Description Properties Approval
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2-(Thiocyanatomethylthio)benzothiazole

Description Properties Approval
Product Name
2-(Thiocyanatomethylthio)benzothiazole
CAS No.
21564-17-0
Chemical Name
2-(Thiocyanatomethylthio)benzothiazole
Synonyms
TCMTB;BUSAN;benthiazole;2-(THIOCYANOMETHYLTHIO)BENZOTHIAZOLE;TCMTP;Busa 72;busan15;busan30;busan70;busan71
CBNumber
CB9752494
Molecular Formula
C9H6N2S3
Formula Weight
238.35
MOL File
21564-17-0.mol
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2-(Thiocyanatomethylthio)benzothiazole Property

Melting point:
<-10 °C
Boiling point:
>120 °C
Density 
d25 1.05 (c = 0.30)
refractive index 
1.5500 (estimate)
Flash point:
(open cup): 66°C
storage temp. 
0-6°C
solubility 
soluble in Chloroform, Ethyl Acetate
form 
Oil
pka
-0.09±0.10(Predicted)
color 
Brown to Dark Brown
Odor
pungent odor
InChI
InChI=1S/C9H6N2S3/c10-5-12-6-13-9-11-7-3-1-2-4-8(7)14-9/h1-4H,6H2
InChIKey
TUBQDCKAWGHZPF-UHFFFAOYSA-N
SMILES
S(CSC1=NC2=CC=CC=C2S1)C#N
CAS DataBase Reference
21564-17-0(CAS DataBase Reference)
NIST Chemistry Reference
Thiocyanic acid, (2-benzothiazolylthio)methyl ester(21564-17-0)
EPA Substance Registry System
2-(Benzothiazolylthio)methyl thiocyanate (21564-17-0)
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Safety

Hazard Codes 
T+,N,Xn
Risk Statements 
22-26-36/38-43-50/53-36/37/38
Safety Statements 
28-36/37-38-45-60-61-36-26
RTECS 
XK8150900
HS Code 
29342000
Hazardous Substances Data
21564-17-0(Hazardous Substances Data)
Toxicity
LD50 in male, female rats (mg/kg): 752, 679 orally (Rush)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H330Fatal if inhaled

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P320Specific treatment is urgent (see … on this label).

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
T535280
Product name
Tolcide2230(90%)
Packaging
1g
Price
$425
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0069042
Product name
TCMTB
Purity
95.00%
Packaging
100MG
Price
$739.2
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0069042
Product name
TCMTB
Purity
95.00%
Packaging
1G
Price
$1871.1
Updated
2021/12/16
Matrix Scientific
Product number
098898
Product name
2-((Thiocyanatomethyl)thio)benzo[d]thiazole
Purity
95+%
Packaging
1g
Price
$2835
Updated
2021/12/16
AK Scientific
Product number
P282
Product name
2-(Thiocyanatomethylthio)benzothiazole
Packaging
1g
Price
$3877
Updated
2021/12/16
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2-(Thiocyanatomethylthio)benzothiazole Chemical Properties,Usage,Production

Description

(Benzothiazol-2-ylthio)methyl thiocyanate (TCMTB) is a chemical compound classified as a benzothiazole. 2-(thiocyanomethylthio)benzothiazole is a a soil and seed treatment used to control various fungal and bacterial infections. It is moderately soluble in water, has a low volatility and is not expected to be persistent in soil systems. It is not eexpected to leach to groundwater. It has a pungent odour, is highly toxic to most aquatic species and moderately toxic to birds. 2-(thiocyanomethylthio)benzothiazole is highly toxic to humans via the oral route and is a recognised irritant.    
   

Properties

TCMTB is an oily, flammable, red to brown liquid with a pungent odor that is very slightly soluble in water. It decomposes on heating producing hydrogen cyanide, sulfur oxides, and nitrogen oxides. The degradation products are 2-mercaptobenzothiazole (2-MBT) and 2-benzothiazolesulfonic acid.

