentrated to a viscous state and finally purified by column chromatographic separation to afford the target product 9,10-diaminophenanthrene in 170 mmol yield.

References

[1] Patent: CN108516961, 2018, A. Location in patent: Paragraph 0099; 0101

9,10-DIAMINOPHENANTHRENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 9,10-DIAMINOPHENANTHRENE manufacturers

Career Henan Chemical Co
Product
9,10-DIAMINOPHENANTHRENE 53348-04-2
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200kg
Release date
2018-12-24

53348-04-2, 9,10-DIAMINOPHENANTHRENERelated Search:


  • 9,10-PHENANTHRENEDIAMINE
  • 9,10-DIAMINOPHENANTHRENE
  • phenanthrene-9,10-diylamine
  • Phenanthrene-9,10-diamine
  • Einecs 258-490-9
  • 9,10-Diaminophenanthrene 97%
  • N-methyl-N-(1-oxopropyl)carbamic acid (2,2-dimethyl-1,3-benzodioxol-4-yl) ester
  • 53348-04-2
  • C14H12N2
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  • Nitrogen Compounds
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