ChemicalBook > CAS DataBase List > 2-(2-Bromoethyl)-1,3-dioxane

2-(2-Bromoethyl)-1,3-dioxane

Product Name
2-(2-Bromoethyl)-1,3-dioxane
CAS No.
33884-43-4
Chemical Name
2-(2-Bromoethyl)-1,3-dioxane
Synonyms
)-1,3-dioxane;2-Bromopropionaldehy;LABOTEST-BB LT00233134;2-(2-bromoethyl)-3-dioxane;2-(2-Bromethyl)-1,3-dioxane;2-(2-BROMOETHYL)-1,3-DIOXANE;1,3-Dioxane, 2-(2-bromoethyl)-;2-(2-Bromoethyl)-1,3-dioxane>2-(2-Bromoethyl)-1,3-dioxane 98%;2-(2-BROMOETHYL)-1,3-DIOXANE, STAB.
CBNumber
CB9715024
Molecular Formula
C6H11BrO2
Formula Weight
195.05
MOL File
33884-43-4.mol
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2-(2-Bromoethyl)-1,3-dioxane Property

Melting point:
157-161 °C
Boiling point:
67-70 °C2.8 mm Hg(lit.)
Density 
1.431 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.481(lit.)
Flash point:
206 °F
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
ethanol: soluble50 (μg/mL)
form 
Liquid
color 
Clear colorless
Water Solubility 
It is not soluble in water but soluble in organic solvent such as ethanol.
BRN 
1421628
InChI
InChI=1S/C6H11BrO2/c7-3-2-6-8-4-1-5-9-6/h6H,1-5H2
InChIKey
WMDHQEHPOVOEOG-UHFFFAOYSA-N
SMILES
O1CCCOC1CCBr
CAS DataBase Reference
33884-43-4(CAS DataBase Reference)
NIST Chemistry Reference
2(2-Bromoethyl)-1,3-dioxane(33884-43-4)
EPA Substance Registry System
1,3-Dioxane, 2-(2-bromoethyl)- (33884-43-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-24/25
WGK Germany 
3
F 
8-10
TSCA 
Yes
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
269131
Product name
2-(2-Bromoethyl)-1,3-dioxane
Purity
98%
Packaging
10g
Price
$79.7
Updated
2023/06/20
Sigma-Aldrich
Product number
269131
Product name
2-(2-Bromoethyl)-1,3-dioxane
Purity
98%
Packaging
50g
Price
$300
Updated
2023/06/20
TCI Chemical
Product number
B1182
Product name
2-(2-Bromoethyl)-1,3-dioxane
Purity
>97.0%(GC)
Packaging
5g
Price
$39
Updated
2024/03/01
TCI Chemical
Product number
B1182
Product name
2-(2-Bromoethyl)-1,3-dioxane
Purity
>97.0%(GC)
Packaging
25g
Price
$154
Updated
2024/03/01
Alfa Aesar
Product number
L00958
Product name
2-(2-Bromoethyl)-1,3-dioxane, 98%
Packaging
10g
Price
$34.65
Updated
2024/03/01
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2-(2-Bromoethyl)-1,3-dioxane Chemical Properties,Usage,Production

Uses

2-(2-Bromoethyl)-1,3-dioxane was used in the synthesis of ketone adducts 2-[3-oxo-4(S)-(triphenylmethyl) amino-6-methylheptyl]-1,3-dioxane and 2-[3-oxo-4(S)-(triphenylmethyl)amino-6-methylheptyl]-1,3-dioxolane.

General Description

The reaction of Grignard reagent prepared from 2-(2-bromoethyl)-1,3-dioxane and N-tert-butanesulfinyl aldimines was studied.

Synthesis

A 2-L, three-necked flask has a mechanical stirrer, thermometer, and gas inlet tube. In the flask, 750 mL of dichloromethane, 112 g (2.00 mol) of acrolein (Note 1), and 0.10 g of dicinnamalacetone indicator are placed under nitrogen. The yellow solution is cooled to 0–5°C with an ice bath. Gaseous hydrogen bromide is bubbled into the solution with stirring until the indicator becomes deep red. The ice bath is removed, and 1.0 g of p-toluenesulfonic acid monohydrate and 152.2 g (2.00 mol, 144 mL) of 1,3-propanediol are added. The yellow solution is stirred at room temperature for 8 hr and then concentrated with a rotary evaporator. The residual oil is washed with two 250-mL portions of saturated aqueous sodium bicarbonate and dried over anhydrous potassium carbonate. Vacuum distillation through a 30-cm Vigreux column yields 252 g (65%) of 2-(2-Bromoethyl)-1,3-dioxane as a colourless liquid.

storage

This bromide is recognized to possess irritant properties and should therefore invariably be handled with gloved hands inside an efficient hood. It is also advisable that these reagents be refrigerated for long-term storage in order to minimize the potential for acid liberation.

2-(2-Bromoethyl)-1,3-dioxane Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(2-Bromoethyl)-1,3-dioxane Suppliers

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View Lastest Price from 2-(2-Bromoethyl)-1,3-dioxane manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-(2-Bromoethyl)-1,3-dioxane 33884-43-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-15
Henan Aochuang Chemical Co.,Ltd.
Product
2-(2-Bromoethyl)-1,3-dioxane 33884-43-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-30
Career Henan Chemical Co
Product
2-(2-Bromoethyl)-1,3-dioxane 33884-43-4
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-20

33884-43-4, 2-(2-Bromoethyl)-1,3-dioxaneRelated Search:

Bromocyclopentane 1-Bromohexane Cyclohexane Ethylcyclohexane Enrofloxacin hydrochloride Hexane Hexabromocyclododecane Acetal Methylcyclohexane 1,4-Dioxane 1,3,5-trioxane Cyclohexene oxide 1,3-DIOXANE 3-Bromo-1-propanol 3-BROMOPROPIONALDEHYDE DIMETHYL ACETAL 1-Bromo-3-methoxypropane 1,2-Dioxane 1-BROMO-3-ETHOXYPROPANE

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  • LABOTEST-BB LT00233134
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  • 2-(2-BROMOETHYL)-1,3-DIOXANE, STAB.
  • 2-bromopropanal 1,3-propanediol acetal
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  • 33884-43-4
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