Approval

TCMTB is not an authorized plant protection product in the European Union.In Germany, Austria and Switzerland, no plant protection products containing this active substance are authorized.

Chemical Properties

Brown Oil

Physical properties

It is a viscous reddish liquid and is insoluble in vater, but soluble in organic solvents such as acetone,dimethylformamide,cyclohexanone, benzene and xylene. It has a specific gravityof 1.38,a boiling point greater than 120℃ and a vapour pressure of about 0.05 torr. The supplier normally dissolves TCMTB in a mixture of organic solvents to form a concentrate. Emulsifiers or surfactants may be added to the concentrate to improve the stability of emulsions formed when the concentrate is diluted withwater. TCMTB is sold commercially as 80% technical material under thetrade name "TCMTB" by Buckman Laboratories,Which is the soleanufacturer of the material.The patented preparationinvolves a reaction of 2-mercaptobenzothiazole and chloromethylthiocyanate,but confidential data obtained from Buckman Laboratories indicates another preparative method may now be used.

History

The commercial use of TCMTB apparently had its origins in with Buckman Laboratories,Inc., of Memphis,Tennessee. In thelate 1940's this company became involved in the search for solutions to the problem of breaks in paper on high speed paperachines due to the formation of microbiological slime.rhecompany first developed the microbiocide BSM-11,a product containing mercuric acetate and trichlorophenol, which seemed tof ind acceptance in the paper making industry. However, in view of the potentiaL for adverse health and environmental impacts from the use of mercury compounds,BuckmanLaboratories developed a 1ine of organosulphur compounds whichalso proved to be effective slime control agents."Alone, or inconjunction with other active ingredients,TCMTB is now found in avariety of Buckman products.

Uses

2-(Thiocyanatomethylthio)benzothiazole is an antimicrobial agent used as a substitute for chlorophenols in industrial applications.

Uses

Wood preservative, marine biocide, fungicide.

Application

2-(Thiocyanatomethylthio)benzothiazole can be used as:

  • Industrial antimicrobial used instead of chlorophenols;
  • Used as a wood preservative, marine biocide, and fungicide;
  • Used as a contact fungicide for barley, cotton. corn, oats, rice, sorghum. sugar beets, safflower, and wheat;
  • in seed treatments for cereals, corn, cotton, legumes, rice, sorghum, and sugar beets;
  • as preservative in paints and leather production;
  • Used as a wood preservative, biocide (pulp & paper mills, sewage systems), product preservative and slimicide (paper, leather, paint, carpet, textiles, wallpaper), and seed treatment pesticide.

Toxicology

There are few published studies on the toxicity of TCMTB or Busan1030. Confidential information received from Buckman Laboratoriesindicates that most of the toxicity studies on TCMTB and Busan 1030 have been carried out by private laboratories and that this data vas submitted to government agencies as part of the pesticideregistration process. "Unfortunately, this data is not available from Agriculture Canada, but has been requested by the company from the B.C. Ministry of Environment and Parks' wasteManagement Branch .

2-(Thiocyanatomethylthio)benzothiazole Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Thiocyanatomethylthio)benzothiazole Suppliers

Hubei Shishun Biotechnology Co. Ltd
Tel
027-59223025 15107168801
Fax
027-59223025
Email
1718480011@qq.com
Country
China
ProdList
9853
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2988
Advantage
65
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
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View Lastest Price from 2-(Thiocyanatomethylthio)benzothiazole manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
2-(Thiocyanatomethylthio)benzothiazole 21564-17-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-28
WUXI HONOR SHINE CHEMICAL CO.,LTD
Product
TCMTB 21564-17-0
Price
US $0.00/kg
Min. Order
25kg
Purity
30%;60%;80%
Supply Ability
200TONS
Release date
2022-06-10
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-(Thiocyanatomethylthio)benzothiazole 21564-17-0
Price
US $100.00-50.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-21

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