ChemicalBook > CAS DataBase List > 6-CHLOROBENZOTHIAZOLE

6-CHLOROBENZOTHIAZOLE

Product Name
6-CHLOROBENZOTHIAZOLE
CAS No.
2942-10-1
Chemical Name
6-CHLOROBENZOTHIAZOLE
Synonyms
6-Chlorbenzthiazol;6-Chlor-benzothiazol;6-CHLOROBENZOTHIAZOLE;Benzothiazole,6-chloro-;6-Chlorobenzo[d]thiazole;6-Chloro-1,3-benzothiazole;Benzothiazole, 6-chloro- (6CI,7CI,8CI,9CI)
CBNumber
CB9738430
Molecular Formula
C7H4ClNS
Formula Weight
169.63
MOL File
2942-10-1.mol
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6-CHLOROBENZOTHIAZOLE Property

Melting point:
41 °C
Boiling point:
111 °C(Press: 2 Torr)
Density 
1.435±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
0.21±0.10(Predicted)
Appearance
Off-white to gray Solid
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Safety

HS Code 
29342000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C651798
Product name
6-Chlorobenzo[d]thiazole
Packaging
500mg
Price
$310
Updated
2021/12/16
AK Scientific
Product number
2985AB
Product name
6-Chlorobenzo[d]thiazole
Packaging
100mg
Price
$127
Updated
2021/12/16
Matrix Scientific
Product number
119473
Product name
6-Chlorobenzo[d]thiazole
Purity
95+%
Packaging
250mg
Price
$202
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0044170
Product name
6-CHLOROBENZOTHIAZOLE
Purity
95.00%
Packaging
5MG
Price
$499.82
Updated
2021/12/16
Matrix Scientific
Product number
119473
Product name
6-Chlorobenzo[d]thiazole
Purity
95+%
Packaging
1g
Price
$504
Updated
2021/12/16
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6-CHLOROBENZOTHIAZOLE Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

95-24-9

2942-10-1

The general procedure for the synthesis of 6-chlorobenzothiazole from 2-amino-6-chlorobenzothiazole was as follows: 0.3 mmol of 2-amino-6-chlorobenzothiazole, 0.6 mmol of sodium nitrite, and 3 mL of 1,2-dichloroethane were added to a closed reaction vessel. The reaction mixture was stirred at 110°C for 60 hours. After completion of the reaction, the mixture was cooled to room temperature, diluted with 10 mL of dichloromethane and subsequently filtered. The solvent was removed by distillation under reduced pressure and the resulting residue was purified by column chromatography with an eluent ratio of V (petroleum ether)/V (ethyl acetate) = 6/1 to give the final 6-chlorobenzothiazole in 89% yield.

References

[1] Chemical and Pharmaceutical Bulletin, 1998, vol. 46, # 4, p. 623 - 630
[2] Patent: CN105367442, 2016, A. Location in patent: Paragraph 0018
[3] Chemical and Pharmaceutical Bulletin, 1997, vol. 45, # 9, p. 1547 - 1549
[4] Tetrahedron, 2013, vol. 69, # 22, p. 4436 - 4444
[5] Synthetic Communications, 1980, vol. 10, # 3, p. 167 - 174

6-CHLOROBENZOTHIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-CHLOROBENZOTHIAZOLE Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
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+86-21-54098501
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+86-21-54096319
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sales@sinch.com.cn
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China
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
Fax
021-58099609
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bin.wu@shlschem.com
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China
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9883
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China DongFan Chemical Co.,LTD
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86-0571-85151182
Fax
86-0571-85151182
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China
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chenyue Chemicals Co., Ltd.
Tel
+86-0519-85500896
Fax
+86-0519-85335069
Email
benzoxazolone@163.com
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China
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178
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Beijing Taiya Jie Technology Development Co., Ltd.
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021-33690831-8001 13552411790
Fax
021-33690831
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postmaster@tyjchem.cn
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China
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Shanghai ACT chemical Limited
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021-59904146 18001826933
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+86-21-59904146
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China
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ShangHai AmK Pharmaceutical Technology Co., Ltd.
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微信 17321281695 18019252918
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sale@amkchem.com
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China
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Nanjing Duolong Bio-tech Co.,Ltd.
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18905173768
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025-83263139
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52513593@qq.com
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China
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Cool Pharm, Ltd
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021-60455363 18019463053
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50966098
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sales@coolpharm.com
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China
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58