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BIS(PHENYLTHIO)METHANE

Product Name
BIS(PHENYLTHIO)METHANE
CAS No.
3561-67-9
Chemical Name
BIS(PHENYLTHIO)METHANE
Synonyms
Bis(phenylthio);DIPHENYLTHIOMETHANE;BIS(PHENYLTHIO)METHANE;Bis(phenyithio)methane;Bis(thiophenoxy)methane;Bis(phenylthio)methane,97%;Bis(phenylthio)methane >Bis(phenylthio)methane,98+%;Methylenebis(phenyl sulfide);Formaldehydediphenylmercapatal
CBNumber
CB9686902
Molecular Formula
C13H12S2
Formula Weight
232.36
MOL File
3561-67-9.mol
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BIS(PHENYLTHIO)METHANE Property

Melting point:
34-37 °C(lit.)
Boiling point:
194 °C8 mm Hg(lit.)
Density 
1.2633 (rough estimate)
refractive index 
1.6210 (estimate)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Light yellow
Water Solubility 
Insoluble in water.
BRN 
1874146
CAS DataBase Reference
3561-67-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 3335
WGK Germany 
3
F 
13
HazardClass 
STENCH
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B1444
Product name
Bis(phenylthio)methane
Purity
>97.0%(GC)
Packaging
5g
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
B1444
Product name
Bis(phenylthio)methane
Purity
>97.0%(GC)
Packaging
25g
Price
$68
Updated
2024/03/01
Alfa Aesar
Product number
L01723
Product name
Bis(phenylthio)methane, 98+%
Packaging
5g
Price
$29.65
Updated
2024/03/01
Alfa Aesar
Product number
L01723
Product name
Bis(phenylthio)methane, 98+%
Packaging
25g
Price
$90.65
Updated
2024/03/01
TRC
Product number
P320828
Product name
Bis(phenylthio)methane
Packaging
50mg
Price
$45
Updated
2021/12/16
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BIS(PHENYLTHIO)METHANE Chemical Properties,Usage,Production

Chemical Properties

light yellow crystalline powder

Uses

Bis(phenylthio)methane (PhSCH2SPh) may be used in the synthesis of the following:

  • dihydroxy thioethers
  • [Cu4I4{μ-PhS2CH2SPh}2]n
  • [(η5-C5Me5)MCl2(η1-(PhS)2CH2)] (M=Rh, Ir ; C5Me5= pentamethylcyclopentadienyl)
  • 6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactoheptodialdo-1,5-pyranose diphenyl dithioacetal

Synthesis Reference(s)

Synthetic Communications, 19, p. 31, 1989 DOI: 10.1080/00397918908050949
Synthesis, p. 447, 1975 DOI: 10.1055/s-1975-23797

General Description

Bis(phenylthio)methane (PhSCH2SPh) is a dithioether ligand. It forms coordination complex with silver(I) salts. It participates in the synthesis of (-)-rasfonin.

BIS(PHENYLTHIO)METHANE Preparation Products And Raw materials

Raw materials

Thiophenol Diiodomethane weak SODIUM THIOPHENOXIDE

Preparation Products

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BIS(PHENYLTHIO)METHANE Suppliers

Americas 1 Belgium 4 Canada 1 China 57 Europe 2 France 1 Germany 4 India 6 Japan 3 Norway 1 Switzerland 2 United Kingdom 13 United States 31 Global 126
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from BIS(PHENYLTHIO)METHANE manufacturers

Career Henan Chemical Co
Product
(Methylenebis(thio))bisbenzene 3561-67-9
Price
US $1.00/g
Min. Order
1g
Purity
Min98%HPLC
Supply Ability
g/kg/ton
Release date
2020-01-09

3561-67-9, BIS(PHENYLTHIO)METHANERelated Search:

DICYCLOHEXYLDICHLOROSILANE BIS(4-CHLOROPHENYLTHIO)METHANE BIS(PHENYLSULFONYL)METHANE TRIPHENYL TRITHIOORTHOFORMATE BIS(PHENYLTHIO)METHANE BIS-(TOLUENE-4-SULFONYL)-METHANE Probucol ELSIBUCOL 4-[4-[2-(4-hydroxy-3,5-ditert-butyl-phenyl)sulfanylpropan-2-ylsulfanyl]-2,6-ditert-butyl-phenoxy]-4-oxo-butanoic acid BIS(P-TOLUENESULFONYL)DIAZOMETHANE 1,1,3-TRIS(PHENYLTHIO)-1-PROPENE BIS(2-CHLOROPHENYL) CYANOCARBONIMIDODITHIOATE CAMOBUCOL BIS[(4-CHLOROPHENYL)THIOMETHYLENE]BIPHOSPHONIC ACID, TETRAISOPROPYL ESTER 1,1-BIS(PHENYLSULFONYL)ETHYLENE SALOR-INT L147877-1EA 1,1,1-TRIFLUORO-4,4-BIS(PHENYLTHIO)BUT-3-EN-2-ONE 1-([2-METHYL-1-(PHENYLTHIO)PROPYL]THIO)BENZENE

  • BIS(PHENYLTHIO)METHANE
  • 1-(methylthio)-2-(phenylthio)benzene
  • 1,1'-(Methanediyldisulfanediyl)dibenzene
  • 1-([(PHENYLTHIO)METHYL]THIO)BENZENE
  • DIPHENYLTHIOMETHANE
  • FORMALDEHYDE DIPHENYL MERCAPTAL
  • 1,1'-(METHYLENEBIS(THIO))BISBENZENE
  • [methylenebis(thio)]bisbenzene
  • Formaldehydediphenylmercapatal
  • Bis(phenylthio)methane,98+%
  • Methylenebis(phenyl sulfide)
  • Phenyl(phenylthiomethyl) sulfide
  • Bis(phenylthio)methane,97%
  • 1,1'-(Methanediyldisulphanediyl)dibenzene
  • Bis(phenylthio)methane, Bis(phenylsulphanyl)methane
  • Bis(phenylthio)methane >=98.0% (GC)
  • Bis(phenylthio)
  • ([(Phenylsulfanyl)methyl]sulfanyl)benzene
  • Benzene, 1,1'-[methylenebis(thio)]bis-
  • Bis(phenyithio)methane
  • Bis(thiophenoxy)methane
  • Diphenylthiomethane, Formaldehyde diphenyl mercaptal
  • Bis(phenylthio)methane &gt
  • 3561-67-9
  • C6H5SCH2SC6H5
  • C13H12S2
  • CH2SC6H52
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  • BI - BZ
  • Analytical Standards
  • Analytical Chromatography Product Catalog
  • Sulfur Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry