ChemicalBook > CAS DataBase List > N,N-Dibenzylhydroxylamine

N,N-Dibenzylhydroxylamine

Product Name
N,N-Dibenzylhydroxylamine
CAS No.
621-07-8
Chemical Name
N,N-Dibenzylhydroxylamine
Synonyms
TIMTEC-BB SBB000533;Dibenzylhydroxyamine;N,N-Dibenzylhydroxyl;DIBENZYL HYDROXYLAMINE;N,N-Dibenzylhydroxylami;N,N-DIBENZYLHYDROXYAMINE;bis(4-ethylphenyl)diazene;N,N-DIBENZYLHYDROXYLAMINE;N,N-Dibenzylhydroxylamine[1];N,N-Dibenzylhydroxylamine>
CBNumber
CB9681826
Molecular Formula
C14H15NO
Formula Weight
213.27
MOL File
621-07-8.mol
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N,N-Dibenzylhydroxylamine Property

Melting point:
125-128 °C (lit.)
Boiling point:
353.27°C (rough estimate)
Density 
1.0439 (rough estimate)
refractive index 
1.5300 (estimate)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
Water Solubility 
Insoluble in water
form 
powder to crystal
pka
13.19±0.69(Predicted)
color 
White to Almost white
BRN 
978234
CAS DataBase Reference
621-07-8(CAS DataBase Reference)
NIST Chemistry Reference
Hydroxylamine, n,n-dibenzyl-,(621-07-8)
EPA Substance Registry System
Benzenemethanamine, N-hydroxy-N-(phenylmethyl)- (621-07-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
2928.00.2500
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D35457
Product name
N,N-Dibenzylhydroxylamine
Purity
98%
Packaging
5g
Price
$27.04
Updated
2024/03/01
TCI Chemical
Product number
D2004
Product name
N,N-Dibenzylhydroxylamine
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$108
Updated
2024/03/01
Alfa Aesar
Product number
B22447
Product name
N,N-Dibenzylhydroxylamine, 98%
Packaging
5g
Price
$40.65
Updated
2024/03/01
Alfa Aesar
Product number
B22447
Product name
N,N-Dibenzylhydroxylamine, 98%
Packaging
25g
Price
$135.65
Updated
2024/03/01
Alfa Aesar
Product number
B22447
Product name
N,N-Dibenzylhydroxylamine, 98%
Packaging
100g
Price
$364.65
Updated
2024/03/01
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N,N-Dibenzylhydroxylamine Chemical Properties,Usage,Production

Chemical Properties

white to slightly yellow adhering crystalline

Uses

N,N-Dibenzylhydroxylamine, upon oxidation, yields N-benzyl-α-phenylnitrone, which can undergo cycloaddition reaction with suitable dipolarophiles. It can be used to synthesize N,N,O-trisubstituted hydroxylamines and arylamines.

Preparation

A mixture of 14 gm (0.202 mole) of hydroxylamine hydrochloride and 50 gm (0.395 mole) of benzyl chloride in 200 ml of 70% ethanol is treated with 60 gm of crystalline sodium carbonate. The mixture is heated under a reflux condenser for 2 hr, cooled to room temperature, filtered, and the solids discarded. The filtrate is treated with sufficient ice water to cause precipitation of A^N-dibenzylhydroxylamine. The reaction mixture is then thoroughly cooled in a freezing mixture to permit complete precipitation of product to take place. The yield, upon filtration, is 26 gm (61.5%), m.p. 123°C. A similar preparation has recently been reported [13a].

N,N-Dibenzylhydroxylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N-Dibenzylhydroxylamine Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
Hattori Corporation
Tel
--
Fax
--
Email
info@hattoricorp.com
Country
Japan
ProdList
1254
Advantage
58
K. Sakai & Co., Ltd.
Tel
--
Fax
--
Email
em@ksakai.co.jp
Country
Japan
ProdList
957
Advantage
58
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from N,N-Dibenzylhydroxylamine manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
N, N-Dibenzylhydroxyamine 621-07-8
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-13
Hebei Weibang Biotechnology Co., Ltd
Product
N,N-Dibenzylhydroxylamine 621-07-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04
Hebei Chuanghai Biotechnology Co,.LTD
Product
N,N-Dibenzylhydroxylamine 621-07-8
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

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